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Geochemistry and age of paleoproterozoic metavolcanoic and metasedimentary rocks of the Don terrane of the Volga-Don orogen

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1. Title Title of document Geochemistry and age of paleoproterozoic metavolcanoic and metasedimentary rocks of the Don terrane of the Volga-Don orogen
2. Creator Author's name, affiliation, country R. А. Terentiev; Voronezh State University; Russian Federation
2. Creator Author's name, affiliation, country К. А. Savko; Voronezh State University; Russian Federation
2. Creator Author's name, affiliation, country Е. H. Korish; Voronezh State University; Russian Federation
2. Creator Author's name, affiliation, country М. V. Chervyakovskaya; Zavaritskii Institute of Geology and Geochemistry, Ural Branch, Russian Academy of Sciences; Russian Federation
3. Subject Discipline(s)
3. Subject Keyword(s) Voronezh crystalline massif; calc-alkaline mafic rocks; U-Pb age; Sm-Nd isotope age; enriched mantle; subduction
4. Description Abstract

The Don terrane, which is extensively reworked by metamorphism and granitoid intrusions, is part of the Volga–Don orogen stretching along the eastern margin of the Sarmatian segment of the East European Craton. The terrane consists of gneiss-granites of the Pavlovsk complex, metavolcanic rocks, ranging from basaltic andesites to dacites (amphibolites and gneisses), and metasedimentary rocks (marbles and calc-silicate rocks) of the Don Group. The volcanic rocks are typically enriched in LILE and LREE and show negative HFSE anomalies, indicating fluid-assisted melting of the mantle wedge in a subduction zone. The Nd isotopic composition (εNd2200 = –1.2 to +3.4, model age 2180–2550 Ma) and Hf isotopic composition (εHf = –4.3 to +3.3, model age 2290–2640 Ma) indicate an enriched mantle or a mixed crustal–mantle source of the parental melts of the volcanics and a juvenile source for sediments of the Don Group. The U–Pb zircon metamorphic age of the gneisses and amphibolites is 2047 ± 7 Ma, and that of the thermal effect of the granitoid batholith on the host rocks is 2060 ± 4 Ma. According to isotope geochemical and geochronological data, the Don Group is underlain by Archean rocks, contains Archean detrital zircons, but the age of this group is no older than 2300 Ma. A facies and age analogue of the Don Group is the Temryuk Formation of the Central Azov Group of the Ukrainian shield. In the Paleoproterozoic, the eastern margin of Sarmatia was likely a continental arc, which was nearly coeval with the island arc–backarc basin system of the Losevo Group.

5. Publisher Organizing agency, location The Russian Academy of Sciences
6. Contributor Sponsor(s)
7. Date (DD-MM-YYYY) 15.07.2024
8. Type Status & genre Peer-reviewed Article
8. Type Type Research Article
9. Format File format
10. Identifier Uniform Resource Identifier https://journals.eco-vector.com/0016-7525/article/view/660541
10. Identifier Digital Object Identifier (DOI) 10.31857/S0016752524070042
10. Identifier eLIBRARY Document Number (EDN) IZVYVD
10. Identifier Digital Object Identifier (DOI) (PDF (Rus)) 10.31857/S0016-7525697621-643-175928
11. Source Title; vol., no. (year) Геохимия; Vol 69, No 7 (2024)
12. Language English=en ru
13. Relation Supp. Files Fig. 1. Scheme of the location of the junction zone of Sarmatia and Volga-Uralia within the East European Craton. (501KB) doi: 10.31857/S0016-7525697621-643-4270956
Fig. 2. Geological diagram of the stratotype area of ​​the Don series (west of the Volga-Don orogen). (1MB) doi: 10.31857/S0016-7525697621-643-4270958
Fig. 3. Geological sections of wells 0157 (granitoids of the Pavlovsky complex with skialites of amphibolites and gneisses of the Don series) and 6391 (Don series). (1MB) doi: 10.31857/S0016-7525697621-643-4270960
Fig. 4. Classification petrochemical diagrams for metavolcanic rocks of the Don series: SiO2–(Na2O + K2O) (LeBas et al., 1986), Zr/Ti–SiO2 (Winchester, Floyd, 1977), AFM (Irvine, Barragar, 1971) and SiO2–Fe-index (Frost, Frost, 2008). (452KB) doi: 10.31857/S0016-7525697621-643-4270961
Fig. 5. Distribution of rare and rare earth elements in the rocks of the Don series. Chondrite CI and primitive mantle according to (Sun, McDonough, 1989), upper crust according to (Rudnick, Gao 2003). (565KB) doi: 10.31857/S0016-7525697621-643-4270964
Fig. 6. Petrochemical diagrams for carbonate-bearing rocks of the Don series. (143KB) doi: 10.31857/S0016-7525697621-643-4270965
Fig. 7. Micrographs of zircon grains in the cathodoluminescence mode and diagrams with concordia for zircon from amphibolite and gneiss of the Don series (samples 0157/231-243 and 6391/282-288). The numbers of measurement sites correspond to the measurement results in Table 2. (891KB) doi: 10.31857/S0016-7525697621-643-4270967
Fig. 8. εNd(t) – Age diagram for the Don series rocks. The evolution fields of the Nd isotopic composition of the continental crust are given according to (Bibikova et al., 2009; Shchipansky et al., 2007; Savko et al., 2021; Terentiev et al., 2016, 2017). (167KB) doi: 10.31857/S0016-7525697621-643-4270970
Fig. 9. Discrimination diagrams for amphibolites of the Don series: (a) — (Cabanis et Lecolle, 1989); (b) — (Meschede, 1986); (c) — (Wood, 1980); (d) — (Hollocher et al., 2012); (d) — (Pearce, 1982). (342KB) doi: 10.31857/S0016-7525697621-643-4270974
Fig. 10. Discrimination diagrams (Zhang et al., 2017) for carbonate rocks of the Don series. (126KB) doi: 10.31857/S0016-7525697621-643-4270977
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
15. Rights Copyright and permissions Copyright (c) 2024 Russian Academy of Sciences