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Morphological features and genesis of the interpenetration twins of cubic diamond crystals

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1. Title Title of document Morphological features and genesis of the interpenetration twins of cubic diamond crystals
2. Creator Author's name, affiliation, country А. D. Pavlushin; Diamond and Precious Metal Geology Institute, Siberian Branch, Russian Academy of Sciences; Russian Federation
3. Subject Discipline(s)
3. Subject Keyword(s) chinese lantern diamond; twin germination; crystallomorphology; cuboid; microrelief of dissolution; rare forms of diamonds; tetrahexahedroid; typomorphism; spinel twinning law
4. Description Abstract

The paper presents analysis of the crystal morphology of two similarly shaped interpenetration twins of cubic crystals: the Chinese Lantern diamond (Arkhangelsk diamond mining province, provided for this study by courtesy of the ALROSA company) and a diamond crystal from Brazil, which has been studied in much detail by A.E. Fersman. Comparison of data on these diamonds, which were obtained using original methodological techniques for interpreting morphological indications of crystal growth and dissolution, revealed a number of crystal morphological features of crystals characteristic of regular accretions of this type. In addition to tetragonal pits characteristic of the cuboids, ribbon-shaped, jagged, and drop-shaped relief features typical of surface dissolution, a new type of symmetrical sawtooth microrelief associated with etching of octahedral layers of cuboid growth was discovered on the diamond from the Arkhangelsk province. In accordance with the height and direction of the steps of the relief pattern, the development sequence of the aforementioned types of microrelief is determined according to the increase in the depth of dissolution and the degree of change in the curvature of the surface of the tetrahexahedron on twin cuboids. The genesis of the characteristic equatorial sharp ridge of octahedron faces encircling the twinning plane was revealed. It is demonstrated to has been formed in relation to an early stage of the systematic coalescence of fibrous diamond cuboids and to be a determining condition of its development, first as a interpenetration twin of flat-faced octahedral crystals. Crystal morphological similarities between indications of dissolution on curved tetrahexahedra from kimberlites of the Arkhangelsk pipes and placer sources in Brazil and the north of the Yakutian diamond-bearing province is discussed.

5. Publisher Organizing agency, location The Russian Academy of Sciences
6. Contributor Sponsor(s) Government of the Russian Federation
7. Date (DD-MM-YYYY) 03.02.2025
8. Type Status & genre Peer-reviewed Article
8. Type Type Research Article
9. Format File format
10. Identifier Uniform Resource Identifier https://journals.eco-vector.com/0016-7525/article/view/683291
10. Identifier Digital Object Identifier (DOI) 10.31857/S0016752525020032
10. Identifier eLIBRARY Document Number (EDN) GPUTLD
10. Identifier Digital Object Identifier (DOI) (PDF (Rus)) 10.31857/S0016-7525702146-157-198086
11. Source Title; vol., no. (year) Геохимия; Vol 70, No 2 (2025)
12. Language English=en ru
13. Relation Supp. Files Fig. 1. Sprouting doubles of hexahedral diamond crystals: (a) the Arkhangelsk diamond “Chinese Lantern” from the collection of ALROSA; (b) the original drawing of the Brazilian diamond from the monograph (Fersmann, Goldschmidt, 1911). (181KB) doi: 10.31857/S0016-7525702146-157-4340510
Fig. 2. Schematic description of one of the Brazilian “hexahedral twin sprouting diamond crystals” with facets marked according to A.E. Fersmann (1955): arrows indicate the directions of the crystal dissolution flows; “elegant etching pits” of tetragonal shape are marked on the faces of the cube. (225KB) doi: 10.31857/S0016-7525702146-157-4340511
Fig. 3. Morphology of hexahedral twin sprouting crystals of the Arkhangelsk diamond “Chinese Lantern”: (a) photo of the diamond from the side of the common apex of twins; (b) change of the microrelief type on the convex surface of the tetrahexahedroid in the direction of the cube faces; (c) relics of ribbon-shaped relief pits raised above the surface of the tetrahexahedroid; (d) enlarged fragment of microrelief in fig. (c). (779KB) doi: 10.31857/S0016-7525702146-157-4340512
Fig. 4.Morphology of Fersman's Brazilian diamond No. 122 and the Arkhangelsk diamond: (a) morphology of the Brazilian twin grouping and the scheme of the direction of “dissolution” and “creation” flows according to (Fersman, 1955); (b) idealized model of the Brazilian diamond with deciphering of Fersman's indices and the position of facets; (c) photo of the Arkhangelsk diamond “Chinese lantern”; (d) crystallography of the twin grouping of cuboids according to A. E. Fersman and the scheme of the direction of “dissolution” and “creation” flows. E. Fersman and the scheme of the direction of dissolution flows on the diamond surface. (1MB) doi: 10.31857/S0016-7525702146-157-4340513
Fig. 5. Morphology of penetration twins of cubic diamond crystals: (a) “sharp growth ridge in equatorial notch in a beautiful twin formation”, Brazilian diamond No. 118 (Fersman, 1955); (b) penetration twin of cubic crystals with “growth ridge”, weight 5. 71 carats, Mbuzhi-Mayi (Miba) kimberlite pipe, DR Congo (photo from open source johnbetts-fineminerals.com); (c) scheme of the primary growth form of the penetration twin and correspondence of octahedron faces on it and on the “growth crest”. (1MB) doi: 10.31857/S0016-7525702146-157-4340514
Fig. 6.Types of microrelief on the surface of the Chinese Lantern diamond and interpretation of the sequence of microrelief appearance as the depth of dissolution increases and the curvature of tetrahexahedroid faces changes. Notation: 1 - ribbon-shaped relief of dissolution; 2 - toothed and drop-shaped relief of dissolution on the surface of tetrahexahedroid; 3 - tetragonal etching pits on the faces of hexahedron; 4 - sawtooth relief on the surface of tetrahexahedroid. The dotted red line indicates the correspondence of the sawtooth relief pattern to the rib shape of the octahedron. (1MB) doi: 10.31857/S0016-7525702146-157-4340515
Fig. 7. Elements of the nucleation of the sawtooth relief on the surface of the relics of a face close in position to the rhombodododecahedron (Fig. 3a). (773KB) doi: 10.31857/S0016-7525702146-157-4340516
Fig. 8. Saw-shaped microrelief of dissolution on the curved surface of tetrahexahedroid diamond from the Ebelyakh placer (Yakutia) (BSE image): (a) general view of the crystal; (b) enlarged fragment of the surface with saw-shaped microrelief. (235KB) doi: 10.31857/S0016-7525702146-157-4340517
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15. Rights Copyright and permissions Copyright (c) 2025 Russian Academy of Sciences