Indexing metadata

Copper in Hydrothermal Systems: a Thermodynamic Description of Hydroxocomplexes

Dublin Core PKP Metadata Items Metadata for this Document
1. Title Title of document Copper in Hydrothermal Systems: a Thermodynamic Description of Hydroxocomplexes
2. Creator Author's name, affiliation, country N. N. Akinfiev; Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry, Russian Academy of Sciences
2. Creator Author's name, affiliation, country A. V. Zotov; Russian State Geological Prospecting University named after S. Ordzhonikidze
3. Subject Discipline(s)
3. Subject Keyword(s) copper; complex formation; thermodynamic properties; hydrothermal process; modeling
4. Description Abstract

The experimental data available in the literature on the solubility of Cu(met.) and Cu2O (cuprite) in water under hydrothermal conditions have been processed. Key experiments were carried out on the solubility of cuprite at 300 C, saturated vapor pressure of H2O, vs. pH of the solution. As a result, a set of values of thermodynamic properties for 25°C, 1 bar and parameters of the HKF (Helgeson-Kirkham-Flowers) and AD (Akinfiev-Diamond) equation of states for Cu(I) hydroxocomplexes was obtained, which make it possible to describe their behavior in a wide range of temperatures (0 – 600 C), pressures (1 – 3000 bar) and densities of aqueous fluid (0.01 – 1 gcm–3). As it has been shown by thermodynamic modeling the Cu+ ion is prevalent in the acidic and weakly alkaline regions of the aqueous solvent over the entire temperature and pressure range studied. The effect of the neutral CuOH hydroxocomplex begins to show up in the alkaline region at T > 300 C and grows with increasing temperature. The second copper hydroxocomplex Cu(OH)2– shows up only in the strongly alkaline region, and the temperature has almost no effect on its behavior

5. Publisher Organizing agency, location The Russian Academy of Sciences
6. Contributor Sponsor(s)
7. Date (DD-MM-YYYY) 01.01.2023
8. Type Status & genre Peer-reviewed Article
8. Type Type Unknown
9. Format File format
10. Identifier Uniform Resource Identifier https://journals.eco-vector.com/0016-7770/article/view/660141
10. Identifier Digital Object Identifier (DOI) 10.31857/S0016777023010021
10. Identifier eLIBRARY Document Number (EDN) LARZSH
10. Identifier Digital Object Identifier (DOI) (PDF (Rus)) 10.31857/S0016-77706514-14-175532
11. Source Title; vol., no. (year) Геология рудных месторождений; Vol 65, No 1 (2023)
12. Language English=en
13. Relation Supp. Files (121KB) doi: 10.31857/S0016-77706514-14-4268078
(91KB) doi: 10.31857/S0016-77706514-14-4268079
(73KB) doi: 10.31857/S0016-77706514-14-4268080
(93KB) doi: 10.31857/S0016-77706514-14-4268081
(110KB) doi: 10.31857/S0016-77706514-14-4268082
(126KB) doi: 10.31857/S0016-77706514-14-4268083
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.)
15. Rights Copyright and permissions Copyright (c) 2023 Russian Academy of Sciences