Petroleum ChemistryPetroleum ChemistryНефтехимия0028-24213034-5626The Russian Academy of Sciences67740810.31857/S0028242124060016MGZVQAArticlesСтатьиReview ArticleСовременные промышленные и альтернативные методы получения алкиламиновСовременные промышленные и альтернативные методы получения алкиламиновhttps://orcid.org/0000-0001-6801-0158ДементьеваОксана Сергеевна
Russian Federation

с. н. с., к. х. н.

dementyeva@ips.ac.ruhttps://orcid.org/0009-0009-5217-5527БорисовАнтон Витальевич
Russian Federation

ст. лаборант

dementyeva@ips.ac.ruhttps://orcid.org/0000-0002-2010-5294БаженовСтепан Дмитриевич
Russian Federation

зав. лаб., к. х. н.

dementyeva@ips.ac.ruИнститут нефтехимического синтеза им. А. В. Топчиева РАНРоссийский государственный университет нефти и газа (НИУ) имени И. М. Губкина1512202464650954420032025Copyright ©; 2024, Russian Academy of SciencesCopyright ©; 2024, Российская академия наук2024Russian Academy of SciencesРоссийская академия наукhttps://journals.eco-vector.com/0028-2421/article/view/677408

В обзоре проведен анализ современной научно-технической литературы, посвященной традиционным промышленным методам и новым альтернативным способам получения аминов, в частности, алкиламинов, с применением гетерогенных и гомогенных катализаторов. Рассмотрены основные направления превращения углеродсодержащих молекул при взаимодействии с аммиаком и другими азотсодержащими соединениями в амины различной степени замещенности. Выделены основные подходы к дизайну и получению катализаторов синтеза аминов. Освещены основные проблемы альтернативных способов их производства. Продемонстрирована возможность вовлечения в синтез алкиламинов техногенного диоксида углерода как одного из компонентов комплекса технологий улавливания, утилизации и хранения углерода (carbon capture, utilization and storage — CCUS).

В обзоре проведен анализ современной научно-технической литературы, посвященной традиционным промышленным методам и новым альтернативным способам получения аминов, в частности, алкиламинов, с применением гетерогенных и гомогенных катализаторов. Рассмотрены основные направления превращения углеродсодержащих молекул при взаимодействии с аммиаком и другими азотсодержащими соединениями в амины различной степени замещенности. Выделены основные подходы к дизайну и получению катализаторов синтеза аминов. Освещены основные проблемы альтернативных способов их производства. Продемонстрирована возможность вовлечения в синтез алкиламинов техногенного диоксида углерода как одного из компонентов комплекса технологий улавливания, утилизации и хранения углерода (carbon capture, utilization and storage — CCUS).

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