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<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" article-type="research-article" dtd-version="1.2" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">Petroleum Chemistry</journal-id><journal-title-group><journal-title xml:lang="en">Petroleum Chemistry</journal-title><trans-title-group xml:lang="ru"><trans-title>Нефтехимия</trans-title></trans-title-group></journal-title-group><issn publication-format="print">0028-2421</issn><issn publication-format="electronic">3034-5626</issn><publisher><publisher-name xml:lang="en">The Russian Academy of Sciences</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="publisher-id">686755</article-id><article-id pub-id-type="doi">10.31857/S0028242125020072</article-id><article-id pub-id-type="edn">KMELKU</article-id><article-categories><subj-group subj-group-type="toc-heading" xml:lang="en"><subject>Articles</subject></subj-group><subj-group subj-group-type="toc-heading" xml:lang="ru"><subject>Статьи</subject></subj-group><subj-group subj-group-type="article-type"><subject>Research Article</subject></subj-group></article-categories><title-group><article-title xml:lang="en">Получение и фотокаталитические свойства композитных фотокатализаторов TiO<sub>2</sub>-MCM-22</article-title><trans-title-group xml:lang="ru"><trans-title>Получение и фотокаталитические свойства композитных фотокатализаторов TiO<sub>2</sub>-MCM-22</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-3574-0039</contrib-id><name><surname>Садовников</surname><given-names>Алексей Александрович</given-names></name><address><country country="RU">Russian Federation</country></address><email>sadovnikov@ips.ac.ru</email><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-3815-9565</contrib-id><name><surname>Наранов</surname><given-names>Евгений Русланович</given-names></name><address><country country="RU">Russian Federation</country></address><bio xml:lang="ru"><p>к. х. н.</p></bio><email>sadovnikov@ips.ac.ru</email><xref ref-type="aff" rid="aff3"/></contrib><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0009-0006-4139-1476</contrib-id><name><surname>Новоселова</surname><given-names>Кристина Николаевна</given-names></name><address><country country="RU">Russian Federation</country></address><email>sadovnikov@ips.ac.ru</email></contrib><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0009-0001-2744-2242</contrib-id><name><surname>Родригес Пинеда</surname><given-names>Рикардо Артурович</given-names></name><address><country country="RU">Russian Federation</country></address><email>sadovnikov@ips.ac.ru</email><xref ref-type="aff" rid="aff3"/></contrib><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0001-9297-4950</contrib-id><name><surname>Максимов</surname><given-names>Антон Львович</given-names></name><address><country country="RU">Russian Federation</country></address><bio xml:lang="ru"><p>д. х. н., академик РАН</p></bio><email>sadovnikov@ips.ac.ru</email><xref ref-type="aff" rid="aff3"/></contrib></contrib-group><aff-alternatives id="aff1"><aff><institution xml:lang="en"></institution></aff><aff><institution xml:lang="ru">Институт нефтехимического синтеза им. А. В. Топчиева РАН</institution></aff></aff-alternatives><aff-alternatives id="aff2"><aff><institution xml:lang="ru">Институт общей и неорганической химии им. Н. С. Курнакова РАН</institution></aff><aff><institution xml:lang="en"></institution></aff></aff-alternatives><aff id="aff3"><institution>Институт нефтехимического синтеза им. А. В. Топчиева РАН</institution></aff><pub-date date-type="pub" iso-8601-date="2025-04-15" publication-format="electronic"><day>15</day><month>04</month><year>2025</year></pub-date><volume>65</volume><issue>2</issue><issue-title xml:lang="en"/><issue-title xml:lang="ru"/><fpage>147</fpage><lpage>153</lpage><history><date date-type="received" iso-8601-date="2025-07-05"><day>05</day><month>07</month><year>2025</year></date><date date-type="accepted" iso-8601-date="2025-07-05"><day>05</day><month>07</month><year>2025</year></date></history><permissions><copyright-statement xml:lang="en">Copyright ©; 2025, Russian Academy of Sciences</copyright-statement><copyright-statement xml:lang="ru">Copyright ©; 2025, Российская академия наук</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="en">Russian Academy of Sciences</copyright-holder><copyright-holder xml:lang="ru">Российская академия наук</copyright-holder></permissions><self-uri xlink:href="https://journals.eco-vector.com/0028-2421/article/view/686755">https://journals.eco-vector.com/0028-2421/article/view/686755</self-uri><abstract xml:lang="ru"><p>Разработан быстрый и простой метод синтеза эффективных фотокатализаторов на основе диоксида титана и мезопористого цеолита MCM-22 из различных прекурсоров титана. Полученные фотокатализаторы были проанализированы методами рентгенофазового анализа (РФА), низкотемпературной адсорбции азота, растровой электронной микроскопии (РЭМ). Фотокаталитическая активность образцов TiO<sub>2</sub>-MCM-22 была протестирована в реакциях фотокаталитического разложения красителя кристаллического фиолетового и окисления ацетона. Наибольшую фотокаталитическую активность продемонстрировал образец с соотношением TiO<sub>2</sub><sub>-</sub>цеолит 1 : 1, полученный из тетрахлорида титана. Степень деградации кристаллического фиолетового составила 22% при УФ-облучении в течение 2 ч, а в реакции разложения ацетона активность составила 642 млн д. (выход CO<sub>2</sub>).</p></abstract><trans-abstract xml:lang="en"><p/></trans-abstract><kwd-group xml:lang="ru"><kwd>MCM-22</kwd><kwd>фотокатализ</kwd><kwd>диоксид титана</kwd><kwd>нанокомпозит</kwd></kwd-group><funding-group><funding-statement xml:lang="en">The work was carried out using the equipment of the Collective Use Center "Analytical Center for Problems of Deep Oil Refining and Petrochemistry" of the Institute of General Chemistry of the Russian Academy of Sciences. The authors express their gratitude to the Collective Use Center of Physics and Mathematics of the Institute of General Chemistry of the Russian Academy of Sciences for assistance in studying the properties of catalysts using scanning electron microscopy. Certification of the synthesized samples of heterogeneous catalysts was carried out with the financial support of the Ministry of Education and Science of the Russian Federation (Agreement No. 075-15-2021-1363).</funding-statement><funding-statement xml:lang="ru">Работа выполнена с использованием оборудования ЦКП «Аналитический центр проблем глубокой переработки нефти и нефтехимии» ИНХС РАН. Авторы выражают благодарность ЦКП ФМИ ИОНХ РАН за содействие в проведении исследований свойств катализаторов методом растровой электронной микроскопии. Аттестация синтезированных образцов гетерогенных катализаторов выполнена при финансовой поддержке Минобрнауки России (Соглашение № 075-15-2021-1363).</funding-statement></funding-group></article-meta></front><body></body><back><ref-list><ref id="B1"><label>1.</label><mixed-citation>Dong H., Zeng G., Tang L., Fan C., Zhang C., He X., He Y. An overview on limitations of <math><msub><mi>TiO</mi><mn>2</mn></msub></math>-based particles for photocatalytic degradation of organic pollutants and the corresponding countermeasures // Water Res. 2015. V. 79. P. 128–146. https://dx.doi.org/10.1016/j.watres.2015.04.038</mixed-citation></ref><ref id="B2"><label>2.</label><mixed-citation>Haghighat Mamaghani A.H., Haghighat F., Lee C.-S. Role of titanium dioxide (<math><msub><mi>TiO</mi><mn>2</mn></msub></math>) structural design/morphology in photocatalytic air purification // Appl. Catal. B: Environ. 2020. V. 269. ID118735. https://dx.doi.org/10.1016/j.apcatb.2020.118735</mixed-citation></ref><ref id="B3"><label>3.</label><mixed-citation>Ao C.H., Lee S.C. Indoor air purification by photocatalyst <math><msub><mi>TiO</mi><mn>2</mn></msub></math> immobilized on an activated carbon filter installed in an air cleaner // Chem. Eng. Sci. 2005. V. 60. № 1. P. 103–109. https://dx.doi.org/10.1016/j.ces.2004.01.073</mixed-citation></ref><ref id="B4"><label>4.</label><mixed-citation>Sadovnikov A.A., Baranchikov A.E., Zubavichus Y.V., Ivanova O.S., Murzin V.Y., Kozik V.V., Ivanov V.K. Photocatalytically active fluorinated nano-titania synthesized by microwave-assisted hydrothermal treatment // J. Photochem. Photobiol. A. 2015. V. 303–304. P. 36–43. https://dx.doi.org/10.1016/j.jphotochem.2015.01.010</mixed-citation></ref><ref id="B5"><label>5.</label><mixed-citation>Sadovnikov A.A., Naranov E.R., Maksimov A.L., Baranchikov A.E., Ivanov V.K. Photocatalytic activity of fluorinated titanium dioxide in ozone decomposition: 1 // Russ. J. Appl. Chem. 2022. V. 95, № 1. P. 118–125. https://dx.doi.org/10.1134/S1070427222010153</mixed-citation></ref><ref id="B6"><label>6.</label><mixed-citation>Rueda-Marquez J.J., Levchuk I., Fernández Ibañez P., Sillanpää M. A critical review on application of photocatalysis for toxicity reduction of real wastewaters // J. Cleaner Prod. 2020. V. 258. ID120694. https://dx.doi.org/10.1016/j.jclepro.2020.120694</mixed-citation></ref><ref id="B7"><label>7.</label><mixed-citation>Shan A.Y., Mohd. Ghazi T.I., Rashid S.A. Immobilisation of titanium dioxide onto supporting materials in heterogeneous photocatalysis: A review // Appl. Catal. A: Gen. 2010. V. 389, № 1–2. P. 1–8. https://dx.doi.org/10.1016/j.apcata.2010.08.053</mixed-citation></ref><ref id="B8"><label>8.</label><mixed-citation>Lin L., Wang H., Xu P. Immobilized <math><msub><mi>TiO</mi><mn>2</mn></msub></math>-reduced graphene oxide nanocomposites on optical fibers as high performance photocatalysts for degradation of pharmaceuticals // Chem. Eng. J. 2017. V. 310. Pt. 2. P. 389–398. https://dx.doi.org/10.1016/j.cej.2016.04.024</mixed-citation></ref><ref id="B9"><label>9.</label><mixed-citation>Tran M.L., Fu C.-C., Chiang L.-Y., Hsieh C.-T., Liu S.-H., Juang R.-S. Immobilization of <math><msub><mi>TiO</mi><mn>2</mn></msub></math> and <math><msub><mi>TiO</mi><mn>2</mn></msub></math>-GO hybrids onto the surface of acrylic acid-grafted polymeric membranes for pollutant removal: Analysis of photocatalytic activity // J. Environ. Chem. Eng. 2020. V. 8, № 5. ID104422. https://dx.doi.org/10.1016/j.jece.2020.104422</mixed-citation></ref><ref id="B10"><label>10.</label><mixed-citation>Gar Alalm M., Tawfik A., Ookawara S. Enhancement of photocatalytic activity of <math><msub><mi>TiO</mi><mn>2</mn></msub></math> by immobilization on activated carbon for degradation of pharmaceuticals // J. Environ. Chem. Eng. 2016. V. 4, № 2. P. 1929–1937. https://dx.doi.org/10.1016/j.jece.2016.03.023</mixed-citation></ref><ref id="B11"><label>11.</label><mixed-citation>Bahrudin N.N. Evaluation of degradation kinetic and photostability of immobilized <math><msub><mi>TiO</mi><mn>2</mn></msub></math>/activated carbon bilayer photocatalyst for phenol removal // Appl. Surf. Sci. Adv. 2022. V. 7. ID100208. https://dx.doi.org/10.1016/j.apsadv.2021.100208</mixed-citation></ref><ref id="B12"><label>12.</label><mixed-citation>Li F., Sun S., Jiang Y., Xia M., Sun M., Xue B. Photodegradation of an azo dye using immobilized nanoparticles of <math><msub><mi>TiO</mi><mn>2</mn></msub></math> supported by natural porous mineral // J. Hazard. Mater. 2008. V. 152, № 3. P. 1037–1044. https://dx.doi.org/10.1016/j.jhazmat.2007.07.114</mixed-citation></ref><ref id="B13"><label>13.</label><mixed-citation>de Oliveira W.V., Morais A.Í.S., Honorio L.M.C., Trigueiro P.A., Almeida L.C., Pena Garcia R.R., Viana B.C., Furtini M.B., Silva-Filho E.C., Osajima J.A. <math><msub><mi>TiO</mi><mn>2</mn></msub></math> Immobilized on Fibrous Clay as Strategies to Photocatalytic Activity // Mat. Res. 2020. V. 23. № 1. ID e20190463. https://dx.doi.org/10.1590/1980-5373-mr-2019-0463</mixed-citation></ref><ref id="B14"><label>14.</label><mixed-citation>Yu J.C., Wang X., Fu X. Pore-Wall Chemistry and Photocatalytic Activity of Mesoporous Titania Molecular Sieve Films // Chem. Mater. 2004. V. 16, № 8. P. 1523–1530. https://dx.doi.org/10.1021/cm049955x</mixed-citation></ref><ref id="B15"><label>15.</label><mixed-citation>Younis S.A., Amdeha E., El-Salamony R.A. Enhanced removal of p-nitrophenol by β-<math><msub><mi>Ga</mi><mn>2</mn></msub><msub><mi>O</mi><mn>3</mn></msub></math>-<math><msub><mi>TiO</mi><mn>2</mn></msub></math> photocatalyst immobilized onto rice straw-based <math><msub><mi>SiO</mi><mn>2</mn></msub></math> via factorial optimization of the synergy between adsorption and photocatalysis // J. Environ. Chem. Eng. 2021. V. 9, № 1. ID104619. https://dx.doi.org/10.1016/j.jece.2020.104619</mixed-citation></ref><ref id="B16"><label>16.</label><mixed-citation>Wang B., Zhang G., Sun Z., Zheng S. Synthesis of natural porous minerals supported <math><msub><mi>TiO</mi><mn>2</mn></msub></math> nanoparticles and their photocatalytic performance towards Rhodamine B degradation // Powder Technol. 2014. V. 262. P. 1–8. https://dx.doi.org/10.1016/j.powtec.2014.04.050</mixed-citation></ref><ref id="B17"><label>17.</label><mixed-citation>Jansson I., Suárez S., Garcia-Garcia F.J., Sánchez B. Zeolite–<math><msub><mi>TiO</mi><mn>2</mn></msub></math> hybrid composites for pollutant degradation in gas phase // Appl. Catal. B: Environ. 2015. V. 178. P. 100–107. https://dx.doi.org/10.1016/j.apcatb.2014.10.022</mixed-citation></ref><ref id="B18"><label>18.</label><mixed-citation>Hu G., Yang J., Duan X., Farnood R., Yang C., Yang J., Liu W., Liu Q. Recent developments and challenges in zeolite-based composite photocatalysts for environmental applications // Chem. Eng. J. 2021. V. 417. ID129209. https://dx.doi.org/10.1016/j.cej.2021.129209</mixed-citation></ref><ref id="B19"><label>19.</label><mixed-citation>Kovalevskiy N.S., Lyulyukin M.N., Selishchev D.S., Kozlov D.V. Analysis of air photocatalytic purification using a total hazard index: Effect of the composite TiO2/zeolite photocatalyst // J. Hazard. Mater. 2018. V. 358. P. 302–309. https://dx.doi.org/10.1016/j.jhazmat.2018.06.035</mixed-citation></ref><ref id="B20"><label>20.</label><mixed-citation>Jiang N., Shang R., Heijman S.G.J., Rietveld L.C. High-silica zeolites for adsorption of organic micro-pollutants in water treatment: A review // Water Res. 2018. V. 144. P. 145–161. https://dx.doi.org/10.1016/j.watres.2018.07.017</mixed-citation></ref><ref id="B21"><label>21.</label><mixed-citation>Corma A., Corell C., Pérez-Pariente J. Synthesis and characterization of the MCM-22 zeolite // Zeolites. 1995. V. 15, № 1. P. 2–8. https://dx.doi.org/10.1016/0144-2449(94)00013-I</mixed-citation></ref><ref id="B22"><label>22.</label><mixed-citation>Sadovnikov A.A., Nechaev E.G., Beltiukov A.N., Gavrilov A.I., Makarevich A.M., Boytsova O.V. Titania mesocrystals: working surface in photocatalytic reactions // Russ. J. Inorg. Chem. 2021. V. 66, № 4. P. 460–467. https://dx.doi.org/10.1134/S0036023621040197</mixed-citation></ref><ref id="B23"><label>23.</label><mixed-citation>Садовников А.А., Новоселова К.Н., Судьин В.В., Наранов Е.Р. Влияние аниона аммиачного комплекса серебра на активность сформированных in situ Ag/<math><msub><mi>TiO</mi><mn>2</mn></msub></math>-катализаторов // Нефтехимия. 2024. Т. 64, № 5. С. 491–498. https://dx.doi.org/10.31857/S0028242124050077</mixed-citation></ref></ref-list></back></article>
