Petroleum ChemistryPetroleum ChemistryНефтехимия0028-24213034-5626The Russian Academy of Sciences69342110.31857/S0028242125040014ArticlesСтатьиResearch ArticleЗамещенные цеолиты ZSM‑22: Сравнение физико-химических и каталитических свойств (обзор)Замещенные цеолиты ZSM‑22: Сравнение физико-химических и каталитических свойств (обзор)OstroumovaV. A.ОстроумоваВ. А.ostroumova@ips.ac.ruInstitute of Petrochemical Synthesis named after A. V. Topchieva of RASИнститут нефтехимического синтеза им. А. В. Топчиева РАН15082025654VOL 65, NO4 (2025)ТОМ 65, №4 (2025)25128215102025Copyright ©; 2025, Russian Academy of SciencesCopyright ©; 2025, Российская академия наук2025Russian Academy of SciencesРоссийская академия наукhttps://journals.eco-vector.com/0028-2421/article/view/693421

In this review, a comparative analysis of the literature on the synthesis, physicochemical, and catalytic properties of substituted ZSM-22 zeolites is presented. The physicochemical characteristics of Ce, Fe, Ga, B, and V substituted ZSM-22 samples are compared with those of the parent analog based on X-ray phase analysis, transmission electron microscopy, scanning electron microscopy, low-temperature nitrogen adsorption-desorption, FTIR spectroscopy of adsorbed pyridine, UV spectroscopy, X-ray photoelectron spectroscopy, temperature-programmed desorption of ammonia, and others. The possibility of using substituted ZSM-22 zeolites in the reactions of hydroisomerization of long-chain hydrocarbons, isomerization of butenes, methanol conversion to olefins, decomposition of nitrous oxide, disproportionation of ethylbenzene, and hydroxylation of arenes to phenols is demonstrated.

В обзоре проведен сравнительный анализ литературы по синтезу, физико-химическим и каталитическим свойствам замещенных цеолитов ZSM-22. Физико-химические характеристики Ce-, Fe-, Ga-, B- и V-замещенных образцов цеолитов ZSM-22 сравнены с характеристиками исходного аналога (на основании рентгенофазового анализа, просвечивающей электронной микроскопии, сканирующей электронной микроскопии, низкотемпературной адсорбции–десорбции азота, ИК-спектроскопии адсорбированного пиридина, УФ-спектроскопии, рентгенофазовой электронной спектроскопии, термопрограммируемой десорбции аммиака и др.). Показана возможность использования замещенных цеолитов ZSM-22 в реакциях гидроизомеризации длинноцепочечных углеводородов, изомеризации бутенов, превращения метанола в олефины, разложения закиси азота, диспропорционирования этилбензола и гидроксилирования аренов до фенолов.

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