| Dublin Core |
PKP Metadata Items |
Metadata for this Document |
| 1. |
Title |
Title of document |
Synthesis of N-Substituted Morpholine C60-Fullerene Adducts in the Presence of LiOH and Lead(IV) Acetate |
| 2. |
Creator |
Author's name, affiliation, country |
Z. S Kinzyabaeva; Institute of Petrochemistry and Catalysis, Ufa Federal Research Center of the Russian Academy of Sciences |
| 2. |
Creator |
Author's name, affiliation, country |
Z. N Fazletdinova; Institute of Petrochemistry and Catalysis, Ufa Federal Research Center of the Russian Academy of Sciences |
| 3. |
Subject |
Discipline(s) |
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| 3. |
Subject |
Keyword(s) |
C<sub>60</sub> fullerene; amino alcohols; lead (IV) acetate; oxidation |
| 4. |
Description |
Abstract |
A N -phenyl-substituted morpholine adduct of C60 fullerene, 1,9-[4′-phenylmorpholine]-1,9-dihydro-(C60-Ih) [5,6]fullerene, was obtained for the first time with a yield of 56% in the reaction of 2-phenylaminoethanol with fullerene in the presence of LiOH and Pb(OAc)4 at room temperature for 1 h. The amino alcohol with an electron donor group (2-methylaminoethanol) in the reaction with fullerene showed a higher reactivity: the product 1,9-[4′-methylmorpholine]-1,9-dihydro-(С60-Ih)[5,6]fullerene was isolated in 68% yield. The presence of electron-withdrawing groups at the α- or β-carbon atom relative to the nitrogen atom in amino alcohols [carboxylic (2-amino-3-hydroxypropanoic acid, serine) or carbonyl (aminoacetic acid) groups] does not contribute to the reactions with fullerene under the studied conditions. |
| 5. |
Publisher |
Organizing agency, location |
ФИЦ КазНЦ РАН |
| 6. |
Contributor |
Sponsor(s) |
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| 7. |
Date |
(DD-MM-YYYY) |
15.07.2023
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| 8. |
Type |
Status & genre |
Peer-reviewed Article |
| 8. |
Type |
Type |
Research Article |
| 9. |
Format |
File format |
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| 10. |
Identifier |
Uniform Resource Identifier |
https://journals.eco-vector.com/0044-460X/article/view/666922 |
| 10. |
Identifier |
Digital Object Identifier (DOI) |
10.31857/S0044460X23070028 |
| 10. |
Identifier |
eLIBRARY Document Number (EDN) |
HFECZI |
| 11. |
Source |
Title; vol., no. (year) |
Žurnal obŝej himii; Vol 93, No 7 (2023) |
| 12. |
Language |
English=en |
ru |
| 13. |
Relation |
Supp. Files |
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| 14. |
Coverage |
Geo-spatial location, chronological period, research sample (gender, age, etc.) |
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| 15. |
Rights |
Copyright and permissions |
Copyright (c) 2023 Russian Academy of Sciences
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