Template Synthesis of the Trinuclear Cobalt(III) Complex with Diarylimidazole-Based Ligands: Synthesis and Properties
| Dublin Core | PKP Metadata Items | Metadata for this Document | |
| 1. | Title | Title of document | Template Synthesis of the Trinuclear Cobalt(III) Complex with Diarylimidazole-Based Ligands: Synthesis and Properties |
| 2. | Creator | Author's name, affiliation, country | I. A. Nikovskii; Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia; Bauman State Technical University, Moscow, Russia |
| 2. | Creator | Author's name, affiliation, country | K. M. Karnaukh; University of California, 93106, Santa Barbara, California, USA |
| 2. | Creator | Author's name, affiliation, country | T. M. Aliev; Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia |
| 2. | Creator | Author's name, affiliation, country | A. V. Polezhaev; Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia; Bauman State Technical University, Moscow, Russia |
| 2. | Creator | Author's name, affiliation, country | K. A. Spiridonov; Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia; Moscow State University, Moscow, Russia |
| 2. | Creator | Author's name, affiliation, country | A. A. Dan’shina; Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia; Moscow Institute of Physics and Technology (National Research University), Dolgoprudnyi, Moscow oblast, Russia |
| 2. | Creator | Author's name, affiliation, country | Yu. V. Nelyubina; Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia; Bauman State Technical University, Moscow, Russia |
| 2. | Creator | Author's name, affiliation, country | V. V. Novikov; Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia; Bauman State Technical University, Moscow, Russia |
| 3. | Subject | Discipline(s) | |
| 3. | Subject | Keyword(s) | polynuclear cobalt complexes; redox-active ligands; XRD; cyclic voltammetry; UV-VIS spectroscopy |
| 4. | Description | Abstract | The trinuclear cobalt(III) complex [(Bipy)5Co3(L)2](Cl)3 (I) is synthesized by the template reaction of 2,2'-(1H-imidazole-4,5-diyl)bis(4-ethylphenol) (L) and bis(2,2-bipyridine)cobalt(II) dichloride in the presence of diazabicycloundecene. The complex is isolated in the individual state and characterized by elemental analysis, cyclic voltammetry, UV-VIS spectroscopy, and X-ray diffraction (XRD) (CIF file СCDC no. 2201135). According to the obtained data, the cobalt ions in trinuclear complex I have the oxidation state +3, and the complex formation occurs with the oxidation of the initial cobalt(II) ions. |
| 5. | Publisher | Organizing agency, location | The Russian Academy of Sciences |
| 6. | Contributor | Sponsor(s) |
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| 7. | Date | (DD-MM-YYYY) | 01.06.2023 |
| 8. | Type | Status & genre | Peer-reviewed Article |
| 8. | Type | Type | Unknown |
| 9. | Format | File format | |
| 10. | Identifier | Uniform Resource Identifier | https://journals.eco-vector.com/0132-344X/article/view/667505 |
| 10. | Identifier | Digital Object Identifier (DOI) | 10.31857/S0132344X23700238 |
| 10. | Identifier | eLIBRARY Document Number (EDN) | POVWLR |
| 11. | Source | Title; vol., no. (year) | Koordinacionnaâ himiâ; Vol 49, No 6 (2023) |
| 12. | Language | English=en | |
| 13. | Relation | Supp. Files |
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| 14. | Coverage | Geo-spatial location, chronological period, research sample (gender, age, etc.) | |
| 15. | Rights | Copyright and permissions |
Copyright (c) 2023 И.А. Никовский, К.М. Карнаух, Т.М. Алиев, А.В. Полежаев, К.А. Спиридонов, А.А. Даньшина, Ю.В. Нелюбина, В.В. Новиков |