Adducts of Sterically Hindered Tellurium Catecholate with N-Methylpyrrolidone
| Dublin Core | PKP Metadata Items | Metadata for this Document | |
| 1. | Title | Title of document | Adducts of Sterically Hindered Tellurium Catecholate with N-Methylpyrrolidone |
| 2. | Creator | Author's name, affiliation, country | P. A. Petrov; Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences; Russian Federation |
| 2. | Creator | Author's name, affiliation, country | E. A. Filippova; Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences; Russian Federation |
| 2. | Creator | Author's name, affiliation, country | T. S. Sukhikh; Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences; Russian Federation |
| 3. | Subject | Discipline(s) | |
| 3. | Subject | Keyword(s) | tellurium; quinones; XRD; N-methylpyrrolidone; NMR |
| 4. | Description | Abstract | The formation of adducts of tellurium(IV) 3,6-di-tert-butyl catecholate (Te(Cat36)2) with N-methylpyrrolidone (NMP) is studied. The crystallization from a CH2Cl2–NMP–aromatic hydrocarbon mixture is found to result in the formation of dimeric complexes [{Te(Cat36)2}2(μ-NMP)(μ-arene)] (arene = C6H6, C7H8), whereas mononuclear [Te(Cat36)2(NMP)2] is formed from a CH2Cl2–NMP–alkane mixture. The formation of the adducts with aromatic hydrocarbons indicates a possibility of using the tellurium complexes for the separation of hydrocarbon mixtures, including an industrially important benzene–cyclohexane mixture. |
| 5. | Publisher | Organizing agency, location | The Russian Academy of Sciences |
| 6. | Contributor | Sponsor(s) |
Ministry of Science and Higher Education of the Russian Federation (121031700313-8) |
| 7. | Date | (DD-MM-YYYY) | 15.10.2024 |
| 8. | Type | Status & genre | Peer-reviewed Article |
| 8. | Type | Type | Research Article |
| 9. | Format | File format | |
| 10. | Identifier | Uniform Resource Identifier | https://journals.eco-vector.com/0132-344X/article/view/667654 |
| 10. | Identifier | Digital Object Identifier (DOI) | 10.31857/S0132344X24100033 |
| 10. | Identifier | eLIBRARY Document Number (EDN) | LPWAYK |
| 11. | Source | Title; vol., no. (year) | Koordinacionnaâ himiâ; Vol 50, No 10 (2024) |
| 12. | Language | English=en | ru |
| 13. | Relation | Supp. Files |
Scheme 1 (76KB) Fig. 1. Molecular structures of complexes I (a), II (b), III (c) (thermal ellipsoids of 30% probability; H atoms are not shown) (551KB) |
| 14. | Coverage | Geo-spatial location, chronological period, research sample (gender, age, etc.) | |
| 15. | Rights | Copyright and permissions |
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