Intercalation of saponite-containing material (SCM) by electrolyte solutions as an effective method of ceramics fire shrinkage reducing
- Authors: Klipa V.V.1, Danilov V.E.1, Ayzenshtadt A.M.1, Frolova M.A.1
-
Affiliations:
- Northern (Arctic) Federal University (NAFU) named after M.V. Lomonosov
- Issue: No 3 (2026)
- Pages: 77-82
- Section: Статьи
- URL: https://journals.eco-vector.com/0585-430X/article/view/705356
- DOI: https://doi.org/10.31659/0585-430X-2026-844-3-77-82
- ID: 705356
Cite item
Abstract
Currently, saponite is widely applied in various industries. However, at present this mineral usage conditions are related to a polymineral system with saponite content level of up to 60-65%. Thus, saponite-containing material (SCM) extracted from a recycled water suspension at kimberlite ores enrichment is one of by-products of mining. But to achieve the necessary properties in terms of designed products (including ceramic products), preliminary physico-chemical treatment of SCM is almost always required. Natural saponite contains a significant amount of bound water, which removal at elevated temperatures leads to the mineral basal interlayer compression, the material shrinkage and the microcracks formation. Based on it, the work purpose was to evaluate prospects of using the intercalation with electrolyte solutions as a method of saponite-containing material modification, to minimize fire shrinkage.
About the authors
V. V. Klipa
Northern (Arctic) Federal University (NAFU) named after M.V. Lomonosov
Author for correspondence.
Email: klipavadim97@gmail.com
Postgraduate Student
Russian Federation, 22, Severnaya Dvina Embankment, Arkhangelsk, 163002V. E. Danilov
Northern (Arctic) Federal University (NAFU) named after M.V. Lomonosov
Email: v.danilov@narfu.ru
Candidate of Science (Engineering)
Russian Federation, 22, Severnaya Dvina Embankment, Arkhangelsk, 163002A. M. Ayzenshtadt
Northern (Arctic) Federal University (NAFU) named after M.V. Lomonosov
Email: a.isenshtadt@narfu.ru
Doctor of Science (Chemistry)
Russian Federation, 22, Severnaya Dvina Embankment, Arkhangelsk, 163002M. A. Frolova
Northern (Arctic) Federal University (NAFU) named after M.V. Lomonosov
Email: m.aizenstadt@narfu.ru
Candidate of Science (Chemistry)
Russian Federation, 22, Severnaya Dvina Embankment, Arkhangelsk, 163002References
- Shpilevaya (Verzhak) D.V., Garanin K.V. Diamond deposits of the Arkhangelsk region and environmental problems of their development. Vestnik of Moscow University. Series 4: Geology. 2005. No. 6, pp. 18–26. (In Russian). EDN: HTXTGP
- Morozova M.V., Aizenshtadt A.M., Frolova M.A., Makhova T.A. Use of saponite-containing waste as a component of dry construction mix for fine-grained concrete with improved performance characteristics. Academia. Architektura i Stroitel’stvo. 2015. No. 4, pp. 137–141. (In Russian). EDN: VCNHYR
- Savonenkov V.G., Anderson E.B., Shabalev S.I. Gliny kak geologicheskaya sreda dlya izolyatsii radioaktivnykh otkhodov [Clays as a geological environment for the isolation of radioactive waste]. St. Petersburg: Rosatom. 2012. 215 p.
- Zubkova O.S., Pyagai I.N., Pankratieva K.A., Toropchina M.A. Development of the composition and study of the properties of a sorbent based on saponite. Zapiski Gornogo Instituta. 2023. Vol. 259, pp. 21–29. (In Russian). EDN: ICCFLN. https://doi.org/10.31897/PMI.2023.1
- Nakvasina E.N., Romanov E.M., Shabanova E.N., Kosareva E.N., Kononov O.D. The use of saponite-containing materials as a mineral fertilizer when growing potatoes in the Arkhangelsk region. Vestnik of KrasGAU. 2019. No. 1 (142), pp. 60–68. (In Russian). EDN: VVZBQK
- Drozdyuk T.A., Ayzenshtadt A.M., Korolev E.V. High-temperature modification of saponite-containing material. Stroitel’nye Materialy [Construction Materials]. 2021. No. 11, pp. 30–35. (In Russian). EDN: CTPPCM. https://doi.org/10.31659/0585-430X-2021-797-11-30-35
- Danilov V.E., Aizenshtadt A.M., Drozdyuk T.A., Frolova M.A., Garamov G.A. Intercalation of saponite from electrolyte solutions differing in the nature of the cation. Fizika i Khimiya Obrabotki Materialov. 2024. No. 2, pp. 36–46. (In Russian). EDN: SUMGKR. https://doi.org/10.30791/0015-3214-2024-2-36-46
- Ogorodova L.P., Kiseleva I.A., Melchakova L.V., Vigasina M.F., Krupskaya V.V., Sudyin V.V. Calorimetric determination of the enthalpy of formation of natural saponite. Geokhimiya. 2015. No. 7, pp. 617–623. (In Russian). EDN: TXUGRJ. https://doi.org/10.7868/S0016752515070079
- Zhang et al. Metal occupancy and its influence on thermal stability of synthetic saponites. Applied Clay Science. 2017. Vol. 135, pp. 282–288. https://doi.org/10.1016/j.clay.2016.10.006
- Kloprogge J.T., Ponce C.P. Spectroscopic studies of synthetic and natural saponites: a review. Minerals. 2021. Vol. 11 (2). 112. EDN: KPFAIQ. https://doi.org/10.3390/min11020112
- Kloprogge J.T., Frost R.L. The effect of temperature synthesis on the FT-Raman and FT-IR spectra of saponites. Vibrational Spectroscopy. 2000. Vol. 23. Iss. 1, pp. 119–127. EDN: AEHUDM. https://doi.org/10.1016/S0924-2031(00)00056-4
- Roberts Blukis, Maria Schindler, Thaïs Couasnon, Liane G. Benning mechanism and control of saponite synthesis from a self-assembling nanocrystalline precursor. Langmuir. 2022. Vol. 38.No. 25, pp. 7678–7688. EDN: CODHWC. https://doi.org/10.1021/acs.langmuir.2c00425
- Ponce C.P., Kloprogge J.T. Urea-assisted synthesis and characterization of saponite with different octahedral (Mg, Zn, Ni, Co) and tetrahedral metals (Al, Ga, B), a review. Life (Basel). 2020. Vol. 10. No. 9. 168. EDN: PTONVJ. https://doi.org/10.3390/life10090168
- Mamontov V.G., Belyaeva S.A., Shmakova K.A. IR absorption spectra of particle size distribution fractions of typical virgin chernozem in Kursk region. Vestnik of the Timiryazev Agricultural Academy. 2023. No. 4, pp. 5–19. (In Russian). EDN: TIZJIF. https://doi.org/10.26897/0021-342X-2023-4-5-19
- Bishop J., Madeová J., Komadel P., Fröschl H. The influence of structural Fe, Al, and Mg on the infrared OH bands in the spectrum of dioctahedral smectites. Clay Minerals. 2002. Vol. 37, pp. 607–616. EDN: LQBLFP. https://doi.org/10.1180/0009855023740063
- Aizenshtadt A.M., Korolev E.V., Malygina M.A., Drozdyuk T.A., Frolova M.A. Structural modification of highly dispersed powders of overburden rocks of saponite-containing bentonite clay. Fizika i Khimiya Obrabotki Materialov. 2023. No. 1, pp. 56–63. (In Russian). EDN: BGBWRA. https://doi.org/10.30791/0015-3214-2023-1-56-63
- Ayzenshtadt A.M., Frolova M.A., Danilov V.E., Drozdyuk T.A., Malygina M.A. Modification transformations of saponite-containing material during mechanical grinding. Stroitel’nye Materialy [Construction Materials]. 2023. No. 7, pp. 54–59. (In Russian). EDN: QWPMZV. https://doi.org/10.31659/0585-430X-2023-815-7-54-59
Supplementary files
