Доклады Академии наукДоклады Академии наук0869-5652The Russian Academy of Sciences1342510.31857/S0869-56524862189-192Research ArticleOne-step and selective approach to silicon-containing exo-norbornenesGusevaM. A.bmv@ips.ac.ruBermeshevaE. V.bmv@ips.ac.ruChapalaP. P.bmv@ips.ac.ruBermeshevM. V.bmv@ips.ac.ruA.V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of SciencesMIREA - Russian Technological UniversityFirst Sechenov Moscow State Medical University under Ministry of Health of the Russian Federation2705201948621891921406201914062019Copyright © 2019, Russian academy of sciences2019<p>One-step and selective approach to the synthesis of Si-containing exo-norbornenes has been developed based on hydrosilylation reaction of norbornadiene-2,5 with unactivated silanes using Pd-complexes in the presence of bulky ligands. This approach leads to only exo-isomers of norbornene derivatives. The absence of alkylation step by organometallic compounds or photochemical isomerization makes the suggested approach promising for the synthesis of new polymeric materials with desired properties.</p>norbornadiene-2,5 hydrosilylationPd-catalystspolynorbornenesнорборнадиен-2,5гидросилилированиеPd-катализаторыполинорборнены[Alentiev D. A., Egorova E. S., Bermeshev M. V., Starannikova L. E., Topchiy M. A., Asachenko A. F., Gribanov P. S., Nechaev M. S., Yampolskii Y. P., Finkelshtein E. S. // J. Materials Chem. 2018. V. 6. № 40. Р. 19 393-19 408. DOI: 10.1039/c8ta06034g][Sundell B. J., Lawrence Iii J.A., Harrigan D. J., Vaughn J. T., Pilyugina T. S., Smith D. R. // Rsc. Adv. 2016. V. 6. № 57. Р. 51619-51628. DOI: 10.1039/c6ra10383a][Grove N. R., Kohl P. A., Bidstrup Allen S. A., Jayaraman S., Shick R. // J. Polym. Sci., Pt B: Polym. Phys. 1999. V. 37. № 21. Р. 3003-3010. DOI: 10.1002/(sici)1099-0488(19991101)37:21<3003:: aid-polb10>3.0.co;2-t][Chapala P. P., Bermeshev M. V., Gavrilova N. N. // Polym. Sci. Ser. A. 2017. V. 59. № 1. Р. 143-148. DOI: 10.1134/s0965545x17010035][Tsai S. D., Register R. A. // Macromol. Chem. Phys. 2018. V. 219. № 11. 1800059. DOI: doi:10.1002/macp.201800059][Alentiev D. A., Bermeshev M. V., Starannikova L. E., Bermesheva E. V., Shantarovich V. P., Bekeshev V. G., Yampolskii Y. P., Finkelshtein E. S. // J. Polym. Sci. Pt A: Polym. Chem. 2018. V. 56. № 12. Р. 1234-1248. DOI: 10.1002/pola.29003][Petrov V. A., Vasil’ev N.V. // Curr. Org. Synth. 2006. V. 3. Р. 215-259. DOI: 10.2174/157017906776819204][Bermeshev M., Chapala P., Lakhtin V., Genaev A., Filatova M., Peregudov A., Utegenov K., Ustynyuk N., Finkelshtein E. // Silicon. 2015. V. 7. Р. 117-126. DOI: 10.1007/s12633-014-9263-6][Kuivila H. G., Warner C. R. // J. Org. Chem. 1964. V. 29. № 10. Р. 2845-2851. DOI: 10.1021/jo01033a008]