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Osumilite-bearing lavas of the Keli highlands (Greater Caucasus): petrological and geochemical characteristics, mineral composition and conditions of magmatic melts formation

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1. Título Título do documento Osumilite-bearing lavas of the Keli highlands (Greater Caucasus): petrological and geochemical characteristics, mineral composition and conditions of magmatic melts formation
2. Autor principal Autor, estabelecimento, país Е. Kaigorodova; Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry of the Russian Academy of Sciences; Rússia
2. Autor principal Autor, estabelecimento, país V. Lebedev; Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry of the Russian Academy of Sciences; Rússia
2. Autor principal Autor, estabelecimento, país P. Kartashov; Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry of the Russian Academy of Sciences; Rússia
2. Autor principal Autor, estabelecimento, país E. Kovalchuk; Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry of the Russian Academy of Sciences; Rússia
2. Autor principal Autor, estabelecimento, país A. Chugaev; Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry of the Russian Academy of Sciences; Rússia
3. Assunto Disciplinas
3. Assunto Palavras-chave Greater Caucasus; Keli Highland; Quaternary magmatism; dacites; osumilite-(Mg); ring silicates; milarite group; mineral composition; geothermobarometry; petrogenesis
4. Descrição Resumo

Comprehensive petrological, geochemical and mineralogical studies of osumilite-bearing andesite-dacitic lavas of the volcano Kordieritoviy (Keli Highland, Greater Caucasus), erupted at the end of the Pleistocene (about 200 Ka), were carried out. The results of petrographic study of thin sections and microprobe analysis showed that the rocks contain three paragenetic mineral associations: (1) “xenogenic” (metamorphogenic) – garnet (XPrp = 0.42, XAlm = 0.51–0.53, XGrs = 0.04–0.05) + hercynite + sapphire + bronzite + pargasite + ilmenite; (2) early magmatic – hypersthene + hercynite + garnet (XPrp = 0.21–0.31, XAlm = 0.52–0.71, XGrs = 0.04–0.13) + ferro-kersutite + ilmenite; (3) late magmatic – hypersthene-ferrohypersthene + labradorite + garnet (XPrp = 0.04–0.14, XAlm = 0.65–0.81, XGrs = 0.06–0.18) + osumilite-(Mg) + phlogopite + tridymite + ilmenite + apatite. Osumilite-(Mg) (phenocrysts, xenomorphic aggregates in the rock matrix and crystals in miarolic cavities), the average formula of which for dacites of the Kordieritoviy volcano can be written as (K0.73Na0.06Ca0.020.20)1.00(Mg1.06Fe2+0.90Mn0.04)2.00(Al2.75Fe2+0.18Fe3+0.06Ti0.01)3.00(Si10.34Al1.66)12O30, formed mainly at late magmatic stages – in intermediate chambers immediately before the rise of the melt to the surface or after its eruption. Accordingly, this mineral in the studied lavas has purely magmatic origin. Thermobarometric calculations and petrological modeling showed that the deep magma chamber of the Kordieritoviy volcano was located at a level of 45–53 km from the surface in near the Moho boundary. The temperature of the melt at the early magmatic stage was no less than 1100°C at 17–23 kbar. Crystallization of osumilite-(Mg) in intermediate magmatic chambers (at depths of 30–40 km) and during the process of lava outpouring occurred at 1030–870°C and pressure progressively decreasing from 14–9 to 1 kbar. A petrogenetic model has been proposed to explain the reasons for the formation of exotic osumilite-containing lavas of the Kordieritoviy volcano. Its main provisions include: (1) enriched upper mantle source (lithospheric mantle metasomatized as a result of permanent interaction at the Moho boundary with the overlying lower crust composed of metamorphosed terrigenous-volcanogenic formations); (2) generation of “dry” basaltic magmas in the source; (3) crystallization differentiation in the source (fractionation of olivine and chrome spinels) with the formation of a “dry” superheated andesitic melt; (4) limited-scale assimilation by highly differentiated andesitic melts rising to the surface of the material of the lower crust, directly below the volcano, composed of leucocratic granulites, with simultaneous fractionation of garnet, orthopyroxene and ilmenite from the melt.

5. Editor Organizador, cidade The Russian Academy of Sciences
6. Contributor Patrocinadores
7. Data (DD-MM-AAAA) 06.12.2024
8. Tipo Tipo ou gênero da pesquisa Artigo avaliado por pares
8. Tipo Tipo Artigo científico
9. Formato Formato do arquivo
10. Identificador Identificador universal, URI https://journals.eco-vector.com/0869-5903/article/view/657773
10. Identificador Digital Object Identifier (DOI) 10.31857/S0869590324050026
10. Identificador eLIBRARY Document Number (EDN) ALTCCZ
10. Identificador Digital Object Identifier (DOI) (PDF (Rus)) 10.31857/S0869-5903325552-585-173158
11. Fonte Revista/Conferêcia, tomo, número (ano) Петрология; Volume 32, Nº 5 (2024)
12. Língua Russian=ru, English=en ru
13. Relação Arquivos suplementares Fig. 1. Map of the manifestations of Quaternary volcanism in the Kelsky Highlands (Greater Caucasus) according to data (Lebedev et al., 2011). Stratigraphic dissection of basement rocks by (Mosar et al., 2022). 1 – volcanites of the III (Late Pleistocene–Holocene) phase of activity; 2 – volcanites of the II (Late Pleistocene) phase of activity; 3 – volcanites of the I (Middle Pleistocene) phase of activity; 4 – Quaternary lavas of the Kazbek and Kabardzhin volcanoes; 5-16 – sedimentary basement rocks (5-9 – Cretaceous, 10-16 – Jurassic): 5 – Dgnali formation, terrigenous siliceous turbidites; 6 – Pasanauri formation, terrigenous siliceous turbidites; 7 – Bahani formation, mudstones, siliceous and calcareous turbidites; 8 – Edisi formation, mudstones, siliceous and calcareous turbidites; 9 – the Mleti formation, mudstones, siliceous and calcareous turbidites; 10 – the Tsipori formation, limestones, calcareous turbidites; 11 – the Dumatsho formation, limestones, clay limestones, calcareous clays, 12 – the Kazari formation, clastic calcareous turbidites; 13 – the Narvan formation, clastic calcareous turbidites, rarely siliceous turbidites; 14 – Shevardenskaya formation, clay shales, rarely terrigenous siliceous turbidites, sometimes sandy limestones; 15 – Busarchil formation, clay shales, siliceous terrigenous turbidites, sandstones; 16 – Gudushaur formation, clay shales, siltstones, terrigenous siliceous turbidites; 17 – volcanic apparatuses: a – stratovolcanoes and extrusive domes; b – slag cones; c – lava volcanoes; 18 – tectonic structures: a – thrusts, b – axes of large folds. (624KB) doi: 10.31857/S0869-5903325552-585-4259330
Fig. 2. View of the Cordierite volcano and the Patara-Nepiskalo volcanic massif from the Gudauri village area (photo by V.A. Lebedev). (267KB) doi: 10.31857/S0869-5903325552-585-4259331
Fig. 3. The main petrographic differences of the rocks of the Cordierite volcano. (a) gray garnet–containing orthopyroxene andesites-dacites, (b) pink osmylite-containing orthopyroxene dacites, (c) gray-pink osmylite-garnet-containing orthopyroxene dacites. (675KB) doi: 10.31857/S0869-5903325552-585-4259332
Fig. 4. Classification diagrams for the studied rocks of the Cordierite volcano. The gray color indicates the rock field of the Kel volcanic center according to the data (Lebedev et al., 2011). (a) TAS (Le Bas et al., 1986), (b) SiO2–K2O (Peccerillo, Taylor, 1976), (c) AFM (Irvine, Baragar, 1971), (d) Na2O–K2O (Middlemost, 1975), (e) A/CNK–A/NK (Shand, 1943). (364KB) doi: 10.31857/S0869-5903325552-585-4259333
Fig. 5. Distribution spectra of trace elements and REE in the studied igneous rocks of the Cordierite volcano, normalized with respect to the chondrite reservoir (a) and to the average composition of the primitive mantle (PM) (b). Data for normalization from (Sun, McDonough, 1989). (161KB) doi: 10.31857/S0869-5903325552-585-4259334
Fig. 6. Isotope diagrams of eNd–87Sr/86Sr (a) and 206Pb/204Pb–207Pb/204Pb (b) for lavas of the Cordierite volcano, the Kel volcanic center and other young magmatic formations of the Greater Caucasus. The author's and literary data were used in the construction (Lebedev, Vashakidze, 2014; Parfenov et al., 2019; Chugaev et al., 2013; Bewick, 2016). (293KB) doi: 10.31857/S0869-5903325552-585-4259335
Fig. 7. Some features of the mineral composition of dacites of the Cordierite volcano (micrographs of transparent sections, mod. KE-81A). Hereafter, the abbreviation of minerals according to (Warr, 2021): Amp – amphibole, Crn – corundum, Grt – garnet, Ilm – ilmenite, Orc – orthopyroxene, Osm – osmylite, Phl – phlogopite, Pl – plagioclase, Spl – spinel, Trd – tridymite. Photo (a–g, e, z, i) – with one nicola; photo (d, g) – nicoli are crossed. (1MB) doi: 10.31857/S0869-5903325552-585-4259336
Fig. 8. The shape of the secretions (a, b) and the composition of plagioclase (c) in the sample of dacite KE-81A. (a) – plagioclase border around the grain of xenogenic spinel, (b) – phenocrysts Pl-1 with growth zonality (images in backscattered electrons – BSE, point numbers in the figure correspond to the numbers in Supplemental 1, ESM_1), (c) – composition of plagioclases from dacites of the Cordierite volcano on the triple diagram Ab–An–Or. (401KB) doi: 10.31857/S0869-5903325552-585-4259337
Fig. 9. Phenocrysts of different garnet generations and their composition in a sample of KE-81A dacite. (a–d) – BSE images (the numbers of points in the figure correspond to those in the table. 2), (e) – the position of the points of garnets from dacites of the Cordierite volcano on the summary genetic diagram for pyrope-almandine-grossular garnets of different origin (Sobolev, 1964). 1 – Grt-1; 2 – Grt-2; 3 – Grt-3. (671KB) doi: 10.31857/S0869-5903325552-585-4259338
Fig. 10. Orthopyroxene isolations of different generations and their composition in the dacites of the Cordierite volcano. (a–d) – BSE images (the point numbers in the figure correspond to the numbers in Supplemental 1, ESM_3), (e) – classification diagram, (e, g) – binary diagrams for orthopyroxenes of different generations from dacites of the Cordierite volcano. (710KB) doi: 10.31857/S0869-5903325552-585-4259339
Fig. 11. The form of osmylite-(Mg) secretions in a sample of KE-81A dacite. (a, b) – phenocrysts, (c) – crystals in myaroles, (d) – xenomorphic secretions in the bulk, (e, f) – BSE images (the numbers of points in the figure correspond to the numbers in Tables 3 and Supplemental 1, ESM_4). (778KB) doi: 10.31857/S0869-5903325552-585-4259340
Fig. 12. The positions of the points of the osmilite-(Mg) composition from the dacites of the Cordierite volcano on the genetic diagram K/(K + Na + Ca)–Mg/(Mg + Fe + Mn). References to literary sources are in the symbols on the diagram. (343KB) doi: 10.31857/S0869-5903325552-585-4259341
Fig. 13. Isolations of different spinel generations and their composition in the rocks of the Cordierite volcano. (a, b) – BSE images (the point numbers in the figure correspond to the numbers in Supplemental 1, ESM_5), (c, d) – classification diagrams for spinel from dacites of the Cordierite volcano (c – according to Heimann, Spry, 2005; d – according to Yavuz, Yavuz, 2023). (392KB) doi: 10.31857/S0869-5903325552-585-4259342
Fig. 14. Minor minerals of dacites of the Cordierite volcano. (a–c) – corundum crystals from dacites of the Cordierite volcano (BSE image): (a) – crystal cross section with removed impurity contents according to SEM-EDS data, (b, c) – pseudohexagonal habitus of crystals; (d) – zonal opacite reaction rim around an amphibole grain from osmylite-containing dacites (mod. KE-81A, BSE image); (d, e) – tridymite and apatite secretions in osmylite-(Mg) (d – BSE image, e – in a transparent section with one nicol); (w, z) – ilmenite in dacites of the Cordierite volcano, image BSE (w – xenogenic ilmenite in fusion with rutile in hercynite Spl-1, w – igneous ilmenite in fusion with osmylite-(Mg)). (809KB) doi: 10.31857/S0869-5903325552-585-4259343
Fig. 15. Micrographs (BSE image) indicating the points at which the chemical composition was analyzed (Table. 4) garnets and orthopyroxenes in order to determine the P–T conditions of melt crystallization. (606KB) doi: 10.31857/S0869-5903325552-585-4259344
Fig. 16. The results of calculating the P–T parameters of melt crystallization for bimineral Grt–Opx pairs (the composition of minerals is shown in Table. 4) using the "Ca in Opx" geothermometer ([1] – Nimis, Grutter, 2010) and Grt-Opx geobarometers ([2] – Harley, Green, 1982; [3] – Harley, 1984; [4] – Nikitina et al., 2010). (305KB) doi: 10.31857/S0869-5903325552-585-4259345
Supplimentary 1 (23MB) doi: 10.31857/S0869-5903325552-585-4259346
Supplimentary 2 (11KB) doi: 10.31857/S0869-5903325552-585-4259347
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