Crystal Chemistry of Minerals and Inorganic Compounds with Lavendulan Clusters. II. New Compound Na2+xCu5(PO4)3(PO3+x(OH)1-x)Cl (x ~ 0.175) and Features of the Vertical Linkage of Lavendulan Clusters

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅或者付费存取

详细

The new compound Na2+xCu5(PO4)3(PO3+x(OH)1-x)Cl (x ~ 0.175) is obtained by chemical transport reactions. The crystal structure at 100 K (orthorhombic, Cmce, a = 13.6341(2), b = 13.8802(2), c = 15.5183(3) Å, V = 2936.74(8) Å3, Z = 8) was solved by direct methods and refined to R1 = 0.022. The compound Na2+xCu5(PO4)3(PO3+x(OH)1-x)Cl (x ~ 0.175) is a representative of a new structure type of inorganic compounds. Lavendulan clusters of the composition [Cu5(PO4)8Cl] in its structure are combined into layers parallel to the (001) plane. The layers unite with each other by means of an edge-mirror linkage, resulting in the formation of a dense heteropolyhedral framework with voids occupied by Na+ cations. The new linkage type is the first example of edge-mirror linkage of lavendulan clusters, as opposed to the vertex-mirror and translational linkage types.

作者简介

I. Kornyakov

Nanomaterials Research Centre, Kola Science Centre, RAS; Saint Petersburg State University

Apatity, Russia; Saint Petersburg, Russia

S. Krivovichev

Nanomaterials Research Centre, Kola Science Centre, RAS; Saint Petersburg State University

Email: s.krivovichev@ksc.ru
Apatity, Russia; Saint Petersburg, Russia

A. Kasatkin

Fersman Mineralogical Museum RAS

Moscow, Russia

参考

  1. Bree N. E., O’Keefe M. Bond-valence parameters for solids. Acta Cryst. 1991. Vol. B47. P. 192—197.
  2. Cooper M. A., Hawthorne F. C. Highly undersaturated anions in the crystal structure of andyrobertsite — calcio-andyrobertsite, a doubly acid arsenate of the form K(Cd, Ca)[Cu²⁺₆(AsO₄)₄[As(OH)₂O₃]](H₂O)₂. Canad. Miner. 2000. Vol. 38. P. 817—830.
  3. Crystallis Pro Software System, version 1.171.41.104a. 2021. Rigaku Oxford Diffraction: Oxford, UK.
  4. Dolomanov O. V., Bourhis L. J., Gildea R. J., Howard J. A. K., Puschmann H. OLEX2: A complete structure solution, refinement and analysis program. J. Appl. Cryst. 2009. Vol. 42. P. 339—341.
  5. Kimura K., Sera M., Kimura T. A²⁺ Cation control of chiral domain formation in A(TiO)Cu₄(PO₄)₄ (A = Ba, Sr). Inorg. Chem. 2016. Vol. 55. P. 1002—1004.
  6. Kimura K., Urushihara D., Asaka T., Toyoda M., Miyake A., Tokunaga M., Matsuo A., Kindo K., Yamauchi K., Kimura T. Synthesis, structure, and anomalous magnetic ordering of the spin-1/2 coupled square tetramer system K(NbO)Cu₄(PO₄)₄. Inorg. Chem. 2020. Vol. 59. P. 10986—10995.
  7. Kornyakov I. V., Krivovichev S. V. Gurzhiy V. V. Oxocentered units in three novel Rb-containing copper compounds prepared by CVT reaction method. Z. Anorg. Allg. Chem. 2018. Vol. 644. P. 77—81.
  8. Kornyakov I. V., Krivovichev S. V., Kasatkin A. V. Crystal chemistry of minerals and inorganic compounds with lavendulan clusters. II. New compound Na₁₅₋₋₂Cu₁₇₈(AsO₄)₆F₃Cl₂ (x ~ 0.12) and its relation to axelite. Zapiski RMO. 2025. Vol. 154. N 4. P. 76—90.
  9. Meyer S., Müller-Buschbaum Hk. Cu₄O₁₂-Baugruppen aus planaren CuO₄-Polygonen im Barium-Vanadyl-Oxocuprat(II)-phosphat Ba(VO)Cu₄(PO₄)₄. Z. Anorg. Allg. Chem. 1997. Bd. 623. S. 1693—1698.
  10. Panikorovskii T. L., Krivovichev S. V., Ivanyuk G. Yu., Yakovenchuk V. N. The crystal structure of epifanovite. Zapiski RMO. 2017. Vol. 146. N 3. P. 39—50 (in Russian).
  11. Pekov I. V., Zubkova N. V., Agakhanov A. A., Yapaskurt V. O., Belakowsky D. I., Brirvin S. N., Sidorov E. G., Kutyrev A. V., Pushcharovsky D. Yu. New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XIX. Axelite, Na₁₄Cu₃(AsO₄)₆F₂Cl₂. Miner. Mag. 2022. Vol. 87. P. 109—117.
  12. Pushcharovsky D. Yu., Zubkova N. V., Teat S. J., MacLean E. J., Sarp H. Crystal structure of malmeritic. Eur. J. Miner. 2004. Vol. 16. P. 687—692.
  13. Sarp H., Černý R. Calcio-andyrobertsite-2O, KCaCu₃(AsO₄)₄[AsO₂(OH)₂]₂H₂O: its description, crystal structure and relation with calcio-andyrobertsite-1M. Eur. J. Miner. 2004. Vol. 16. P. 163—169.
  14. Sheldrick G. M. SHELXT — Integrated space-group and crystal structure determination. Acta Cryst. 2015a. Vol. A71. P. 3—8.
  15. Sheldrick G. M. Crystal structure refinement with SHELXL. Acta Cryst. 2015b. Vol. C71. P. 3—8.
  16. Yakubovich O. V., Steele I. M., Kiriukhina G. V., Dimitrova O. V. A microporous potassium vanadyl phosphate analogue of malmeritic: hydrothermal synthesis and crystal structure. Z. Krist. 2015. Vol. 230. P. 337—344.

补充文件

附件文件
动作
1. JATS XML
下载

版权所有 © Russian Academy of Sciences, 2025