Crystal Chemistry of Wermlandite-Group Minerals

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Resumo

Crystal chemical features of wermlandite group minerals are discussed that are assigned to motukoreaite and wermlandite structure types. By comparing the geometric parameters of subcells and the topology of metal-hydroxyl layers for minerals with different anions, it is shown that the metal-hydroxyl layer exhibits no adaptability to the charge and/or geometry of the interlayer anion. The crystal structures of the wermlandite group minerals, like those of other layered double hydroxides, consist of "rigid" metal-hydroxyl layers that transfer the charge (valence forces) to the negatively charged (anion-water or anion-cation-water) layers through a system of hydrogen bonds in which the oxygen of the metal-hydroxyl layer is a donor, and the acceptors are anions, water molecules, and, as in the case of the wermlandite group minerals, cationic complexes A(H2O)6 located between the metal-hydroxyl layers. Unlike most layered double hydroxides, the interlayer distance in the wermlandite group minerals and their synthetic analogues shows neither a linear dependence on the charge nor a linear relationship with the size of the interlayer cation A (although this has been postulated previously). This is because the interlayer distance in this case is determined mainly by (1) the layer charge, i. e. the height of the gap between the two types of layers, and (2) the height of the anion-cation-water layers, namely the height of the sulfate tetrahedra located at two levels of z coordinates and linked to other structural blocks by hydrogen bonds. The superposition of these parameters leads to a nonlinear character of d00n on the layer charge, nor on radii of A cation. A linear correlation is observed between the divalent cation radius (r) and the subcell parameter a' (range 3.05—3.35 Å), according to the equation a' = 0.9614r + 2.2328 (R2 = 0.99), which can be used to diagnose layered double hydroxides with M3+ = Al. The interlayer distances of the wermlandite group minerals and their synthetic analogues are in the range 10.9—11.4 Å. Karchevskyite, which does not correspond to the other members of the group in crystallographic characteristics, requires revision research.

Sobre autores

E. Zhitova

Institute of Volcanology and Seismology, Far Eastern Branch RAS

Autor responsável pela correspondência
Email: zhitova_es@mail.ru
Petropavlovsk-Kamchatsky, Russia

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