Crystal Chemistry of Minerals and Inorganic Compounds with Lavendulan Clusters. I. New Compound Na15–2xCu7+x(AsO4)8F3Cl2 (x ~ 0.12) and Its Relation to Axelite

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The new compound Na15–2xCu7+x(AsO4)8F3Cl2 (x ~ 0.12) was obtained by chemical transport reactions. The crystal structure at 100 K (tetragonal, P4bm, a = 14.58917(16), c = 8.30072(14) Å, V = 1766.76(5) Å3, Z = 2) was solved by direct methods and refined to R1 = 0.025. The crystal structure is based upon copper-arsenate layers formed by combining lavendulan clusters based on Cu1 and Cu2 atoms through Cu3O4FCl octahedra. The crystal structure exhibits sharp axial asymmetry. The Na15–2xCu7+x(AsO4)8F3Cl2 (x ~ 0.12) compound is closely related to axelite Na14Cu7AsO4)8F2Cl2. Nonstoichiometry of composition is caused by isomorphism according to the scheme 2Na+ → Cu2+ + ☐.

作者简介

I. Kornyakov

Nanomaterials Research Centre, Kola Science Centre, RAS; Institute of Earth Sciences, St Petersburg State University

Apatity, Russia; Saint Petersburg, Russia

S. Krivovichev

Nanomaterials Research Centre, Kola Science Centre, RAS; Institute of Earth Sciences, St Petersburg State University

Email: s.krivovichev@ksc.ru
Apatity, Russia; Saint Petersburg, Russia

A. Kasatkin

Fersman Mineralogical Museum, Russian Academy of Sciences

Moscow, Russia

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