Vestnik of the Far East Branch of the Russian Academy of SciencesVestnik of the Far East Branch of the Russian Academy of SciencesВестник Дальневосточного отделения Российской академии наук0869-7698The Russian Academy of Sciences67744610.31857/S0869769824060079HSSNSAChemical Sciences. Functional CoatingsХимические науки. Функциональные покрытияReview ArticleEmbedding of magnetoactive particles from slurry electrolytes into PEO coatings on titaniumВнедрение магнитоактивных частиц из электролитов-суспензий в ПЭО-покрытия на титанеhttps://orcid.org/0000-0002-0341-9881AdigamovaM. V.АдигамоваМ. В.
Russian Federation

Candidate of Sciences in Chemistry, Senior Researcher

кандидат химических наук, старший научный сотрудник

adigamova@ich.dvo.ruhttps://orcid.org/0000-0003-1680-4882LukiyanchukI. V.ЛукиянчукИ. В.
Russian Federation

Candidate of Sciences in Chemistry, Senior Researcher

кандидат химических наук, старший научный сотрудник

lukiyanchuk@ich.dvo.ruhttps://orcid.org/0000-0003-4355-820XMorozovaV. P.МорозоваВ. П.
Russian Federation

Researcher

научный сотрудник

morozova@ich.dvo.ruhttps://orcid.org/0000-0002-0826-0291MalyshevI. V.МалышевИ. В.
Russian Federation

Candidate of Sciences in Chemistry, Researcher

кандидат химических наук, научный сотрудник

malishev@ich.dvo.ruhttps://orcid.org/0000-0001-5489-6832EgorkinV. S.ЕгоркинВ. С.
Russian Federation

Candidate of Sciences in Chemistry, Senior Researcher

кандидат химических наук, старший научный сотрудник

egorkin@ich.dvo.ruhttps://orcid.org/0000-0002-1770-1546TkachenkoI. A.ТкаченкоИ. А.
Russian Federation

Candidate of Sciences in Chemistry, Senior Researcher

кандидат химических наук, старший научный сотрудник

tkachenko@ich.dvo.ruhttps://orcid.org/0000-0002-0963-0557SinebryukhovS. L.СинебрюховС. Л.
Russian Federation

Corresponding Member of RAS, Doctor of Sciences in Chemistry, Associate Professor, Deputy Director

член-корреспондент РАН, доктор химических наук, доцент, заместитель директора

sls@ich.dvo.ruhttps://orcid.org/0000-0003-1576-8680GnedenkovS. V.ГнеденковС. В.
Russian Federation

Corresponding Member of RAS, Doctor of Sciences in Chemistry, Professor, Director

член-корреспондент РАН, доктор химических наук, профессор, директор

svg21@hotmail.comInstitute of Chemistry, FEB RASИнститут химии ДВО РАН0512202468710320032025Copyright ©; 2024, Russian Academy of SciencesCopyright ©; 2024, Российская академия наук2024Russian Academy of SciencesРоссийская академия наукhttps://journals.eco-vector.com/0869-7698/article/view/677446

The paper summarizes the literature data on plasma electrolytic treatment of titanium in electrolytes with dispersed magnetoactive particles in order to form surface structures with certain magnetic properties. The compositions of electrolytes, process parameters and magnetic properties of the resulting coatings are presented. Depending on the chemical nature and characteristics of the particles, an inert or reactive mechanism of their introduction from the electrolyte into the growing coatingsis carried out. It is shown that metal oxide particles located on the surface, mainly in pores, and in the coating bulk make the main contribution to the magnetic properties of the samples. By changing the electrolyte formula and the concentration of components, it is possible to control the composition of the particles and, accordingly, the magnetic characteristics of the coating.

Обобщены литературные данные о плазменно-электролитической обработке титана в электролитах, содержащих дисперсные магнитоактивные частицы, с целью формирования поверхностных структур с определенными магнитными свойствами. Приведены составы электролитов, параметры процесса и магнитные свойства получаемых покрытий. В зависимости от химической природы и характеристик частиц их включение из электролита в растущие покрытия осуществляется по инертному или реактивному механизму. Показано, что основной вклад в магнитные свойства образцов вносят металлооксидные частицы, обнаруженные в порах, на поверхности и в массиве покрытий. Изменяя состав и концентрацию компонентов электролита, можно управлять составом частиц и, соответственно, магнитными характеристиками покрытий.

plasma electrolytic oxidationslurry electrolytestitaniummagnetic propertiesparticles in poresплазменно-электролитическое оксидированиеэлектролиты-суспензиититанмагнитные свойствачастицы в порахPukhir G.A., Mahmoud M.Sh., Nasonova N.V., Lynkov L.M. Protective properties of screens of electromagnetic radiation of a microwave range on the basis of the combined, dielectric and magnetic powder components. Doklady BGUIR. 2011;60(6):94–97. (In Russ.).Пухир Г.А., Махмуд М.Ш., Насонова Н.В. и др. Защитные свойства экранов электромагнитного излучения СВЧ-диапазона на основе комбинированных, диэлектрических и магнитных порошковых компонентов // Доклады БГУИР. 2011. Т. 60, № 6. С. 94–97.Roslyakov I.V., Napolsky K.S., Eliseev A.A. et al. Synthesis of magnetic nanoparticles with controlled anisotropy of functional properties in a matrix of porous aluminum oxide. Russian Nanotechnologies. 2009;4(3/4):69–72. (In Russ.).Росляков И.В., Напольский К.С., Елисеев А.А. и др. Синтез магнитных наночастиц с контролируемой анизотропией функциональных свойств в матрице из пористого оксида алюминия // Российские нанотехнологии. 2009. Т. 4, № 3/4. С. 69–72.Abdulhadi H.D.A., Al-Mashatt E.A.A., Bogush V.A. et al. Electromagnetic screens based on aluminum, its oxides and carbon fibers. Technologies, designs and properties: monograph. Minsk: Bestprint; 2021. 120 p. (In Russ.).Абдулхади Х.Д.А., Аль-Машатт Е.А.А., Богуш В.А. и др. Электромагнитные экраны на основе алюминия, его оксидов и углеродных волокон. Технологии, конструкции и свойства: монография. Минск: Бестпринт, 2021. 120 с.Vladimirov B.V., Krit B.L., Lyudin V.B. et al. Microarc discharge oxidizing of magnesium alloys: a review. Surface Engineering and Applied Electrochemistry. 2014;50(3):195–232. https://doi.org/10.3103/S1068375514030090.Vladimirov B.V., Krit B.L., Lyudin V.B. et al. Microarc discharge oxidizing of magnesium alloys: a review // Surf. Eng. Appl. Electrochem. 2014. Vol. 50 (3). P. 195–232. https://doi.org/10.3103/S1068375514030090.Sibileva S.V., Kozlova L.S. Review of technologies of applying coatings to titanium alloys by plasma electrolytic oxidation. Aviation Materials and Technologies. 2016; 44(S2):3–10. (In Russ.). https://doi.org/10.18577/2071-9140-2016-0-S2-3-10.Сибилева С.В., Козлова Л.С. Обзор технологии получения покрытий на титановых сплавах плазменным электролитическим оксидированием // Авиационные материалы и технологии. 2016. № S2 (44). С. 3–10. https://doi.org/10.18577/2071-9140-2016-0-S2-3-10.Shrestha S., Dunn B.D. Advanced plasma electrolytic oxidation treatment for protection of light weight materials and structures in a space environment. Surface World. 2007;11:4044.Shrestha S., Dunn B.D. Advanced plasma electrolytic oxidation treatment for protection of light weight materials and structures in a space environment // Surface World. 2007. № 11. P. 4044.Borisov A.M., Krit B.L., Lyudin V.B. et al. Microarc oxidation in slurry electrolytes: A review. Surface Engineering and Applied Electrochemistry. 2016;52:50–78. https://doi.org/10.3103/S106837551601004X.Борисов А.М., Крит Б.Л., Людин В.Б. и др. Микродуговое оксидирование в электролитах-суспензиях (обзор) // Электронная обработка материалов. 2016. Т. 52, № 1. С. 50–77.Jiang B.L., Wang Y.M. Plasma electrolytic oxidation treatment of aluminum and titanium alloys. Surface Engineering of Light Alloys: Aluminum, Magnesium and Titanium Alloys. 2010:110–154. https://doi.org/10.1533/9781845699451.2.110.Jiang B.L., Wang Y.M. Plasma electrolytic oxidation treatment of aluminum and titanium alloys // Surface Engineering of Light Alloys: Aluminum, Magnesium and Titanium Alloys. 2010. P. 110–154. https://doi.org/10.1533/9781845699451.2.110.Yang C., Chen P., Wu W et al. A Review of Corrosion-Resistant PEO Coating on Mg Alloy. Coatings. 2024;14(4):451. https://doi.org/10.3390/coatings14040451.Yang C., Chen P., Wu W et al. A Review of Corrosion-Resistant PEO Coating on Mg Alloy // Coatings. 2024. Vol. 14 (4). P. 451. https://doi.org/10.3390/coatings14040451.Rakoch A.G., Strekalina D.M., Gladkova A.A. Wear-resistant coatings obtained on titanium alloy VT6 by plasma electrolytic oxidation. Russian Journal of Non-Ferrous Metals. 2016;2:80–84. (In Russ.). https://doi.org/10.17073/1997-308X-2016-1-44-50.Ракоч А.Г., Стрекалина Д.М., Гладкова А.А. Износостойкие покрытия на титановом сплаве ВТ6, получаемые методом ПЭО // Цветные металлы. 2016. № 2. C. 80–84. https://doi.org/10.17073/1997-308X-2016-1-44-50.Tang H., Xin T.Z., Sun Q. at al. Influence of FeSO4 concentration on thermal emissivity of coatings formed on titanium alloy by micro-arc oxidation. Applied Surface Science. 2011;257(24):10839–10844. https://doi.org/10.1016/j.apsusc.2011.07.118.Tang H., Xin T.Z., Sun Q. at al. Influence of FeSO4 concentration on thermal emissivity of coatings formed on titanium alloy by micro-arc oxidation // Appl. Surf. Sci. 2011. Vol. 257, N 24. P. 10839–10844. https://doi.org/10.1016/j.apsusc.2011.07.118.Yao Z.P., Hu B., Shen Q.X. et al. Preparation of black high absorbance and high emissivity thermal control coating on Ti alloy by plasma electrolytic oxidation. Surface and Coatings Technology. 2014;253:166–170. https://doi.org/10.1016/j.surfcoat.2014.05.032.Yao Z.P., Hu B., Shen Q.X. et al. Preparation of black high absorbance and high emissivity thermal control coating on Ti alloy by plasma electrolytic oxidation // Surf. Coat. Technol. 2014. Vol. 253. P. 166–170. https://doi.org/10.1016/j.surfcoat.2014.05.032.Kurze P., Krysmann W., Schreckenbach J. et al. Coloured ANOF layers on aluminium. Crystal Research and Technology. 1987;22(1):53–58. https://doi.org/10.1002/crat.2170220115.Kurze P., Krysmann W., Schreckenbach J. et al.Coloured ANOF layers on aluminium // Cryst. Res. Technol. 1987. Vol. 22 (1). P. 53–58. https://doi.org/10.1002/crat.2170220115.Terleeva O.P., Sharkeev Yu.P., Slonova A.I. et al. Effect of microplasma modes and electrolyte composition on micro-arc oxidation coatings on titanium for medical applications. Surface and Coatings Technology. 2010;205(6):1723–1729. https://doi.org/10.1016/j.surfcoat.2010.10.019.Terleeva O.P., SharkeevYu.P., Slonova A.I. et al. Effect of microplasma modes and electrolyte composition on micro-arc oxidation coatings on titanium for medical applications // Surf. Coat. Technol. 2010. Vol. 205 (6). P. 1723–1729. https://doi.org/10.1016/j.surfcoat.2010.10.019.Samadi P., Witonska I.A. Plasma electrolytic oxidation layers as alternative supports for metallic catalysts used in oxidation reaction for environmental application. Catalysis Communications. 2023;181:106722. https://doi.org/10.1016/j.catcom.2023.106722.Samadi P., Witonska I.A. Plasma electrolytic oxidation layers as alternative supports for metallic catalysts used in oxidation reaction for environmental application // Catal. Commun. 2023. Vol. 181. P. 106722. https://doi.org/10.1016/j.catcom.2023.106722.Egorkin V.S., Mashtalyar D.V., Gnedenkov A.S. et al. Icephobic performance of combined fluorine-containing composite layers on Al-Mg-Mn-Si alloy surface. Polymers. 2021;13(21):3827. https://doi.org/10.3390/polym13213827.Egorkin V.S., Mashtalyar D.V., Gnedenkov A.S. et al. Icephobic performance of combined fluorine-containing composite layers on Al-Mg-Mn–Si alloy surface // Polymers. 2021. Vol. 13 (21). P. 3827. https://doi.org/10.3390/polym13213827.Mikheev A.E., Savelyev D.O., Ravodina D.V., Girn A.V. Application of optically black lightabsorbing coating on aluminum and titanium alloys. Siberian Aerospace Journal. 2022;23(2):305–314. (In Russ.). https://doi.org/10.31772/2712-8970-2022-23-2-305-314.Михеев А.Е., Савельев Д.О., Раводина Д.В., Гирн А.В. Нанесение оптически черного светопоглощающего покрытия на сплавы алюминия и титана // Сибирский аэрокосмический журнал. 2022. Т. 23, № 2. С. 305–314. https://doi.org/10.31772/2712-8970-2022-23-2-305-314.Jin F.Y., Tong H.H., Li J. et al. Structure and microwave-absorbing properties of Fe-particle containing alumina prepared by micro-arc discharge oxidation. Surface and Coatings Technology. 2006;201:292–295. https://doi.org/10.1016/j.surfcoat.2005.11.116.18 Jin F.Y., Tong H.H., Li J. et al. Structure and microwave-absorbing properties of Fe-particle containing alumina prepared by micro-arc discharge oxidation // Surf. Coat. Technol. 2006. Vol. 201. P. 292–295. https://doi.org/10.1016/j.surfcoat.2005.11.116.Jagminas A., Ragalevicius R., Mazeika K. et al. A new strategy for fabrication Fe2O3/SiO2 composite coatings on the Ti substrate. Journal of Solid State Electrochemistry. 2010;14(2):271–277. https://doi.org/10.1007/s10008-009-0820-7.Jagminas A., Ragalevicius R., Mazeika K. et al. A new strategy for fabrication Fe2O3/SiO2 composite coatings on the Ti substrate // J. Solid State Electrochemistry. 2010. Vol. 14 (2). P. 271–277. DOI: 10.1007/s10008-009-0820-7.Gnedenkov S.V., Sinebryukhov S.L., Tkachenko I.A. et al. Magnetic properties of surface layers formed on titanium by plasma electrolytic oxidation. Inorganic Materials: Applied Research. 2012;5:55–62. https://doi.org/10.1134/S2075113312020062.Гнеденков С.В., Синебрюхов С.Л., Ткаченко И.А. и др. Магнитные свойства поверхностных слоев, формируемых на титане методом плазменно-электролитического оксидирования // Перспективные материалы. 2011. № 5. С. 55–62.Rogov A.B., Terleeva O.P., Mironov I.V., Slonova A.I. Iron-containing coatings obtained by microplasma method on aluminum with usage of homogeneous electrolytes. Applied Surface Science. 2012;258(7):2761. https://doi.org/10.1016/j.apsusc.2011.10.128.Rogov A.B., Terleeva O.P., Mironov I.V., Slonova A.I. Iron-containing coatings obtained by microplasma method on aluminum with usage of homogeneous electrolytes // Appl. Surf. Sci. 2012. Vol. 258 (7). P. 2761. https://doi.org/10.1016/j.apsusc.2011.10.128.Baranova T.A., Chubenko A.K., Ryabikov A.E. et al. Microarc synthesis of nanostructured radiation-absorbing coatings on aluminum and titanium surfaces. IOP Conference Series: Materials Science and Engineering. 2018;286:012037. https://doi.org/10.1088/1757-899X/286/1/012037.Baranova T.A., Chubenko A.K., Ryabikov A.E. et al. Microarc synthesis of nanostructured radiation-absorbing coatings on aluminum and titanium surfaces // IOP Conf. Ser. Mat. Sci. 2018. Vol. 286. P. 012037. https://doi.org/10.1088/1757-899X/286/1/012037.Rudnev V.S., Ustinov A.Yu., Lukiyanchuk I.V. et al. Magnetoactive oxide layers formed on titanium by plasma electrolytic technique. Protection of Metals and Physical Chemistry of Surfaces. 2010;46(5):566–572. https://doi.org/10.1134/S2070205110050114.Руднев В.С., Устинов А.Ю., Лукиянчук И.В. и др. Магнитоактивные оксидные слои на титане, сформированные плазменно-электролитическим методом // Физикохимия поверхности и защита материалов. 2010. Т. 46, № 5. С. 494–500.Adigamova M.V., Lukiyanchuk I.V., Morozova V.P. et al. Fe and/or Co-containing coatings on titanium: Features of plasma electrolytic formation, composition, and magnetic properties. Surface and Coatings Technology. 2022;446:128790. https://doi.org/10.1016/j.surfcoat.2022.128790.Adigamova M.V., Lukiyanchuk I.V., Morozova V.P. et al. Fe and/or Co-containing coatings on titanium: Features of plasma electrolytic formation, composition, and magnetic properties // Surf. Coat. Technol. 2022. Vol. 446. P. 128790. https://doi.org/10.1016/j.surfcoat.2022.128790.Kharitonsky P.V., Frolov A.M., Rudnev V.S. et al. Magnetic properties of iron containing coatings formed by plasma electrolytic oxidation. Bulletin of the Russian Academy of Sciences: Physics. 2010;74(10):1404–1406. (In Russ.). https://doi.org/10.4028/www.scientific.net/SSP.168-169.289.Харитонский П.В., Фролов А.М., Руднев В.С. и др. Магнитные свойства железосодержащих покрытий, полученных методом плазменно-электролитического оксидирования // Известия РАН. Серия физическая. 2010. Т. 74, № 10. С. 1465–1467.Rudnev V.S., Adigamova M.V., Lukiyanchuk I.V. et al. The effect of the conditions of formation on ferromagnetic properties of iron-containing oxide coatings on titanium. Protection of Metals and Physical Chemistry of Surfaces. 2012;48(5):543–552. https://doi.org/10.1134/S2070205112050097.Руднев В.С., Адигамова М.В., Лукиянчук И.В. и др. Влияние условий формирования на ферромагнитные свойства железосодержащих оксидных покрытий на титане // Физикохимия поверхности и защита материалов. 2012. Т. 48, № 5. С. 459–469.Adigamova M.V., Rudnev V.S., Lukiyanchuk I.V. et al. The effect of Fe-containing colloid particles in electrolyte on the composition and magnetic characteristics of oxide layers on titanium formed using the method of plasma electrolytic oxidation. Protection of Metals and Physical Chemistry of Surfaces. 2016;52(3):526–531. https://doi.org/10.1134/S2070205116030023.Адигамова М.В., Руднев В.С., Лукиянчук И.В. и др. Влияние коллоидных Fe-содержащих частиц в электролите на состав и магнитные характеристики оксидных слоев на титане, сформированных методом плазменно-электролитического оксидирования // Физикохимия поверхности и защита материалов. 2016. Т. 52, № 3. С. 324–330.Rudnev V.S., Kharitonskii P.V., Kosterov A. et al. Magnetism of Fe-doped Al2O3 and TiO2 layers formed on aluminum and titanium by plasma-electrolytic oxidation. Journal of Alloys and Compounds. 2020;816:152579. https://doi.org/10.1016/j.jallcom.2019.152579.Rudnev V.S., Kharitonskii P.V., Kosterov A. et al. Magnetism of Fe-doped Al2O3 and TiO2 layers formed on aluminum and titanium by plasma-electrolytic oxidation // J. Alloys Compd. 2020. Vol. 816. P. 152579. https://doi.org/10.1016/j.jallcom.2019.152579.Rudnev V.S., Adigamova M.V., Lukiyanchuk I.V. et al. Oxide coatings with ferromagnetic characteristics on Al, Ti, Zr and Nb. Surface and Coatings Technology. 2020;381:125180. https://doi.org/10.1016/j.surfcoat.2019.125180.Rudnev V.S., Adigamova M.V., Lukiyanchuk I.V. et al. Oxide coatings with ferromagnetic characteristics on Al, Ti, Zr and Nb // Surf. Coat. Technol. 2020. Vol. 381. P. 125180. https://doi.org/10.1016/j.surfcoat.2019.125180.Adigamova M.V., Lukiyanchuk. I.V., Tkachenko I.A., Morozova V.P. Magnetic properties of Fe + Ni-containing TiO2-layer/Ti composites. Protection of Metals and Physical Chemistry of Surfaces. 2022;58( 3):510–518. https://doi.org/10.1134/S2070205122030029.Адигамова М.В., Лукиянчук И.В., Ткаченко И.А., Морозова В.П. Магнитные свойства композитов «Fe+Ni-содержащий TiO2-слой/Ti» // Физикохимия поверхности и защита металлов. 2022. Т. 58, № 3. С. 289–298. DOI: 10.31857/S0044185622030020.Xiaopeng Lu, Carsten Blawert, Yuanding Huang et al. Plasma electrolytic oxidation coatings on Mg alloy with addition of SiO2 particles. Electrochimica Acta. 2016;187:20–33. https://doi.org/10.1016/j.electacta.2015.11.033.Xiaopeng Lu, Carsten Blawert, Yuanding Huang et al. Plasma electrolytic oxidation coatings on Mg alloy with addition of SiO2 particles // Electrochimica Acta. 2016. Vol. 187. P. 20–33. https://doi.org/10.1016/j.electacta.2015.11.033.Adigamova M.V., Malyshev I.V., Lukiyanchuk I.V., Tkachenko I.A. A novel approach to obtaining LaMnO3/TiO2/Ti composites: Features of plasma electrolytic formation, composition, and magnetic properties. Journal of Alloys and Compounds. 2023;967:171675. https://doi.org/10.1016/j.jallcom.2023.171675.Adigamova M.V., Malyshev I.V., Lukiyanchuk I.V., Tkachenko I.A. A novel approach to obtaining LaMnO3/TiO2/Ti composites: Features of plasma electrolytic formation, composition, and magnetic properties // J. Alloys Compd. 2023. Vol. 967. P. 171675. https://doi.org/10.1016/j.jallcom.2023.171675.Adigamova M.V., Malyshev I.V., Lukiyanchuk I.V., Tkachenko I.A., Saiankina K.A. Effect of lanthanum manganite particles on the structure and magnetic behavior of PEO coatings on titanium. Materials Chemistry and Physics. 2024;320:129479. https://doi.org/10.1016/j.matchemphys.2024.129479.Adigamova M.V., Malyshev I.V., Lukiyanchuk I.V., Tkachenko I.A., Saiankina K.A. Effect of lanthanum manganite particles on the structure and magnetic behavior of PEO coatings on titanium // Mater. Chem. Phys. 2024. Vol. 320. P. 129479. https://doi.org/10.1016/j.matchemphys.2024.129479.Demin R.V., Koroleva L.I., Szymszak R., Szymszak H. Experimental evidence for a magnetic two-phase state in manganites. Journal of Experimental and Theoretical Physics Letters. 2002;75:331–335.Demin R.V., Koroleva L.I., Szymszak R., Szymszak H. Experimental evidence for a magnetic two-phase state in manganites // JETP Letters. 2002. Vol. 75. P. 331–335.