Vestnik of the Far East Branch of the Russian Academy of SciencesVestnik of the Far East Branch of the Russian Academy of SciencesВестник Дальневосточного отделения Российской академии наук0869-7698The Russian Academy of Sciences67745210.31857/S0869769824060125HRBLEVChemical sciences. Advanced inorganic materialsХимические науки. Перспективные неорганические материалыReview ArticleNew glasses in the MNbOF5-BaF2-InF3 (M–Mn, Cd, Zn) systemsНовые стекла в системах MNbOF5-BaF2-InF3 (M–Mn, Cd, Zn)IgnatievaL. N.ИгнатьеваЛ. Н.
Russian Federation

Doctor of Sciences in Chemistry, Chief Researcher

доктор химических наук, главный научный сотрудник

ignatieva@ich.dvo.ruSavchenkoN. N.СавченкоН. Н.
Russian Federation

Researcher

научный сотрудник

savchenko@ich.dvo.ruhttps://orcid.org/0000-0002-0494-9948MarchenkoYu. V.МарченкоЮ. В.
Russian Federation

Candidate of Sciences in Chemistry, Senior Researcher

кандидат химических наук, старший научный сотрудник

gor_dvo@mail.ruMashchenkoV. А.МащенкоВ. А.
Russian Federation

Researcher

научный сотрудник

mashchenko@ich.dvo.ruSarinS. A.СаринС. А.
Russian Federation

Researcher

научный сотрудник

sarin@ich.dvo.ruInstitute of Chemistry, FEB RASИнститут химии ДВО РАН05122024618720220032025Copyright ©; 2024, Russian Academy of SciencesCopyright ©; 2024, Российская академия наук2024Russian Academy of SciencesРоссийская академия наукhttps://journals.eco-vector.com/0869-7698/article/view/677452

The article summarizes the results of studying new glasses in the MnNbOF5-BaF2-InF3, ZnNbOF5-BaF2-InF3 and CdNbOF5-BaF2-InF3 systems. The thermal characteristics of glasses were studied, the role of fluorindate and fluoroniobate components in glass formation and crystallization behavior was revealed. Glasses in the MNbOF5-BaF2-InF3 systems can be considered three-component; their structure is formed by polyhedra of fluoroniobate (NbO2F4 and NbO3F3), InF6 and polyhedra formed by MFn. The possibility of obtaining glass ceramics has been demonstrated. For glasses in the CdNbOF5-BaF2-InF3 and ZnNbOF5-BaF2-InF3 systems, the photoluminescence was detected corresponding to emission levels of 542, 573 and 673, 751 nm, depending on the presence and concentration of indium trifluoride in the glass. Luminescent properties are shown only by glasses in which nanoparticles, 9–13 nm, were detected according to SAXS data.

В статье обобщены результаты исследования новых стекол в системах MnNbOF5-BaF2-InF3, ZnNbOF5-BaF2-InF3 и CdNbOF5-BaF2-InF3. Изучены термические характеристики стекол, выявлена роль фториндатных и фторниобатных компонентов в стеклообразовании и кристаллизационном поведении. Стекла в системах MNbOF5-BaF2-InF3 (M = Mn, Zn, Cd) можно считать трехкомпонентными, их структуру формируют полиэдры NbO2F4 и NbO3F3, InF6 и полиэдры, формируемые MFn. Показана возможность получения стеклокерамик. Для стекол в системах CdNbOF5-BaF2-InF3 и ZnNbOF5-BaF2-InF3 зафиксирована фотолюминесценция, соответствующая уровням эмиссии 542, 573 и 673, 751 нм, зависящая от присутствия и концентрации в стекле трифторида индия. Люминесцентные свойства показывают только стекла, в которых по данным МУРР обнаружены наноразмерные включения, 9–13 нм.

glassesstructurecrystallizationluminescenceglass ceramicsстекластруктуракристаллизациялюминесценциястеклокерамикаРоссийский научный фондRussian Science Foundation24-13-00133Poulain Mi., Poulain Ma. Oxyfluoride glasses. Mater. Sci.Forum. 1991;67/68:129–136.Poulain Mi., Poulain Ma. Oxyfluoride glasses // Mater. Sci. Forum. 1991. N 67/68. P. 129–36.Adam J.L. Fluoride glass research in France: fundamental and applications. J. Fluorine Chem. 2001;107:265–270. https: //doi.org/10.1016/S0022-1139(00)00368-7.Adam J.L. Fluoride glass research in France: fundamental and applications // J. Fluorine Chem. 2001. Vol. 107. P. 265–270. https: //doi.org/10.1016/S0022-1139(00)00368-7.Klouche Bouchaour Z.C., Polain M., Belhadji M., Hager I., Mallawany R.E.I. New oxyfluoroniobate glasses. J. Non-Cryst. Solids. 2005;351:816. https: //doi.org/10.1016/j.jnoncrysol.2005.01.081.Klouche Bouchaour Z.C., Polain M., Belhadji M., Hager I., Mallawany R.E.I. New oxyfluoroniobate glasses // J. Non-Cryst. Solids. 2005. Vol. 351. P. 816. https: //doi.org/10.1016/j.jnoncrysol.2005.01.081.Ignat’eva L.N., Antokhina T.F., Savchenko N.N., Polishchuk S.A., Buznik V.M. A spectroscopic study of the structure of fluoroniobate glasses. Glass Phys. Chem. 1998;24(2):97–100.Ignat’eva L.N., Antokhina T.F., Savchenko N.N., Polishchuk S.A., Buznik V.M. A spectroscopic study of the structure of fluoroniobate glasses // Glass Phys. Chem. 1998. Vol. 24 (2). P. 97–100.Ignatieva L.N., Bouznik V.M. The quantum chemical study of the fluoride and oxyfluoride glass structure. J. Non-Cryst. Solids. 1999;258:131–139. https: //doi.org/10.1016/S0022-3093(99)00482-2.Ignatieva L.N., Bouznik V.M. The quantum chemical study of the fluoride and oxyfluoride glass structure // J. Non-Cryst. Solids. 1999. Vol. 258. P. 131–139. https: //doi.org/10.1016/S0022-3093(99)00482-2.Ignat’eva L.N. et al. Synthesis and characterization of bismuth-containing oxyfluoroniobate glasses. Rus. J. Inorg. Chem. 2010;55(6):925–931. https: //doi.org/10.1134/S003602361006015X.Ignat’eva L.N. et al. Synthesis and characterization of bismuth-containing oxyfluoroniobate glasses // Rus. J. Inorg. Chem. 2010. Vol. 55 (6). P. 925–931. https: //doi.org/10.1134/S003602361006015X.Ignatieva L., Savchenko N., Marchenko Yu.V. Glasses in the NbO2F-BaF2-InF3-ErF3 systemIgnatieva L., Savchenko N., Marchenko Yu.V. Glasses in the NbO2F-BaF2-InF3-ErF3 system //J. Fluori. Chem. 2018;213:37–41. https: //doi.org/10.1016/j.jfluchem.2018.07.001 15. 15. L.J. Fluori. Chem. 2018. Vol. 213. P. 37–41. https: //doi.org/10.1016/j.jfluchem.2018.07.001 15. 15. L.Nazabal V., et al. Fluoride and oxyfluoride glasses for optical applications. J. Fluori. Chem. 2012;134:18–23. https: //doi.org/10.1016/j.jfluchem.2011.06.035.Nazabal V. et al. Fluoride and oxyfluoride glasses for optical applications // J. Fluori. Chem. 2012. Vol. 134. P. 18–23. https: //doi.org/10.1016/j.jfluchem.2011.06.035.Kai J., Li. W., Lin Y. Proc. XVII. Int. Congress on Glass. Beijing; 1995. Vol. 5. P. 704.Kai J., Li. W., Lin Y. // Proc. XVII. Int. Congress on Glass. Beijing; 1995. Vol. 5. P. 704.Polyshchuk S.A. et al. Ionic conduction in glasses in the MnNbOF5-BaF2-BiF3 system. Rus. J. Inorg. Chem. 2013;58(4):387–391. https: //doi.org/10.1134/S003602361304013X.Polyshchuk S.A. et al. Ionic conduction in glasses in the MnNbOF5-BaF2-BiF3 system // Rus. J. Inorg. Chem. 2013. Vol. 58 (4). P. 387–391. https: //doi.org/10.1134/S003602361304013X.Aseev V.A., Kolobkova E.V., Nekrasova Ya.A., Nikonorov N.V., Rokhmin A.S. Oxy-fluoride glasses for red phosphors. Mater. Phys. and Mech. 2013;17:135–141.Aseev V.A., Kolobkova E.V., Nekrasova Ya.A., Nikonorov N.V., Rokhmin A.S. Oxy-fluoride glasses for red phosphors // Mater. Phys. and Mech. 2013. Vol. 17. P. 135–141.Ignatieva L.N. et al. The glasses in the 30BaZrF6-70NaPO3-хEuF3 system. Rus. J. Inorg. Chem. 2022;67:1639–1645. https: //doi.org/10.1134/S0036023622100461.Ignatieva L.N. et al. The glasses in the 30BaZrF6-70NaPO3-хEuF3 system // Rus. J. Inorg. Chem. 2022. Vol. 67. P. 1639–1645. https: //doi.org/10.1134/S0036023622100461.Polishchuk S.A., Ignatieva L.N., Marchenko Yu.V., Buznik V.M. Bismuth-containing fluoride glasses. J. Struct. Chem. 2016;57(5):901–909. https: //doi.org/10.1134/S0022476616050085.Polishchuk S.A., Ignatieva L.N., Marchenko Yu.V., Buznik V.M. Bismuth-containing fluoride glasses // J. Struct. Chem. 2016. Vol. 57 (5). P. 901–909. https: //doi.org/10.1134/S0022476616050085.Ignatieva L.N., Polyshchuk S.A., Antokhina T.F., Bouznik V.M. Glasses in MnNbOF5-BaF2 and MnNbOF5-PbF2 systems. Phys. Chem. Glasses. 2005;46(2):153–156.Ignatieva L.N., Polyshchuk S.A., Antokhina T.F., Bouznik V.M. Glasses in MnNbOF5-BaF2 and MnNbOF5-PbF2 systems // Phys. Chem. Glasses. 2005. Vol. 46 (2). P. 153–156.Agulyansky А. The Chemistry of Tantalium and Niobium Fluoride Compounds. Elsevier. B.V.; 2004. 396 c.Agulyansky А. The Chemistry of Tantalium and Niobium Fluoride Compounds. Elsevier. B.V., 2004. 396 p.Davidovich R.L. Atlas of derivatograms of complex metal fluorides of groups III–V. M.: Nauka; 1976. 284 p. (In Russ.).Давидович Р.Л. Атлас дериватограмм комплексных фторидов металлов III–IV групп. М.: Наука, 1976. 284 с.Ignat’eva L.N. et al. Glasses in the CuNbOF5-BaF2 and CuNbOF5-PbF2 systems. Rus. J. Inorg. Chem. 2007;52(9):1328–1332. https: //doi.org/10.1134/S0036023607090021.Ignat’eva L.N. et al. Glasses in the CuNbOF5-BaF2 and CuNbOF5-PbF2 systems // Rus. J. Inorg. Chem. 2007. Vol. 52 (9). P. 1328–1332. https: //doi.org/10.1134/S0036023607090021.Ignatieva L.N., Savchenko N.N., Marchenko Yu.V., Sarin S.A. Synthesis, structure and crystallization of glasses in the CdNbOF5-BaF2-InF3 system. Ceram. Int. 2019;45:17737–17741. https: //doi.org/10.1016/j.ceramint.2019.05.343.Ignatieva L.N., Savchenko N.N., Marchenko Yu.V., Sarin S.A. Synthesis, structure and crystallization of glasses in the CdNbOF5-BaF2-InF3 system // Ceram. Int. 2019. Vol. 45. P. 17737–17741. https: //doi.org/10.1016/j.ceramint.2019.05.343.Ignat’eva L.N., Savchenko N.N., Marchenko Yu.V., Zverev G.A., Buznik V M. Structure and Crystallization of Glasses in the MnNbOF5-BaF2-InF3 System. Rus. J. Inorg. Chem. 2018;63(11):1389–1394. https: //doi.org/10.1134/S0036023618110062.Ignat’eva L.N., Savchenko N.N., Marchenko Yu.V., Zverev G.A., Buznik V M. Structure and Crystallization of Glasses in the MnNbOF5-BaF2-InF3 System // Rus. J. Inorg. Chem. 2018. Vol. 63 (11). P. 1389–1394. https: //doi.org/10.1134/S0036023618110062.Ignatieva L.N. et al. Oxyfluoroniobate glasses in the ZnNbOF5-BaF2-InF3 system. J. Non-Cryst. Solids 2024;623:122691. https: //doi.org/10.1016/j.jnoncrysol.2023.122691.Ignatieva L.N. et al. Oxyfluoroniobate glasses in the ZnNbOF5-BaF2-InF3 system // J. Non-Cryst. Solids. 2024. Vol. 623. P. 122691. https: //doi.org/10.1016/j.jnoncrysol.2023.122691.Davidovich R.L., Levchishina T.F., Kaidalova T.A., Sergienko V.I. The synthesis and properties of oxofluoroniobates and fluorotantalates of bivalent metals. J. Less Com. Metals. 1972;27(1):35.Davidovich R.L., Levchishina T.F., Kaidalova T.A., Sergienko V.I. The synthesis and properties of oxofluoroniobates and fluorotantalates of bivalent metals // J. Less Com. Metals. 1972. Vol. 27 (1). P. 35.Deschamps A., de Geuser F. On the validity of simple precipitate size measurements by small-angle scattering in metallic systems. J. Appl. Cryst. 2011;44:343–352. https: //doi.org/10.1107/S0021889811003049.Deschamps A., de Geuser F. On the validity of simple precipitate size measurements by small-angle scattering in metallic systems // J. Appl. Cryst. 2011. Vol. 44. P. 343–352. https: //doi.org/10.1107/S0021889811003049.Fedorov P.P. Criteria for the formation of fluoride glasses. Inorganic materials. 1997;33(12):1415–1424. (In Russ.).Федоров П.П. Критерии образования фторидных стекол // Неорганические материалы. 1997. Т. 33 (12). С. 1415–1424.Saad M., Poulain M. Glass forming ability Criterion. Mater. Sci. Forum. 1987;19:11–18. https: //doi.org/10.4028/www.scientific.net/MSF.19-20.11.Saad M., Poulain M. Glass forming ability Criterion // Mater. Sci. Forum. 1987. Vol. 19. P. 11–18. https: //doi.org/10.4028/www.scientific.net/MSF.19-20.11.Fedorov P.P., Luginina A.A., Popov A.I. Transparent oxyfluoride glass ceramics. J. Fluorine Chem. 2015;172:22–50. https: //doi.org/10.1016/j.jfluchem.2015.01.009.Fedorov P.P., Luginina A.A., Popov A.I. Transparent oxyfluoride glass ceramics // J. Fluorine Chem. 2015. Vol. 172. P. 22–50. https: //doi.org/10.1016/j.jfluchem.2015.01.009.Davidovich R.L., Fedorov P.P., Popov A.I. Structural chemistry of anionic fluoride and mixed-ligand fluoride complexes of indium (III). Rev. Inorg. Chem. 2016;36:105–133. https: //doi.org/10.1515/revic-2016-0009.Davidovich R.L., Fedorov P.P., Popov A.I. Structural chemistry of anionic fluoride and mixed-ligand fluoride complexes of indium (III) // Rev. Inorg. Chem. 2016. Vol. 36. P. 105–133. https: //doi.org/10.1515/revic-2016-0009.Wells A. Structural inorganic chemistry. M.: Mir; 1988. 564 p.Уэллс А. Структурная неорганическая химия. М.: Мир, 1988. 564 с.Ignatyeva L.N., Polischuk S.A., Savchenko N.N., Antokhina T.F., Marchenko Yu.V., Buznik V.M. Synthesis and features of the structure and crystallization of oxyfluoroniobate glasses. Vestnik of the FEB RAS. 2009;(2):64–71. (In Russ.).Игнатьева Л.Н., Полищук С.А., Савченко Н.Н., Антохина Т.Ф., Марченко Ю.В., Бузник В.М. Cинтез и особенности строения и кристаллизации оксифторниобатных стекол // Вестник ДВО РАН. 2009. № 2. С. 64–71.Ignatieva L.N., Marchenko Yu.V., Savchenko N.N., Merkulov E.B., Mirochnik A.G. Bismuth containing fluorozirconate glasses doped BiPO4. A glass formation, structural, crystallization and luminescent properties. J. Phys. Chem. Solids. 2021. Vol. 152. P. 109979. https: //doi.org/10.1016/j.jpcs.2021.109979.Ignatieva L.N., Marchenko Yu.V., Savchenko N.N., Merkulov E.B., Mirochnik A.G. Bismuth containing fluorozirconate glasses doped BiPO4. A glass formation, structural, crystallization and luminescent properties // J. Phys. Chem. Solids. 2021. Vol. 152. P. 109979. https: //doi.org/10.1016/j.jpcs.2021.109979.Ignatieva L.N., Savchenko N.N., Marchenko Y.V., Mashchenko V.A., Bouznik V.M. Raman study of glasses in the NbO2F-BaF2-InF3-ErF3 and CdNbOF5-BaF2-InF3 systems. Nanosystems: Phys. Chem. Math. 2020;11 (3):0–4. https: //doi.org/10.17586/2220-8054-2020-11-3-333-337.Ignatieva L.N., Savchenko N.N., Marchenko Y.V., Mashchenko V.A., Bouznik V.M. Raman study of glasses in the NbO2F-BaF2-InF3-ErF3 and CdNbOF5-BaF2-InF3 systems // Nanosystems: Phys. Chem. Math. 2020. Vol. 11 (3). P. 0–4. https: //doi.org/10.17586/2220-8054-2020-11-3-333-337.Midryi A.V., Ivanyukovich A.V., Korotkii A.V., Emtsev V.V., Yakushev M.V. Optical properties of indium nitride powder and films, J. Apl. Spectrosc. 2006;73:95–98. https: //doi.org/10.1007/s10812-006-0041-0.Midryi A.V., Ivanyukovich A.V., Korotkii A.V., Emtsev V.V., Yakushev M.V. Optical properties of indium nitride powder and films // J. Apl. Spectrosc. 2006. Vol. 73. P. 95–98. https: //doi.org/10.1007/s10812-006-0041-0.Sychikova Y.A. Photoluminescence of porous indium phosphide caused by quantum transitions in volume-confined layers. Nanostructured materials. 2015;1:25–31. (In Russ.).Сычикова Я.А. Фотолюминесценция пористого фосфида индия, обусловленная квантовыми переходами в объемно-ограниченных слоях // Наноструктурированные материалы. 2015. № 1. С. 25–31.