Wood-polymer composites based on polycondensation copolyimides

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Abstract

The paper describes a methodology for obtaining heat-resistant organosoluble and hot-melt copolyimides for subsequent use as reinforcing binders in the technology of obtaining composite materials based on cellulosecontaining components of wood origin. It is shown that 3,6-diaminoacridine; 9,9-bis-(p-aminophenyl) fluorene, 2,2-bis-(3,4-dicarboxyphenyl)-1,1,1,3,3,3-hexafluoropropane dianhydride and 3,3’,4,4’-tetracarboxydiphenyl oxide dianhydride can be used as raw materials for obtaining copolyimides in composite materials. An optimal method for synthesizing copolyimides of various compositions with a molecular weight of 20…180 kDa is presented. It is shown that in order to obtain wood-polymer composites with satisfactory properties, it is advisable to add wood dust with particles of an average diameter of 0,5...1,1 mm to the matrix of the obtained copolyimides, followed by obtaining the target product in the form of films that can be formed by casting from a solution. The solubility of the obtained polymeric materials in tetrahydrofuran, cyclohexanone, chloroform, dichloroethane, tetrachloroethane, dimethylformamide, dimethylacetamide, dimethylsulfoxide, toluene, nitromethane and acetonitrile was determined. Physicomechanical tests showed that the magnitude of the tensile stress at break of the obtained films was in the range from 140 MPa for a film 0,2 mm thick to 210 MPa for a film 0,5 mm thick, and the relative elongation at break was 5...36 %. Thermomechanical tests showed a sufficiently high heat resistance of the obtained copolyimides and composites based on them. It was established that the working temperature range of the obtained products was maintained without any damage to the shape and internal structure of the material up to a temperature of 300…320 °C. The synthesized copolymers and composites based on them can be used as heat-resistant materials.

About the authors

Andrey N. Ivankin

BMSTU (Mytishchi Branch)

Author for correspondence.
Email: aivankin@inbox.ru

Dr. Sci. (Chem.), Professor

Russian Federation, 1, 1st Institutskaya St., 141005, Mytishchi, Moscow Region

Angella N. Zarubina

BMSTU (Mytishchi Branch)

Email: zarubina@bmstu.ru

Cand. Sci. (Tech.), Associate Professor, Head of the Department of Chemistry and Chemical Technologies of the Forest Complex

Russian Federation, 1, 1st Institutskaya St., 141005, Mytishchi, Moscow Region

Aleksey S. Kuleznev

BMSTU (Mytishchi Branch)

Email: kuleznev00@bmstu.ru

Student

Russian Federation, 1, 1st Institutskaya St., 141005, Mytishchi, Moscow Region

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