Fusel fraction alcohols adsorption study on different grades of active charcoals

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Abstract

A study of the adsorption activity of four samples of initial and activated charcoal was carried out in relation to the purification from fusel group alcohols formed in the alcoholic beverage industry. One of the sorbents was active carbon obtained by activating birch charcoal in a rotary kiln with a zigzag insert. The increased interest in it is due to the fact that activation using this technology provides an increased yield and stable quality of the resulting active carbon. The values of the adsorption capacity of charcoal of different origin during the adsorption of alcohols of the fusel group were determined. The thermodynamic potentials of the sorption process are calculated. In the homologous series of alcohols, with an increase in the hydrocarbon radical by the –CH2– group, the adsorption capacity decreases, the values of the adsorption equilibrium constants increase, and for isomers the corresponding values are higher than for normal alcohols. The effectiveness of the use of active carbon obtained from industrial birch charcoal by its activation in a rotary kiln with a zigzag insert is shown.

About the authors

Yuriy L. Yur’ev

Ural State Forestry University

Author for correspondence.
Email: yurievyul@m.usfeu.ru

Dr. Sci. (Tech.), Professor of the Department of Chemical Technology of Wood, Biotechnology and Nanomaterials

Russian Federation, 37, Sibirsky tract st., 620100, Ekaterinburg

Aleksey V. Sviridov

Ural State Forestry University

Email: sviridovav@m.usfeu.ru

Cand. Sci. (Tech.), Associate Professor of the Department of Chemical Technology of Wood, Biotechnology and Nanomaterials

Russian Federation, 37, Sibirsky tract st., 620100, Ekaterinburg

Natal’ya A. Drozdova

Ural State Forestry University

Email: drozdovana@m.usfeu.ru

Cand. Sci. (Tech.), Associate Professor of the Department of Chemical Technology of Wood, Biotechnology and Nanomaterials

Russian Federation, 37, Sibirsky tract st., 620100, Ekaterinburg

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