Doklady ChemistryDoklady ChemistryДоклады Российской академии наук. Химия, науки о материалах2686-95353034-5111The Russian Academy of Sciences65191110.31857/S2686953524020021zsazmwCHEMISTRYХИМИЯResearch ArticleSynthesis of 4-amino-1,3-diarylimidazolium chloridesСинтез хлоридов 4-амино-1,3-диарилимидазолияShevchenkoM. A.ШевченкоМ. А.
Russian Federation
chern13@yandex.ruPasyukovD. V.ПасюковД. В.
Russian Federation
chern13@yandex.ruLavrentievI. V.ЛаврентьевИ. В.
Russian Federation
chern13@yandex.ruMinyaevM. E.МиняевМ. Е.
Russian Federation
chern13@yandex.ruChernyshevV. M.ЧернышевВ. М.
Russian Federation
chern13@yandex.ruPlatov South-Russian State Polytechnic University (NPI)Южно-Российский государственный политехнический университет (НПИ) имени М.И. ПлатоваN.D. Zelinsky Institute of Organic Chemistry, Russian Academy of SciencesИнститут органической химии им. Н.Д. Зелинского РАН150420245151182902022025Copyright ©; 2024, Russian Academy of SciencesCopyright ©; 2024, Российская академия наук2024Russian Academy of SciencesРоссийская академия наукhttps://journals.eco-vector.com/2686-9535/article/view/651911

The first representatives of 4-amino-1,3-diarylimidazolium chlorides have been synthesized by heating chloroacetonitrile with N,Nʹ-diarylformamidines containing alkyl substituents at positions 2 and 6 of the N-aryl groups. The possibility of postfunctionalization of the obtained aminoimidazolium salts by acylation of the amino group was demonstrated, as well as their applicability as precursors of N-heterocyclic carbenes in the synthesis of Cu/NHC complexes after preliminary protection of the amino group.

Нагреванием хлорацетонитрила с N,Nʹ-диарилформамидинами, содержащими алкильные заместители в положениях 2 и 6 N-арильных групп, синтезированы первые представители хлоридов 4-амино-1,3-диарилимидазолия. Показана возможность постфункционализации полученных аминоимидазолиевых солей путем ацилирования аминогруппы, а также их использование в качестве предшественников N-гетероциклических карбенов в синтезе комплексов Cu/NHC после предварительной защиты аминогруппы.

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