Nucleophilic Addition of Aliphatic Diamines NH2(CH2)nNH2 (n = 6, 9) to Nitrilium Derivatives of the closo-Decaborate Anion [2-B10H9NCR]– (R = CH3, C2H5, nC3H7)

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Abstract

The reaction of a number of nitrilium derivatives of the closo-decaborate anion with hexamethylene- and nonamethylenediamine has been studied. It has been shown that the process proceeds with the functionalization of both amino groups of the nucleophile to form amidines of the type (Bu4N)2[B10H9NH=C(R)NH (CH2)nNH(R)C=NHB10H9] (R = CH3, C2H5, nC3H7; n = 6, 9). Target compounds have been characterized by high resolution multinuclear NMR and ESI mass spectrometry.

About the authors

V. V. Voinova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

N. A. Selivanov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

A. Yu. Bykov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

I. N. Klyukin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
Россия, 119991, Москва, Ленинский пр-т, 31

A. P. Zhdanov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

K. Yu. Zhizhin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

N. T. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: zhdanov@igic.ras.ru
119991, Moscow, Russia

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