NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

Interaction of rare-earth oxides (Pr, Tb, Er) with periodic acid or sodium iodate under hydrothermal conditions in the presence of Na2HPO4⋅12H2O leads to formation of complex NaLn(IO3)4 iodates. The compounds of Pr and Tb are reported for the first time. Single-crystal studies reveal that they are isostructural to the previously reported analogs of other rare-earths and adopt the non-centrosymmetric space group Сс. Polycrystalline samples generate a strong SHG signal above that of the potassium dihydrogen phosphate reference standard. They also exhibit wide optical transparency areas and high thermal stability.

Авторлар туралы

O. Grigorieva

Chemistry Department, Moscow State University

Email: oksankagrigorevaa@mail.ru
119991, Moscow, Russia

S. Stefanovich

Chemistry Department, Moscow State University

Email: oksankagrigorevaa@mail.ru
119991, Moscow, Russia

D. Charkin

Chemistry Department, Moscow State University

Email: oksankagrigorevaa@mail.ru
119991, Moscow, Russia

V. Dolgikh

Chemistry Department, Moscow State University

Email: oksankagrigorevaa@mail.ru
119991, Moscow, Russia

K. Lysenko

Chemistry Department, Moscow State University

Хат алмасуға жауапты Автор.
Email: oksankagrigorevaa@mail.ru
119991, Moscow, Russia

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© О.П. Григорьева, С.Ю. Стефанович, Д.О. Чаркин, В.А. Долгих, К.А. Лысенко, 2023