Ionic and phase compositions of nanosized Y2.5Ce0.5Fe2.5Ga2.5O12 film on Gd3Ga5O12 substrate

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

The ionic and phase compositions of the nanosized Y2.5Ce0.5Fe2.5Ga2.5O12 ferrogarnet film obtained by double ion-beam deposition/sputtering on a Gd3Ga5O12 substrate were studied using X-ray diffraction analysis and X-ray photoelectron spectroscopy. The target for film production was obtained by gel combustion followed by annealing in vacuum. The X-ray diffraction results confirmed the phase homogeneity of Y2.5Ce0.5Fe2.5Ga2.5O12 both in powder and in films form and the absence of cerium dioxide impurity. At the same time, according to X-ray photoelectron spectroscopy, along with Ce3+, Ce4+ ions are present on the surface of the Y2.5Ce0.5Fe2.5Ga2.5O12 film.

Негізгі сөздер

Толық мәтін

Рұқсат жабық

Авторлар туралы

Yu. Teterin

Lomonosov Moscow State University; National Research Center “Kurchatov Institute”

Хат алмасуға жауапты Автор.
Email: ketsko@igic.ras.ru
Ресей, Moscow, 119991; Moscow, 123182

K. Maslakov

Lomonosov Moscow State University

Email: ketsko@igic.ras.ru
Ресей, Moscow, 119991

A. Serokurovа

Scientific and Practical Center on Materials Science, National Academy of Sciences of Belarus

Email: ketsko@igic.ras.ru
Белоруссия, Minsk, 220072

M. Smirnova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: ketsko@igic.ras.ru
Ресей, Moscow, 199191

G. Nikiforova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: ketsko@igic.ras.ru
Ресей, Moscow, 199191

N. Novitskiy

Scientific and Practical Center on Materials Science, National Academy of Sciences of Belarus

Email: ketsko@igic.ras.ru
Белоруссия, Minsk, 220072

S. Sharko

Scientific and Practical Center on Materials Science, National Academy of Sciences of Belarus

Email: ketsko@igic.ras.ru
Белоруссия, Minsk, 220072

A. Teterin

Lomonosov Moscow State University

Email: ketsko@igic.ras.ru
Ресей, Moscow, 119991

M. Markelova

Lomonosov Moscow State University

Email: ketsko@igic.ras.ru
Ресей, Moscow, 119991

V. Amelichev

OOO “S-Innovations”

Email: ketsko@igic.ras.ru
Ресей, Moscow, 117246

V. Ketsko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: ketsko@igic.ras.ru
Ресей, Moscow, 199191

Әдебиет тізімі

  1. Shen H., Zhao Yu, Lia L. et al. // J. Cryst. Growth. 2024. Р. 631. С. 127626. https://doi.org/10.1016/j.jcrysgro.2024.127626
  2. Звездин А.К., Котов В.А. / Современная магнитооптика и магнитооптические материалы Бока-Ратон: CRC Press, 1997. 404 с. https://doi.org/10.1887/075030362X
  3. Аплеснин С.С., Масюгин А.Н., Ситников М.Н. и др. // Письма в ЖЭТФ. 2020. Т. 112. № 10. С. 680. https://doi.org/10.31857/S1234567820220085
  4. Sharma V., Kuanr B.K. // J. Alloys Compd. 2018. V. 748. P. 591. https://doi.org/10.1016/j.jallcom.2018.03.086
  5. Lisnevskaya I.V., Bobrova I.A., Lupeiko T.G. // J. Magn. Magn. Mater. 2016. V. 397 P. 86. https://doi.org/10.1016/j.jmmm.2015.08.084
  6. Smirnova M.N., Glazkova I.S., Nikiforova G.E. et al. // Nanosystems: Physics, Chemistry, Mathematics. 2021. V. 12. Is. 2. P. 210. https://doi.org/10.17586/2220-8054-2021-12-2-210-217
  7. Тетерин Ю.А., Смирнова М.Н., Маслаков К.И. и др. // Журн. неорган. химии. 2023. Т. 68. № 7. С. 904. https://doi.org/10.31857/S0044457X23600135
  8. Смирнова М.Н., Копьева М.А., Береснев Э.Н. и др. // Журн. неорган. химии. 2018. Т. 63. С. 411. https://doi.org/10.7868/S0044457X18040037
  9. Smirnova M.N., Nikiforova G.E., Goeva L.V. et al. // Ceramics. 2019. V. 45. № 4. P. 4509. https://doi.org/10.1016/j.ceramint.2018.11.133
  10. Soboleva Ia.S., Nitsenko V.I., Sobolev A.V. et al. // Int. J. Mol. Sci. 2024. V. 25. № 3. P. 1437. https://doi.org/10.3390/ijms25031437
  11. Smirnova M.N., Nikiforova G.E., Kondrat'eva O.N. // Nanosystems: Physics, Chemistry, Mathematics. 2024. V. 15. № 2. P. 224. https://doi.org/10.17586/2220-8054-2024-15-2-224-232
  12. Maslakov K.I., Teterin Yu.A., Popel A.J. et al. // Appl. Surf. Sci. 2018. V. 448. P. 154. https://doi.org/10.1016/j.apsusc.2018.04.077
  13. Shirley D.A. // Phys. Rev. B. 1972. V. 5. P. 4709. https://doi.org/10.1103/PhysRevB.5.4709
  14. Панов А.П. Пакет программ обработки спектров SPRO и язык программирования SL: Препринт. М.: Ин-т атом. энергии, ИАЭ-6019/15, 1997. 31 с.
  15. Стогний А.И., Новицкий Н.Н., Голикова О.Л. и др. // Неорган. материалы. 2017. Т. 53. № 10. С. 1093. https://doi.org/10.7868/S0002337X17100116
  16. Sharko S.A., Serokurova A.I., Novitskii N.N. et al. // Ceramics. 2023. V. 6. № 3. P. 1415. https://doi.org/10.339/nano12030470
  17. Sosulnikov M.I., Teterin Yu.A. // J. Electron Spectrosc. Relat. Phenom. 1992. V.59. P. 111. https://doi.org/10.1016/0368-2048(92)85002-O
  18. Bagus P.S., Nelin C.J., Brundle C.R. et al. // J. Chem. Phys. 2021. V. 154. P. 094709. https://doi.org/10.1063/5.0039765
  19. Grosvenor A.P., Kobe B.A., Biesinger M.C., McIntyre N.S. // Surf. Interface Anal. 2004. V. 36. P. 1564. https://doi.org/10.1002/sia.1984
  20. Descostes M., Mercier F., Thromat N. et al. // Appl. Surf. Sci. 2000. V. 165. P. 288. https://doi.org/10.1016/S0169-4332(00)00443-8
  21. Teterin Yu.A., Perfil’ev Yu.D., Maslakov K.I. // J. Struct. Chem. 2022. V. 63. № 10. P. 1649. https://doi.org/10.1134/S0022476622100110
  22. Wendin G. Breakdown of the One-Electron Pictures in Photoelectron Spectra. Structure and Bonding, V. 45. Berlin, Heidelberg: Springer, 1981. 123 p. https://doi.org/10.1007/BFb0111504
  23. Van Vleck J.H. // Phys. Rev. 1934. V. 45. № 5. P. 405. https://doi.org/10.1103/PhysRev.45.405
  24. Yarzhemsky V.G., Teterin Y.A., Presnyakov I.A. // JETP Letters. 2020. V. 111. № 8. P. 422. https://doi.org/10.1134/S0021364020080135
  25. Teterin Yu.A., Bondarenko T.N., Teterin A.Yu. // J. Electron Spectrosc. Relat. Phenom. 1998. V. 96. P. 221. https://doi.org/10.1016/S0368-2048(98)00240-0

Қосымша файлдар

Қосымша файлдар
Әрекет
1. JATS XML
Жүктеу
2. Fig. 1. Powder diffraction pattern of the YCFG sample.

Жүктеу (38KB)
Метадеректер
3. Fig. 2. Diffraction pattern of the YCFG film on the single-crystal GGG (111) substrate.

Жүктеу (17KB)
Метадеректер
4. Fig. 3. Surface image of the YCFG film with a thickness of ~80 nm and its cross section (in the inset).

Жүктеу (7KB)
Метадеректер
5. Fig. 4. XPS spectrum of O1s electrons of the film: a - initial sample; b - after cleaning with Ar+ ions.

Жүктеу (27KB)
Метадеректер
6. Fig. 5. XPS spectrum of Fe2p electrons of the film: a - initial sample; b - after cleaning with Ar+ ions.

Жүктеу (26KB)
Метадеректер
7. Fig. 6. XPS spectra of Fe3s, Ga3p, and Ce4d electrons of the film: a - initial sample; b - after cleaning with Ar+ ions.

Жүктеу (32KB)
Метадеректер
8. Fig. 7. XPS spectra of Ce3d electrons of the film: a - initial sample; b - after cleaning with Ar+ ions.

Жүктеу (48KB)
Метадеректер

© Russian Academy of Sciences, 2025