Synthesis, Structures, and Spectral Properties of Octa(2,6-difluorophenyl)tetraazaporphyrin and Its Cu(II) and Ni(II) Complexes

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Resumo

Octa(2,6-difluorophenyl)tetraazaporphyrinate magnesium(II) has been treated with 96% sulfuric acid to obtain octa(2,6-difluorophenyl)tetraazaporphyrin. Coordination reactions of octa(2,6-difluorophenyl)tetraazaporphyrin and metal exchange of its magnesium complex with copper and nickel salts in dimethylformamide have been studied. Cu(II) and Ni(II) complexes with octa(2,6-difluorophenyl)tetraazaporphyrin have been synthesized. The resulting compounds have been identified by electron absorption, IR and 1H NMR spectroscopy, and mass spectrometry. The structures of the synthesized compounds were optimized by the DFT method. The fluorescence quantum yields of the studied compounds have been determined.

Sobre autores

A. Rusanov

Krestov Institute of Solutions Chemistry, Russian Academy of Sciences

Email: ngm@isc-ras.ru
153040, Ivanovo, Ivanovo oblast, Russia

N. Chizhova

Krestov Institute of Solutions Chemistry, Russian Academy of Sciences

Email: ngm@isc-ras.ru
153040, Ivanovo, Ivanovo oblast, Russia

A. Likhonina

Krestov Institute of Solutions Chemistry, Russian Academy of Sciences

Email: ngm@isc-ras.ru
153040, Ivanovo, Ivanovo oblast, Russia

N. Mamardashvili

Krestov Institute of Solutions Chemistry, Russian Academy of Sciences

Autor responsável pela correspondência
Email: ngm@isc-ras.ru
153040, Ivanovo, Ivanovo oblast, Russia

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Declaração de direitos autorais © А.И. Русанов, Н.В. Чижова, А.Е. Лихонина, Н.Ж. Мамардашвили, 2023