3D coordination polymers with N-heterocyclic Ga(I) moieties

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Abstract

The reactions of bimetallic acenaphthene-1,2-diimine complex [(Dpp-bian-GaCr(CO)5]2- [Na(Thf)2]2 (I) (Dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) with 4,4ʹ-bipyridine (4,4ʹ-Bipy) and 1,3-bis(4-pyridyl)propane (Bpp) in THF gave 3D coordination polymers [{(Dppbian) GaCr(CO)5}{Na(4,4ʹ-Bipy)3}]n (II) and [(Dpp-bian)GaCr(CO)4Na(Et2O)(Bpp)1,5]n (III), respectively. Compounds II and III were characterized by elemental analysis and NMR and IR spectroscopy. The molecular structure of II was established by X-ray diffraction (CCDC no. 2278024).

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About the authors

Т. S. Koptseva

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: igorfed@iomc.ras.ru
Russian Federation, Nizhny Novgorod

E. V. Baranov

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: igorfed@iomc.ras.ru
Russian Federation, Nizhny Novgorod

I. L. Fedushkin

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: igorfed@iomc.ras.ru
Russian Federation, Nizhny Novgorod

References

  1. Hadlington T.J., Driess M., Jones C. // Chem. Soc. Rev. 2018. V. 47. P. 4176.
  2. Chu T., Nikonov G.I. // Chem. Rev. 2018. V. 118. P. 3608.
  3. Zhong M., Sinhababu S., Roesky H.W. // Dalton Trans. 2020. V. 49. P. 1351.
  4. Hardman N.J., Eichler B.E., Power Ph.P. // Chem. Commun. 2000. № 20. P. 1991.
  5. Jin G., Jones C., Junk P.C., Stasch A. et al. // New J. Chem. 2008. V. 32. P. 835.
  6. Overgaard J., Jones C., Dange D., Platts J.A. // Inorg. Chem. 2011. V. 50. P. 8418.
  7. Jones C., Junk P.C., Platts J.A., Stasch A. // J. Am. Chem. Soc. 2006. V. 128. № 7. P. 2206.
  8. Schmidt E.S., Jockisch A., Schmidbaur H. // J. Am. Chem. Soc. 1999. V. 121. № 41. P. 9758.
  9. Schmidt E.S., Schier A., Schmidbaur H. // Dalton Trans. 2001. № 5. P. 505.
  10. Baker R.J., Farley R.D., Jones C. et al. // Dalton Trans. 2002. № 20. P. 3844.
  11. Dange D., Choong S.L., Schenk Ch. et al. // Dalton Trans. 2012. V. 41. P. 9304.
  12. Morris L.J., Rajeshkumar T., Maron L., Okuda J. // Chem. Eur. J. 2022. V. 28. № 56. P. e202201480.
  13. Seifert A., Scheid D., Linti G., Zessin T. // Chem. Eur. J. 2009. V. 15. № 44. P. 12114.
  14. Jones C., Mills D.P., Rose R.P. // J. Organomet. Chem. V. 691. № 13. P. 3060.
  15. Kassymbek A., Britten J. F., Spasyuk D. et al. // Inorg. Chem. 2019. V. 58. № 13. P. 8665.
  16. Kassymbek A., Vyboishchikov S.F., Gabidullin B.M. et al. // Angew. Chem. Int. Ed. 2019. V. 58. P. 18102.
  17. Baker R.J., Jones C., Platts J.A. // Dalton Trans. 2003. № 19. P. 3673.
  18. Baker R.J., Jones C., Platts J.A. // J. Am. Chem. Soc. 2003. V. 125. № 35. P. 10534.
  19. Aldridge S., Baker R.J., Coombs N.D. et al. // Dalton Trans. 2006. № 27. P. 3313.
  20. Jones C., Mills D.P., Rose R.P. et al. // J. Organomet. Chem. V. 695. № 22. P. 2410.
  21. Fedushkin I.L., Sokolov V.G., Piskunov A.V. et al. // Chem. Commun. 2014. V. 50. P. 10108.
  22. Fedushkin I.L., Sokolov V.G., Makarov V.M. et al. // Russ. Chem. Bull. V. 65. № 6. P. 1495.
  23. Sokolov V.G., Skatova A.A., Piskunov A.V. et al. // Russ. Chem. Bull. V. 69. № 8. P. 1537.
  24. Dodonov V.A., Sokolov V.G., Baranov E.V. et al. // Inorg. Chem. 2022. V. 61. № 38. P. 14962.
  25. Zhang R., Wang Y., Zhao Y. et al. // Dalton Trans. 2021. V. 50. № 39. P. 13634.
  26. Koptseva T.S., Sokolov V.G., Ketkov S.Yu. et al. // Chem. Eur. J. 2021. V. 27. № 18. P. 5745.
  27. Sokolov V.G., Koptseva T.S., Rumyantcev R.V. et al. // Organometallics. 2020. V. 39. № 1. P. 66.
  28. Koptseva T.S., Bazyakina N.L., Baranov E.V., Fedushkin I.L. // Mendeleev Commun. 2023. V. 33. P. 167.
  29. Koptseva T.S., Moskalev M.V., Baranov E.V., Fedushkin I.L. // Organometallics. 2023. V. 42. P. 965.
  30. Koptseva T.S., Bazyakina N.L., Moskalev M.V. et al. // Eur. J. Inorg. Chem. 2021. № 7. P. 675.
  31. Koptseva T.S., Bazyakina N.L., Rumyantcev R.V., Fedushkin I.L. // Mendeleev Commun. 2022. V. 32. P. 780.
  32. Data Collection, Reduction and Correction Program. CrysAlisPro 1.171.42.76а — Software Package, Rigaku OD, 2022.
  33. Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. P. 3.
  34. Sheldrick G.M. SHELXTL. Version 6.14. Structure Determination Software Suite; Madison (WI, USA): Bruker AXS, 2003.
  35. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3.
  36. SCALE3 ABSPACK: Empirical Аbsorption Сorrection, CrysAlisPro 1.171.42.76а — Software Package, Rigaku OD, 2022.
  37. Blatov V.A., Shevchenko A.P., Proserpio D.M. // Cryst. Growth Des. 2014. V. 14. P. 3576.
  38. Spek A.L. // Acta Cryst. 2009. V. 65. P. 148.
  39. Macrae C.F., Sovago I., Cottrell S.J. et al. // J. Appl. Cryst. 2020. V. 53. P. 226.
  40. Sikma R.E., Balto K.P., Figueroa J.S., Cohen S.M. // Angew. Chem. Int. Ed. 2022. V. 61. Art e202206353.

Supplementary files

Supplementary Files
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1. JATS XML
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2. Scheme 1.

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3. Scheme 2.

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4. Fig. 1. 1H NMR spectrum of compound II (400 MHz, C4D8O, 298 K).

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5. Fig. 2. Thermogravimetric analysis II.

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6. Fig. 3. Fragments of crystal packing II: along the crystallographic axis b (a); general view (b). Thermal ellipsoids of atoms of the anionic Ga—Cr complexes are shown with 30% probability. Hydrogen atoms, Ar substituents, and solvate molecules of toluene with THF are not shown. The index A denotes symmetrically equivalent atoms.

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7. Fig. 4. Superposition of two independent molecules of the ionic complex (Dpp-bian)GaCr(CO)5 in II. Thermal ellipsoids with 30% probability are shown. Hydrogen atoms are not shown. The numbering for the first and second molecules of (Dpp-bian)GaCr(CO)5 (with green and brown bonds), respectively, is given through the symbol “|”.

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8. Fig. 5. Visualization of voids in crystal II using the Mercury program [39].

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9. Rice. 6. 1H NMR spectrum of compound III (400 MHz, C4D8O, 298 K).

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10. Rice. 7. Thermogravimetric analysis III.

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11. Fig. 8. Asymmetric part of the 3D structure III (a) and fragments of the crystal packing of III in projection onto the plane b0c (b) and a0c (c). The index A denotes symmetrically equivalent atoms.

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12. Fig. 9. Visualization of voids in crystal III using the Mercury program [39].

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