SOLVOTHERMAL SYNTHESIS, STRUCTURE, AND PROPERTIES OF CADMIUM(II)-ORGANIC COORDINATION POLYMER CONTAINING CARBOXYL GROUPS

B. Xu; Сюй Б.; W. Yao; Яо В.; S. Yu; Юй С.; D. G. Samsonenko; Самсоненко Д. Г.; V. P. Fedin; Федин В. П.; E. Gao; Гао Э.

doi:10.31857/S0132344X23600133

SOLVOTHERMAL SYNTHESIS, STRUCTURE, AND PROPERTIES OF CADMIUM(II)-ORGANIC COORDINATION POLYMER CONTAINING CARBOXYL GROUPS

Authors: Xu B.¹, Yao W.¹, Yu S.²^,3, Samsonenko D.G.², Fedin V.P.²^,3, Gao E.¹
Affiliations:
1. China-Russian Institute of Engineering Materials Chemistry, School of Chemical Engineering, University of Science and Technology Liaoning, Anshan, 114051, China
2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia
3. Novosibirsk State University, 630090, Novosibirsk, Russia
Issue: Vol 49, No 12 (2023)
Pages: 731-736
Section: Articles
URL: https://journals.eco-vector.com/0132-344X/article/view/667631
DOI: https://doi.org/10.31857/S0132344X23600133
EDN: https://elibrary.ru/LPTJNX
ID: 667631

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Abstract

Under the conditions of solvothermal synthesis, a new metal-organic coordination polymer of the composition Cd[H2L] (I, H4L = 4,4'-([2,2'-bipyridine]-6,6'-diylbis(oxy))diphthalic acid). According to X-ray diffraction analysis, each Cd(II) cation binds four organic ligands: one via the coordination of the chelate bipyridyl fragment, two via the bidentate coordination of deprotonated COO groups, and one more via the monodentate coordination of the protonated carboxylate group. The obtained three-dimensional metal-organic framework does not contain free space capable of including guest molecules. Compound I was characterized by powder X-ray diffraction, IR spectroscopy, elemental (C, H, N) and thermogravimetric analyses, and luminescence spectra were recorded for it.

Keywords

metal-organic coordination polymers, synthesis, X-ray diffraction analysis, polycarboxylate ligands, cadmium(II) complexes, luminescence

References

Agafonov M.A., Alexandrov E.V., Artyukhova N.A. et al. // J. Struct. Chem. 2022. V. 63. P. 671.
Kirchon A., Feng L., Drake H.F. et al. // Chem. Soc. Rev. 2018. V. 47. P. 8611.
Bhadra B.N., Ahmed I., Lee H.J., Jhung S.H. // Coord. Chem. Rev. 2022. V. 450. Art. 214237.
Yin H.-Q., X.-B. Yin // Acc. Chem. Res. 2020. V. 53. P. 485.
Ji Z., Wang H., Canossa S. et al. // Adv. Funct. Mater. 2020. V. 30. Art. 2000238.
Mandal S., Natarajan S., Mani P., Pankajakshan A. // Adv. Funct. Mater. 2021. V. 31. Art. 2006291.
Razavi S.A.A., Morsali A. // Coord. Chem. Rev. 2019. V. 399. Art. 213023.
Bruker Apex3 Software Suite: Apex3, SADABS-2016/2 and SAINT. Version 2018.7-2. Madison (WI, USA): Bruker AXS Inc., 2017.
Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. № 1. P. 3.
Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. № 1. P. 3.
Llunell M., Casanova D., Cirera J. et al. SHAPE. Version 2.1. Program for the Stereochemical Analysis of Molecular Fragments by Means of Continuous Shape Measures and Associated Tools. Barcelona: Universitat de Barcelona, 2013.
Shigematsu A., Yamada T., Kitagawa H. // J. Am. Chem. Soc. 2011. V. 133. P. 2034.
He T., Zhang Y.Z., Wu H. et al. // ChemPhysChem. 2017. V. 18. P. 3245.
Sun Z., Yu S., Zhao L. et al. // Chem. Eur. J. 2018. V. 24. № 2018. P. 10829.
Qin Y., Xue M.-H., Dou B.-H. et al. // New J. Chem. 2020. V. 44. P. 2741.
Su J., He W., Li X.-M. et al. // Matter. 2020. V. 2. P. 711.