Формирование на поверхности древесины прозрачных защитных покрытий на основе биоцидных комплексов Mn(II)

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Abstract

Описано формирование на поверхности древесины биостойкого защитного покрытия на основе ацетатных комплексов Mn(II) с 1,10-фенантролином. Описан синтез ацетатных моно-, бис- и трис-хелатных комплексов Mn(II) с 1,10-фенантролином и проведено их исследование методами ИК-спектроскопии и термогравиметрии. Для ацетатных комплексов Mn(II) с 1,10-фенантролином осуществлено изучение их фунгистатической активности по отношению к грибам Ulocladium sp. Исследованы физико-механические свойства новых прозрачных защитных покрытий на древесине, в состав которых в качестве активных биоцидных компонентов входят данные соединения. Прозрачные защитные покрытия представляют собой двухслойные системы с предварительно нанесенным на поверхность древесины первичным пропиточным слоем активного биоцидного компонента – ацетатных 1,10-фенантролиновых комплексов Mn(II) и вторым защитным слоем кремнийорганического лака КО-921 на основе полиметилфенилсилоксановой смолы. Представлены результаты атмосферных погодных испытаний образцов древесины (заболонь сосны) с нанесенными прозрачными защитными покрытиями в плане их способности предотвращать биоразрушение древесины в условиях тропического саванного климата Совместного Российско-Вьетнамского Тропического научно-исследовательского и технологического центра (далее – Российско-Вьетнамского Тропического центра).

About the authors

V. N. Demidov

National Research Centre 'Kurchatov Institute' – PIKN – IChS

199155, Russia, Saint Petersburg, nab. Makarova, 2

I. N. Tsvetkova

National Research Centre 'Kurchatov Institute' – PIKN – IChS

199155, Russia, Saint Petersburg, nab. Makarova, 2

C. V. Nguyen

Primorsky Branch of the Joint Russian-Vietnamese Tropical Research and Technology Centre

5712, Vietnam, Nha Trang, Nguyen Thien Thuat Street, 30

V. I. Voshchikov

National Research Centre 'Kurchatov Institute' – PIKN – IChS

199155, Russia, Saint Petersburg, nab. Makarova, 2

Y. A. Khamidulin

National Research Centre 'Kurchatov Institute' – PIKN – IChS

199155, Russia, Saint Petersburg, nab. Makarova, 2

E. V. Bogomolova

V. L. Komarov Botanical Institute of the Russian Academy of Sciences

197022, Russia, Saint Petersburg, Prof. Popov St., 2, lit. B

T. B. Pakhomova

Saint Petersburg State Technological Institute (Technical University)

190013, Russia, Saint Petersburg, Moskovsky Ave., 24–26/49, lit. A

O. A. Shilova

National Research Centre 'Kurchatov Institute' – PIKN – IChS

199155, Russia, Saint Petersburg, nab. Makarova, 2

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