The effect of a magnetic field on the generation of free radicals in the interaction of quaternary ammonium compounds with hydroperoxides

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The magnetic effects (ME) of a moderate magnetic field (MF, 600 mT) on the rate of radical generation (Wi) in mixed micellar systems of quaternary ammonium compounds with hydroperoxides (QAC-ROOH), measured by the inhibitor method, and the effect of magnetic field on the rate of radical polymerization initiated by radicals, generated from the surface by QAC chemisorbed on a solid carrier upon interaction with hydroperoxide dissolved in the monomer are compared. It has been established that in micellar solutions MF reduces Wi, ME ≈ –0.45. In the case of radical polymerization of styrene containing cumyl hydroperoxide on the surface of mica plates with a chemisorbed monolayer of QAC (CTAB or ACh), the polymerization rate increases in MF.

作者简介

D. Krugovov

Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: kagur1982@mail.ru
俄罗斯联邦, Moscow

A. Gatin

Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: kagur1982@mail.ru
俄罗斯联邦, Moscow

N. Potapova

Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: kagur1982@mail.ru
俄罗斯联邦, Moscow

V. Kondratovich

Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: kagur1982@mail.ru
俄罗斯联邦, Moscow

E. Mengele

Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: kagur1982@mail.ru
俄罗斯联邦, Moscow

O. Kasaikina

Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: kagur1982@mail.ru
俄罗斯联邦, Moscow

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