Kinetics of thermal decomposition of methyl derivatives of 7H-difurazanofuxanoazepine and 7H-tryfurasanoazepine
- Authors: Kazakov A.I.1, Lempert D.B.1, Nabatova A.V.1, Ignatieva E.L.1, Dashko D.V.2, Raznoschikov V.V.1, Yanovskiy L.S.1,3
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Affiliations:
- Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
- “Tekhnolog” Special Design and Technological Bureau
- Moscow Energetic Institute
- Issue: Vol 43, No 4 (2024)
- Pages: 29-36
- Section: Kinetics and mechanism of chemical reactions, catalysis
- URL: https://journals.eco-vector.com/0207-401X/article/view/674958
- DOI: https://doi.org/10.31857/S0207401X24040043
- EDN: https://elibrary.ru/VFHJIF
- ID: 674958
Cite item
Abstract
The thermal stability of N-methyl derivatives of 7H-difurasanofuroxanoazepine and 7H-trifurazanoazepine in non-isothermal and isothermal modes has been studied. Formal-kinetic regularities of decomposition and temperature dependences of reaction rate constants have been determined. The thermal stability methyl, propargyl, cyanomethyl, allyl and amine derivatives of azepines is compared.
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About the authors
A. I. Kazakov
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: akazakov@icp.ac.ru
Russian Federation, Chernogolovka
D. B. Lempert
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Email: akazakov@icp.ac.ru
Russian Federation, Chernogolovka
A. V. Nabatova
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Email: akazakov@icp.ac.ru
Russian Federation, Chernogolovka
E. L. Ignatieva
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Email: akazakov@icp.ac.ru
Russian Federation, Chernogolovka
D. V. Dashko
“Tekhnolog” Special Design and Technological Bureau
Email: akazakov@icp.ac.ru
Russian Federation, St. Petersburg
V. V. Raznoschikov
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Email: akazakov@icp.ac.ru
Russian Federation, Chernogolovka
L. S. Yanovskiy
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences; Moscow Energetic Institute
Email: akazakov@icp.ac.ru
Russian Federation, Chernogolovka; Moscow
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