Kinetics of thermal decomposition of polymethylmethacrylate in a carbon dioxide environment
- 作者: Salgansky E.A.1, Salganskaya M.V.1, Glushkov D.O.2
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隶属关系:
- FRC of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
- National Research Tomsk Polytechnic University
- 期: 卷 43, 编号 8 (2024)
- 页面: 3-9
- 栏目: Kinetics and mechanism of chemical reactions, catalysis
- URL: https://journals.eco-vector.com/0207-401X/article/view/681879
- DOI: https://doi.org/10.31857/S0207401X24080017
- ID: 681879
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详细
A thermogravimetric analysis of the thermal decomposition of polymethylmethacrylate (PMMA) in a carbon dioxide flow was carried out. The kinetic constants of the process were determined. The heating rate of the sample varied over a wide range and amounted to 2, 5, 8, 20, 35 and 50 K/min. The values of the kinetic constants of PMMA decomposition were determined using the isoconversional method. For the degree of conversion of the substance from 10 to 90%, the values of activation energy for the thermal decomposition of PMMA vary in the range from 213.5 to 194.3 kJ/mol, and the values of the pre-exponential coefficient change in the range from 1.62 ⋅ 1016 to 6.85 ⋅ 1012 1/s. The average activation energy for the thermal decomposition of PMMA in a carbon dioxide flow was 206 kJ/mol.
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作者简介
E. Salgansky
FRC of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: sea@icp.ac.ru
俄罗斯联邦, Chernogolovka
M. Salganskaya
FRC of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Email: sea@icp.ac.ru
俄罗斯联邦, Chernogolovka
D. Glushkov
National Research Tomsk Polytechnic University
Email: sea@icp.ac.ru
俄罗斯联邦, Tomsk
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