The Influence of Ionizing Radiation on the Thermo-oxidative Stabilization Processes of the PAN Precursor for Carbon Fiber Production. Review

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Currently, issues related to reducing costs and improving environmental efficiency are becoming increasingly relevant in the process of carbon fiber production. The article presents the results of research and developments conducted over the past few decades in the field of using ionizing radiation for the pre-treatment of polyacrylonitrile fiber (PAN) before thermo-oxidative stabilization in production, aimed at reducing the cost of technology and improving the properties of the resulting carbon fibers. The processes of free radical formation and the mechanisms of cyclization initiation of irradiated fibers are discussed.

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作者简介

Shavkat Nurmatov

Institute of Material Science of the Physics-Sun SPA of the Academy of Sciences of Uzbekistan

Email: sh.nurmatov@imssolar.uz
ORCID iD: 0000-0002-7206-5220
Scopus 作者 ID: 12039741100

Cand. Sci. (Eng.), Senior Researcher, Deputy of Science

乌兹别克斯坦, Tashkent

Marina Rumi

Institute of Material Science of the Physics-Sun SPA of the Academy of Sciences of Uzbekistan

Email: marinarumi@yandex.ru
ORCID iD: 0000-0002-7895-1688
SPIN 代码: 6412-2848

Cand. Sci. (Chem.), Senior Researcher of the Laboratory of Heat-Accumulating, Heat-Insulating Materials and Solar Technologies

乌兹别克斯坦, Tashkent

Ella Urazaeva

Institute of Material Science of the Physics-Sun SPA of the Academy of Sciences of Uzbekistan

Email: panch100@yandex.ru
ORCID iD: 0000-0002-4769-3911
SPIN 代码: 5271-6086
Scopus 作者 ID: 8609839500

Junior Researcher of the Laboratory of Heat-Accumulating, Heat-Insulating Materials and Solar Technologies

乌兹别克斯坦, Tashkent

Mars Zufarov

Institute of Material Science of the Physics-Sun SPA of the Academy of Sciences of Uzbekistan

Email: marsuz@mail.ru
ORCID iD: 0000-0002-4518-5139
SPIN 代码: 5586-2755
Scopus 作者 ID: 6602113597

Junior Researcher of the Laboratory of Heat-Accumulating, Heat-Insulating Materials and Solar Technologies

乌兹别克斯坦, Tashkent

Elvira Mansurova

Institute of Material Science of the Physics-Sun SPA of the Academy of Sciences of Uzbekistan

Email: elvirauz@mail.ru
ORCID iD: 0000-0003-1286-3228
SPIN 代码: 5485-8627
Scopus 作者 ID: 6603604220

Junior Researcher of the Laboratory of Heat-Accumulating, Heat-Insulating Materials and Solar Technologies

乌兹别克斯坦, Tashkent

Sukhrob Gulmatov

Institute of Material Science of the Physics-Sun SPA of the Academy of Sciences of Uzbekistan

Email: suxrobgulmatov16024@gmail.com
ORCID iD: 0009-0001-4492-5641

Junior Researcher of the Laboratory of Solar Technologies and Nanostructured Functional Materials

乌兹别克斯坦, Tashkent

Izzat Mirzohidov

Institute of Material Science of the Physics-Sun SPA of the Academy of Sciences of Uzbekistan

Email: mirzokhidovizzat@gmail.com
ORCID iD: 0009-0007-7331-6443

Specialist of the Laboratory of Light and Extremely Durable Alternative Energy from Carbon Fiber

乌兹别克斯坦, Tashkent

Navruzbek Kenjayev

Institute of Material Science of the Physics-Sun SPA of the Academy of Sciences of Uzbekistan

Email: navruzbekenjayev@gmail.com
ORCID iD: 0009-0004-6062-6344

Research Intern

乌兹别克斯坦, Tashkent

Rakhimjon Urinboyev

Institute of Material Science of the Physics-Sun SPA of the Academy of Sciences of Uzbekistan

编辑信件的主要联系方式.
Email: rahimjonravshanovich1990@gmail.com

PhD Student

乌兹别克斯坦, Tashkent

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2. Fig. 1. Molecular structure of polyacrylonitrile precursor [32]

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3. Fig. 2. Structure of oxidized PAN as a result of stabilization in air, reflecting different degrees of oxidation of molecules [4]

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4. Fig. 3. Free radical structure used for computer simulations [3]

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5. Fig. 4. Thermostabilizing mechanism of PAN fibers irradiated by electrons [25]

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6. Fig. 5. Scheme of formation of secondary free radicals under the influence of γ-radiation on copolymer PAN [9]

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7. Fig. 6. Cycling initiation mechanism for γ-irradiated PAN fibers during heat treatment [36]

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8. Fig. 7. Mechanism of initiation of cycling of heat-treated PAN precursors after electron beam learning [18]

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