Adsorption properties of single gold, nickel and platinum nanoparticles deposited on the silicon surface

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Abstract

Gold, nickel and platinum nanoparticles were synthesized by impregnating the monocrystalline silicon surface with precursors (an aqueous solution of the corresponding salt). The morphology of formed nanostructured coatings has been studied, the electronic structure and adsorption properties of synthesized nanoparticles with respect to H2, O2, and H2O have been determined. It was found that oxidized nickel nanoparticles are reduced by molecular hydrogen, and unalloyed platinum nanoparticles are oxidized by molecular oxygen already at room temperature, which is not observed for particles deposited in a similar way on highly oriented pyrolytic graphite. We also found that the formation of water molecules on gold nanoparticles in interaction with H2 and O2 proceeds in two stages, unlike the three-stage process (sequential exposure in H2, O2, H2) which is characteristic of nanoparticles deposited on graphite. Differences in the adsorption properties of nanoparticles of the same type deposited on graphite and silicon are associated with the adsorption of a significant amount of test gases on the latter.

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A. K. Gatin

Федеральный исследовательский центр химической физики им. Н.Н. Семенова РАН

Email: mvgrishin68@yandex.ru
Russian Federation, ул. Косыгина, 4, корп. 1, Москва, 119991

S. A. Ozerin

Федеральный исследовательский центр химической физики им. Н.Н. Семенова РАН

Email: mvgrishin68@yandex.ru
Russian Federation, ул. Косыгина, 4, корп. 1, Москва, 119991

P. K. Ignateva

Федеральный исследовательский центр химической физики им. Н.Н. Семенова РАН; Федеральное государственное автономное образовательное учреждение высшего образования “Московский физико-технический институт (национальный исследовательский университет)”

Email: mvgrishin68@yandex.ru
Russian Federation, ул. Косыгина, 4, корп. 1, Москва, 119991; пер. Институтский, 9, Долгопрудный, Московская обл., 141701

V. A. Kharitonov

Федеральный исследовательский центр химической физики им. Н.Н. Семенова РАН

Email: mvgrishin68@yandex.ru
Russian Federation, ул. Косыгина, 4, корп. 1, Москва, 119991

S. Y. Sarvadii

Федеральный исследовательский центр химической физики им. Н.Н. Семенова РАН

Email: mvgrishin68@yandex.ru
Russian Federation, ул. Косыгина, 4, корп. 1, Москва, 119991

M. V. Grishin

Федеральный исследовательский центр химической физики им. Н.Н. Семенова РАН

Author for correspondence.
Email: mvgrishin68@yandex.ru
Russian Federation, ул. Косыгина, 4, корп. 1, Москва, 119991

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2. Fig. 1. Gold nanoparticles applied by impregnation onto the surface of oxidized silicon: a – topographic image of a surface area, b – profile along the line indicated on the topographic image, c – averaged I–V characteristics of silicon (curve 1) and gold (curve 2).

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3. Fig. 2. I–V characteristics of gold nanoparticles measured after exposure to H2 (a), O2 (b) and H2O (c).

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4. Fig. 3. Oxidized silicon single crystal with deposited nickel nanoparticles: a – topographic image of a surface area, b – profile along the line indicated on the topographic image, c – current-voltage characteristics of the substrate (curve 1) and nanoparticles (curve 2).

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5. Fig. 4. I–V characteristics of nickel deposited on the surface of oxidized silicon (a) after exposure to H2 and (b) after exposure to H2O.

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6. Fig. 5. Oxidized silicon single crystal with deposited platinum nanoparticles: a – topographic image of a surface area, b – profile along the line indicated on the topographic image, c – current-voltage characteristics of the substrate (curve 1) and nanoparticles (curve 2).

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7. Fig. 6. I–V characteristics of platinum nanoparticles deposited on the surface of oxidized silicon (a) after exposure to H2, (b) after exposure to O2.

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