IN SITU ENCAPSULATION OF NICKEL NANOPARTICLES IN POLYSACCHARIDE SHELLS DURING THEIR FABRICATION BY ELECTRICAL EXPLOSION OF WIRE

A. P. SAFRONOV; Сафронов А. П.; I. V. BEKETOV; Бекетов И. В.; A. V. BAGAZEEV; Багазеев А. В.; A. I. MEDVEDEV; Медведев А. И.; A. M. MURZAKAEV; Мурзакаев А. М.; T. V. TERZIYAN; Терзиян Т. В.; A. YU. ZUBAREV; Зубарев А. Ю.

doi:10.31857/S0023291223600311

IN SITU ENCAPSULATION OF NICKEL NANOPARTICLES IN POLYSACCHARIDE SHELLS DURING THEIR FABRICATION BY ELECTRICAL EXPLOSION OF WIRE

Autores: SAFRONOV A.P.¹^,2, BEKETOV I.V.¹^,2, BAGAZEEV A.V.¹, MEDVEDEV A.I.¹^,2, MURZAKAEV A.M.¹^,2, TERZIYAN T.V.², ZUBAREV A.Y.²
Afiliações:
1. Institute of Electrophysics, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia
2. Yeltsin Ural Federal University, Yekaterinburg, Russia
Edição: Volume 85, Nº 4 (2023)
Páginas: 463-475
Seção: Articles
##submission.dateSubmitted##: 27.02.2025
##submission.datePublished##: 01.07.2023
URL: https://journals.eco-vector.com/0023-2912/article/view/671345
DOI: https://doi.org/10.31857/S0023291223600311
EDN: https://elibrary.ru/OOMKCN
ID: 671345

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Resumo

Nickel nanoparticles are obtained by electrical explosion of wire under the action of a high-voltage discharge followed by condensation in an inert gas medium. When butane is added to the gas medium, a carbon shell is deposited onto the condensing nickel particles. Immediately after the synthesis, liquid-phase modification of nanoparticles is carried out with aqueous solutions of polysaccharides agarose and gellan. As a result, a polymer shell is formed on particles of Ni and nickel particles coated with a carbon shell (Ni@C). The dispersity, crystalline structure, and magnetic properties of Ni and Ni@C nanoparticles are characterized by transmission microscopy, X-ray diffraction analysis, and vibration magnetometry. The total carbon
content on the surface of the nanoparticles is determined by thermal analysis with simultaneous mass spectrometry. It is shown that, under the studied conditions, polysaccharides are deposited onto the nanoparticles in amounts up to 2 wt % to form a shell with a thickness of about 4 nm. When agarose is used as a modifier, the content of the polysaccharide increases with the concentration of the modifying solution. When gellan is used as a modifier, a more complex concentration dependence is observed: an initial increase is followed by a decrease in the amount of deposited polysaccharide. The results are discussed from the viewpoint of the influence of the molecular weight of a polymer on the adsorption process.

Palavras-chave

ELECTRICAL EXPLOSION OF WIRE, NANOPARTICLES, NICKEL, POLYMER SHELLS, AGAROSE, GELLAN

Bibliografia

Гусев А.И. Наноматериалы, наноструктуры, нанотехнологии. М.: Физматлит, 2009. 416 с.
Kim Y., Zhao X. Magnetic soft materials and robots // Chemical Reviews. 2022. V. 122. № 5. P. 5317–5364. https://doi.org/10.1021/acs.chemrev.1c00481
Wu S., Hu W., Ze Q., Sitti M., Zhao R. Multifunctional magnetic soft composites: A review // Multifunctional Materials. 2020. V. 3. P. 042003. https://doi.org/10.1088/2399-7532/abcb0c
Liao J., Huang H. Review on magnetic natural polymer constructed hydrogels as vehicles for drug delivery // Biomacromolecules. 2020. V. 21. № 7. P. 2574–2594. https://doi.org/10.1021/acs.biomac.0c00566
Shin B.Y., Cha B.G., Jeong J.H., Kim J. Injectable macroporous ferrogel microbeads with a high structural stability for magnetically actuated drug delivery // ACS Applied Materials & Interfaces. 2017. V. 9. № 37. P. 31372–31380. https://doi.org/10.1021/acsami.7b06444
Llandro J., Palfreyman J.J., Ionescu A., Barnes C.H.W. Magnetic biosensor technologies for medical applications: A review // Medical & Biological Engineering & Computing. 2010. V. 48. № 10. P. 977–998. https://doi.org/10.1007/s11517-010-0649-3
Qui J., Li Y., Wang Y., Zhao Z., Zhou Y., Wang Y. Synthesis of carbon-encapsulated nickel nanocrystals by arc discharge of coal-based carbons in water // Fuel. 2004. V. 83. № 4. P. 615–617. https://doi.org/10.1016/j.fuel.2003.09.005
Ermoline A., Schoenitz M., Dreizin E., Yao N. Production of carbon-coated aluminium nanopowders in pulsed microarc discharge // Nanotechnology. 2002. V. 13. № 5. P. 638–643. https://doi.org/10.1088/0957-4484/13/5/320
Athanassiou E., Grass R., Stark W. Large-scale production of carbon-coated copper nanoparticles for sensor applications // Nanotechnology. 2006. V. 17. P. 1668–1673. https://doi.org/10.1088/0957-4484/17/6/022
Kotov Yu.A. Electric explosion of wires as a method for preparation of nanopowders // Journal of Nanoparticle Research. 2003. V. 5. P. 539–550. https://doi.org/10.1023/B:NANO.0000006069.45073.0b
Патент РФ 2033901. Котов Ю.А., Бекетов И.В., Саматов О.М. Способ получения сферических ультрадисперсных порошков оксидов активных металлов. БИ № 12, 1995, с. 134.
Патент РФ 2149735. Котов Ю.А., Бекетов И.В., Саматов О.М. Установка для получения высокодисперсных порошков металлов, сплавов и их химических соединений методом электрического взрыв проволоки. БИ № 15, 2000, с. 284.
Kurlyandskaya G.V., Bhagat S.M., Safronov A.P., Beketov I.V., Larranaga A. Spherical magnetic nanoparticles fabricated by electric explosion of wire // AIP Advances. 2011. V. 1. P. 042122. https://doi.org/10.1063/1.3657510
Beketov I.V., Safronov A.P., Medvedev A.I., Alonso J., Kurlyandskaya G.V., Bhagat S.M. Iron oxide nanoparticles fabricated by electric explosion of wire: Focus on magnetic nanofluids // AIP Advances. 2012. V. 2. P. 022154. https://doi.org/10.1063/1.4730405
Beketov I.V., Safronov A.P., Medvedev A.I., Murzakaev A.M., Zhidkov I.S., Cholah S.O., Maximov A.D. Encapsulation of Ni nanoparticles with oxide shell in vapor condensation // Chimica Techno Acta. 2019. V. 6. № 3. P. 93–103. https://doi.org/10.15826/chimtech.2019.6.3.02
Beketov I.V., Safronov A.P., Bagazeev A.V., Larrañaga A., Kurlyandskaya G.V., Medvedev A.I. In situ modification of Fe and Ni magnetic nanopowders produced by the electrical explosion of wire // Journal of Alloys & Compounds. 2014. V. 586. P. 483–488. https://doi.org/10.1016/j.jallcom.2013.01.152
Safronov A.P., Terziyan T.V., Petrov A.V., Beketov I.V. Tuning of interfacial interactions in poly(isoprene) ferroelastomer by surface modification of embedded metallic iron nanoparticles // Nanosystems: Physics, Chemistry, Mathematics. 2021. V. 12. № 4. P. 520–527. https://doi.org/10.17586/2220-8054-2021-12-4-520-527
Rochas C., Lahaye M. Average molecular weight and molecular weight distribution of agarose and agarose-type polysaccharides // Carbohydr. Polym. 1989. V. 10. № 4. P. 289–298. https://doi.org/10.1016/0144-8617(89)90068-4
Brunchi C.-E., Morariu S., Bercea M. Intrinsic viscosity and conformational parameters of xanthan inaqueous solutions: Salt addition effect // Colloids and Surfaces B: Biointerfaces. 2014. V. 122. P. 512–519. https://doi.org/10.1016/j.colsurfb.2014.07.023
Foner S., Vibrating sample magnetometer // Rev. Sci. Instrum. 1956. V. 27. № 7. P. 548.
Beketov I.V., Safronov A.P., Medvedev A.I., Murzakaev A.M., Timoshenkova O.R., Demina T.M. In-situ formation of carbon shells on the surface of Ni nanoparticles synthesized by the electric explosion of wire // Nanosystems: Physics, Chemistry, Mathematics. 2018. V. 9 № 4. P. 513–520.https://doi.org/10.17586/22208054201894513520
Guenet M.J. Polymer-Solvent Molecular Compounds. Oxford: Elsevier Ltd., 2008.
Iurciuc C., Savin A., Lungu C., Martin P., Popa M. Gellan. Food applications // Cellulose chemistry and technology. 2016. V. 50. № 1. P. 1–13.
Rubinstein M., Colby R.H. Polymer Physics; 1st ed.; Oxford University Press: New York, 2003.
Morris E.R., Nishinari K., Rinaudo M. Gelation of gellan – A review // Food Hydrocolloids. 2012. V. 28. № 2. P. 373–411. https://doi.org/10.1016/j.foodhyd.2012.01.004
Rinaudo M. Physicochemical behaviour of semi-rigid biopolymers in aqueous medium // Food Hydrocolloids. 2017. V. 68. P. 122–127. https://doi.org/10.1016/j.foodhyd.2016.09.015
Safronov A.P., Rusinova E.V., Terziyan T.V., Zemova Y.S., Kurilova N.M., Beketov I.V., Zubarev A.Yu. Gelation in alginate-based magnetic suspensions favored by poor interaction among sodium alginate and embedded particles // Applied Sciences. 2023. V. 13. № 7. P. 4619. https://doi.org/10.3390/app13074619