Получение CО и CH4 по реакции гидрирования CO2 в условиях катализа в низкотемпературной плазме

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Abstract

Исследован процесс гидрирования CO2 в плазме барьерного разряда с использованием катализаторов на основе микро- и мезопористых материалов. Катализаторы синтезированы методом пропитки носителей, содержащих цеолиты типов MFI и MTW, а также мезопористый материал SBA-15. Полученные катализаторы исследованы физико-химическими методами анализа (низкотемпературная адсорбция–десорбция N2, термопрограммированная десорбция NH3, рентгеновская фотоэлектронная спектроскопия, рентгенофазовый анализ). Установлено, что повышение селективности по CH4 (до 87%) достигается в присутствии цеолитсодержащих катализаторов с низкой кислотностью. В присутствии катализаторов, содержащих мезопористый материал SBA-15, повышаются конверсия CO2 (с 24 до 33%) и выход CO, однако реакция метанирования CO2 не протекает (селективность по CH4 составляет < 2.5%).

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About the authors

Олег Владимирович Голубев

Институт нефтехимического синтеза им. А. В. Топчиева РАН

Author for correspondence.
Email: golubev@ips.ac.ru
ORCID iD: 0000-0002-8558-3094

к. х. н.

Russian Federation, Москва, 119991

Антон Львович Максимов

Институт нефтехимического синтеза им. А. В. Топчиева РАН

Email: golubev@ips.ac.ru
ORCID iD: 0000-0001-9297-4950

д. х. н., чл.- корр. РАН

Russian Federation, Москва, 119991

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Supplementary files

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2. Fig. 1. Schematic diagram of the plasma-catalytic unit.

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3. Fig. 2. Adsorption isotherms of the synthesised catalyst samples.

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4. Fig. 3. X-ray photoelectron spectra of the synthesised catalyst samples. Blue line - experimental data, red line - approximating spectrum.

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5. Fig. 4. NH3-TPD curves (a) and X-ray diffraction patterns (b) of the synthesised catalyst samples.

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6. Fig. 5. Results of plasma-catalytic hydrogenation of CO2: a) reactant conversion; b) CO/CH4 selectivity; c) CO/CH4 yield; d) power and energy efficiency.

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7. Fig. 6. Barrier discharge reactor design: a) registration of optical spectra; b) overview spectrum; c) spectrum of the region outside the catalyst zone; d) spectrum of the catalyst layer region.

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