Ion-Selective Membrane Electrode for Determination of the Octahydrotriborate Anion

A. V. Kopytin; Копытин А. В.; E. S. Turyshev; Турышев Е. С.; M. Sh. Madraimov; Мадраимов М. Ш.; A. S. Kubasov; Кубасов А. С.; K. Yu. Zhizhin; Жижин К. Ю.; L. K. Shpigun; Шпигун Л. К.; N. T. Kuznetsov; Кузнецов Н. Т.

doi:10.31857/S0044457X22601432

Ion-Selective Membrane Electrode for Determination of the Octahydrotriborate Anion

Authors: Kopytin A.V.¹, Turyshev E.S.¹, Madraimov M.S.², Kubasov A.S.¹, Zhizhin K.Y.¹, Shpigun L.K.¹, Kuznetsov N.T.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
2. Mendeleev University of Chemical Technology of Russia
Issue: Vol 68, No 1 (2023)
Pages: 10-16
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://journals.eco-vector.com/0044-457X/article/view/665318
DOI: https://doi.org/10.31857/S0044457X22601432
EDN: https://elibrary.ru/GWLWQG
ID: 665318

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Abstract

An ion-selective electrode (ISE) based on a plasticized polyvinyl chloride membrane chemically doped with tetradecylammonium octahydrotriborate ([(С10H21)4N+]
) has been developed. It is shown that the electrode has a reversible potentiometric response with respect to the octahydrotriborate anion in the presence of a number of other inorganic anions. The influence of the concentration of the electrode-active material and the nature of the plasticizer in the membrane phase on the electrochemical characteristics of the fabricated sensor have been studied. The optimal composition of the ion-sensitive membrane has been found. It has been found that the developed sensor provides a wide range of detectable concentrations of
(1 × 10–7…1 × 10–2) and a low detection limit (10–7.3 M). The new ISE can be recommended for direct potentiometric detection of free octahydrotriborate anions in technological aqueous solutions.

Keywords

octahydrotriborate anion, polymer membrane, tetradecylammonium octahydrotriborate

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