Electrochromic Properties and Preparation of Thin V2O5 Films Using Heteroligand Complexes of Vanadyl

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Abstract

Microstructural features, phase composition, and eletrochromic properties of V2O5 film formed by spin-coating using vanadyl alkoxoacetylacetonate as a precursor have been studied. The obtained material possesses a significant amount of V4+ ions, which is indicated both by the presence of the corresponding modes on the Raman spectra and the presence of the V7O16 phase. As a result, the material exhibits anodic electrochromism – it colors upon oxidation, changing color from pale blue to a much less transparent orange-yellow. The optical contrast can reach 30% at a wavelength of 400 nm, and the coloration efficiency is 65.26 cm2/C. The results of the study clearly demonstrate the promising application of materials based on V2O5, obtained using heteroligand hydrolytically active vanadyl complexes, as functional components of devices that provide a change in optical properties when an electrical voltage is applied.

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About the authors

F. Yu. Gorobtsov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: phigoros@gmail.com
Russian Federation, Moscow, 119991

N. P. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: phigoros@gmail.com
Russian Federation, Moscow, 119991

Т. L. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: phigoros@gmail.com
Russian Federation, Moscow, 119991

E. P. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: phigoros@gmail.com
Russian Federation, Moscow, 119991

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Supplementary files

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2. Fig. 1. IR reflectance spectroscopy results for the glass substrate (1) and the V2O5 film formed on it (2).

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3. Fig. 2. Results of CR spectroscopy of the formed V2O5 film on a glass substrate. Marker * denotes modes characteristic of VO2, marker + - modes characteristic of V7O16.

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4. Fig. 3. Microstructure (SEM) of the formed V2O5 film on glass substrate.

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5. Fig. 4. Microstructure (AFM) of the formed V2O5 film on glass substrate.

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6. Fig. 5. Results of measuring electrochromic properties of V2O5 film: a - transmittance spectra of the cell in the visible and near-infrared ranges before the measurements and after 15 s of exposure at different values of potential; b - CVA recorded at a rate of potential change of 50 mV/s; c - change in the transmittance of the electrochromic cell based on V2O5 film at a wavelength of 400 nm and potential sweep during CVA recording; d - change in the transmittance of the cell at a wavelength of 400 nm and exposure for 15 s at 2. 5 V and 10 s at -3.2 V.

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