Structural transitions during thermal destruction in the family of zinc fluoridozirconate crystal hydrates

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Abstract

The structure of ZnZrF6 · 6H2O and ZnZrF6 · 5H2O (high- and low-temperature forms) crystal hydrates and their products of thermal destruction: ZnZrF6 · 4H2O, ZnZrF6 · 2H2O, ZnZrF6 and ZnZr2F10 · 2H2O have been studied. With the exception of ZnZr2F10 · 2H2O, the compounds of ZnZrF6 · nH2O (n = 6, 5, 4, 2, 0) are isostructural to their formula analogues: NiZrF6 · 6H2O, α- and β-MgZrF6 · 5H2O, CuZrF6 · 4H2O, MgZrF6 · 2H2O, MgZrF6, respectively. The structure of ZnZr2F10 · 2H2O is built from unique infinite network anionic layers [Zr2F10]2–, in which ZrF8 square antiprisms are formed tetranuclear cycles and are shared six of their vertices with four neighboring Zr-polyhedra according to the law “…–edge–edge–vertex–vertex–…”; ZnF4(H2O)2-octahedra link Zr-layers to each other into a framework.

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K. A. Saiankina

Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences

Author for correspondence.
Email: kseniyag@ich.dvo.ru
Russian Federation, Vladivostok, 690022

N. A. Didenko

Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences

Email: kseniyag@ich.dvo.ru
Russian Federation, Vladivostok, 690022

N. N. Savchenko

Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences

Email: kseniyag@ich.dvo.ru
Russian Federation, Vladivostok, 690022

A. V. Gerasimenko

Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences

Email: kseniyag@ich.dvo.ru
Russian Federation, Vladivostok, 690022

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Supplementary files

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3. Fig. 1. Complex anions [ZrF6]2– — (a) and cations [Zn(H2O)6]2+ — (b) in structure I.

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4. Fig. 2. Fragment of the Zr–Zn chain in structure II.

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5. Fig. 3. Crystal structures: III — (a) and IV — (b).

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6. Fig. 4. Fragment of the Zr–Zn chain in structure V — (a) and in VI — (b).

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7. Fig. 5. The system of H-bonds between H2O molecules in structures V– (a) and VI — (b).

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8. Fig. 6. Fragment of the Zr–Zn layer in structure VII — (a) and crystal structure VII — (b).

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