Synthesis and Functionalization of Unsymmetrical Terbium(III) Bis-Phthalocyaninates, Promising Components of Hybrid Magnetic Materials

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Resumo

A new unsymmetrical terbium bis-Phthalocyaninate Tb(A7B) with one terminal aliphatic OH group was obtained by template cross-condensation of diethoxyphthalonitrile (A) and phthalonitrile (B) functionalized with diethylene glycol moiety. The subsequent functionalization of the complex included the successive replacement of this OH group by the iodide and thioacetate substituents. The synthesized complexes can act as components of hybrid materials upon immobilization on surfaces of various nature.

Sobre autores

A. Yagodin

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: martynov@phyche.ac.ru
119071, Moscow, Russia

I. Kormshchikov

Faculty of Chemistry, Moscow State University

Email: martynov@phyche.ac.ru
119991, Moscow, Russia

A. Martynov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: martynov@phyche.ac.ru
119071, Moscow, Russia

Yu. Gorbunova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences; Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: martynov@phyche.ac.ru
119071, Moscow, Russia; 119991, Moscow, Russia

A. Tsivadze

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences; Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Autor responsável pela correspondência
Email: martynov@phyche.ac.ru
119991, Moscow, Russia; 119991, Moscow, Russia

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Declaração de direitos autorais © А.В. Ягодин, И.Д. Кормщиков, А.Г. Мартынов, Ю.Г. Горбунова, А.Ю. Цивадзе, 2023