Synthesis, Structure, and Electrochemical Properties of Cobalt Complex Based on N-(2,5-Bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

New bis-chelate cobalt(II) complex [Co(DPG)2(DMF)2] (1), where DPG is N-(2,5-bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate, has been prepared and characterized. The complex is the first example of cobalt complex containing phosphorylated derivative of α-amino acid. Octahedral coordination geometry of the cobalt complex 1 has been determined by X-ray diffraction. Electrochemical reduction of the obtained complex has been found to be irreversible two-electron process (
 = –1.70 V vs Ag/AgNO3, 1 × 10–2 М in CH3CN), resulting in formation of cobalt metal adsorbed on the surface of working electrode.

Авторлар туралы

I. Sakhapov

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: ilyas.sakhapov@iopc.ru
420088, Kazan, Russia

A. Kagilev

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences; Alexander Butlerov Institute of Chemistry, Kazan Federal University

Email: yakhvar@iopc.ru
420088, Kazan, Russia; 420008, Kazan, Russia

A. Kantyukov

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences; Alexander Butlerov Institute of Chemistry, Kazan Federal University

Email: yakhvar@iopc.ru
420088, Kazan, Russia; 420008, Kazan, Russia

I. Mikhailov

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences; Alexander Butlerov Institute of Chemistry, Kazan Federal University

Email: yakhvar@iopc.ru
420088, Kazan, Russia; 420008, Kazan, Russia

O. Sof’icheva

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: yakhvar@iopc.ru
420088, Kazan, Russia

D. Islamov

Laboratory for Structural Analysis of Biomacromolecules, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: yakhvar@iopc.ru
420011, Kazan, Russia

Z. Gafurov

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: yakhvar@iopc.ru
420088, Kazan, Russia

D. Yakhvarov

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences; Alexander Butlerov Institute of Chemistry, Kazan Federal University

Хат алмасуға жауапты Автор.
Email: yakhvar@iopc.ru
420088, Kazan, Russia; 420008, Kazan, Russia

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Қосымша файлдар


© И.Ф. Сахапов, А.А. Кагилев, А.О. Кантюков, И.К. Михайлов, О.С. Софьичева, Д.Р. Исламов, З.Н. Гафуров, Д.Г. Яхваров, 2023