电邮这篇文章 Heteroleptic Cobalt Complexes with Abnormally Coordinated N-Heterocyclic Carbene
- 作者: Petrov P.A.1, Nikolaevskii S.A.2, Yambulatov D.S.2, Sukhikh T.S.1, Starikova A.A.3, Kiskin M.A.2, Sokolov M.N.1, Eremenko I.L.2
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隶属关系:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
- Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia
- 期: 卷 49, 编号 7 (2023)
- 页面: 398-405
- 栏目: Articles
- URL: https://journals.eco-vector.com/0132-344X/article/view/667494
- DOI: https://doi.org/10.31857/S0132344X22600527
- EDN: https://elibrary.ru/YJHFWF
- ID: 667494
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详细
The reaction of cobalt pivalate [Co(Piv)2]n and in situ generated N‑heterocyclic carbene IPrPh (1,3-bis(2,6-diisopropylphenyl)-2-phenylimidazol-4-ylidene) affords heteroligand complexes [Co2(Piv)4-(IPrPh)2] (I), [Co2(Piv)2.8(OtBu)1.2(IPrPh)2] (II), and [Co3(μ3-O)(Piv)4(IPrPh)2] (III). The structures of complexes II·C6H14 and III are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2216724 and 2216725, respectively). Exchange spin-spin interactions between the magnetic Со2+ ions in the synthesized compounds are estimated by quantum chemical calculations.
作者简介
P. Petrov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Email: panah@niic.nsc.ru
Россия, Новосибирск
S. Nikolaevskii
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: sanikol@igic.ras.ru
Россия, Москва
D. Yambulatov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: sanikol@igic.ras.ru
Россия, Москва
T. Sukhikh
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Email: sanikol@igic.ras.ru
Россия, Новосибирск
A. Starikova
Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia
Email: sanikol@igic.ras.ru
Россия, Ростов-на-Дону
M. Kiskin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: sanikol@igic.ras.ru
Россия, Москва
M. Sokolov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Email: sanikol@igic.ras.ru
Россия, Новосибирск
I. Eremenko
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
编辑信件的主要联系方式.
Email: sanikol@igic.ras.ru
Россия, Москва
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