Numerical simulation of orthosilicic acid polycondensation and silica particles formation inhydrothermal solutions
- 作者: Potapov V.V.1, Cerdan A.A.2, Kashutina I.A.3
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隶属关系:
- Research Geotechnological Center of Far East Division of Russian Academy of Sciences
- Moscow Lomonosov State University
- Kamchatka Bering State University
- 期: 编号 4 (2019)
- 页面: 18-28
- 栏目: Articles
- URL: https://journals.eco-vector.com/0203-0306/article/view/15262
- DOI: https://doi.org/10.31857/S0203-03062019418-28
- ID: 15262
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详细
Numerical simulation of the process of polycondensation of orthosilicic acid and colloid silica particles growth under different physical and chemical conditions was done: temperature, pH, ionic strength and other. Calculated dependences of orthosilicic acid concentration and mean radius of silica particles versus time, graphs of particles dimensions distributions were received. Results of calculations were compared with experimental data. Research is important for to make clear role of colloid silica on hydrothermal mineral formation and for industrial extraction and utilization of silica, and also for mineral synthesis.
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作者简介
V. Potapov
Research Geotechnological Center of Far East Division of Russian Academy of Sciences
编辑信件的主要联系方式.
Email: vadim_p@inbox.ru
俄罗斯联邦, Severo-Vostochnoe highway, 30, p.b. 56, Petropavlovsk-Kamchatsky, 683002
A. Cerdan
Moscow Lomonosov State University
Email: cerdan@mail.ru
Chemical Department
俄罗斯联邦, Leninskie Gory, 1, building 3, Moscow, 119991I. Kashutina
Kamchatka Bering State University
Email: k1i2a3@yandex.ru
俄罗斯联邦, Leningradskaya str. 4, Petropavlovsk-Kamchatsky, 683032
参考
- Кирюхин А.В., Шадрина С.В., Пузанков М.Ю. Моделирование термогидрогеохимических условий формирования продуктивных резевуаров в вулканогенных породах // Вулканология и сейсмология. 2013. № 2. С. 90–104.
- Потапов В.В., Кашутина И.А., Шунина Е.В. Численное моделирование поликонденсации ортокремниевой кислоты в гидротермальных растворах // Вулканология и сейсмология. 2016. № 5. С. 51–63.
- Потапов В.В., Камашев Д.В., Горбач В.А., Близнюков М.А. Образование упорядоченных надмолекулярных структур кремнезема в гидротермальном растворе // Вулканология и сейсмология. 2006. № 6. С. 12–21.
- Фролов Ю.Г., Шабанова Н.А., Попов В.В. Влияние температуры и рН на поликонденсацию кремниевой кислоты в водной среде // Коллоидный журнал. 1983. Т. 45. №1. С. 179–182.
- Чухров Ф.В. Коллоиды в земной коре. М.: Изд-во АН СССР, 1955. 671 с.
- Brown K.L., Bacon L.G. Manufacture of silica sols from separated geothermal water // World Geothermal Congress, Kyushu–Tohoku, Japan, May 28 – June 10. 2000. P. 533–537.
- Crerar D.A., Axtmann E.V. Growth and ripening of silica polymers in aqueous solutions // Geochim. et Cosmochim. Acta. 1981. V. 45. P. 1259–1266.
- Kiryukhin A.V., Xu T., Pruess K. et al. Thermal-hydrodynamic-chemical (THC) modeling based on geothermal field data // Geotermics. 2004. V. 33. P. 349–381.
- Ohsawa S., Kawamura T., Nakamatsu N., Yusa Y. Geothermal blue water colored by colloidal silica // World Geothermal Congress, Kyushu–Tohoku, Japan, May 28 – June 10. 2000. P. 663–668.
- Rothbaum H.P., Rohde A.G. Kinetics of silica polymerization and deposition from dilute solutions between 5 and 1800C // Journal of Colloid and Interface Science. 1979. V. 71. N. 3. P. 533–559.
- Weres O., Yee A., Tsao L. Kinetics of silica polymerization // Report LBL-7033, Lawrence Berkeley Laboratory. Berkeley, 1980. 256 p.
- Weres O., Yee A., Tsao L. Kinetics of Silica Polymerization // J. Coll. Interf. Sci. 1981. V. 84. № 2. P. 379–402.
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