Kinetic Peculiarities of Suzuki Reaction under Conditions of Competing Substrates in the Presence of Palladium Catalysts Deposted on Sulfonated Porous Aromatic Polymer

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In this work, the Suzuki reaction was studied under conditions of competing substrates in the presence of catalysts, containing PdII or Pd0 nanoparticles, synthesized using a sulfonated amorphous aromatic polymer as a support. The paper discusses the influence of reaction conditions (stirring rate, temperature, nature of the base), as well as various pairs of competing aryl halides (bromides and iodides) containing both electron-donating and electron-withdrawing groups. It was shown for the first time that aryl bromides containing electron-withdrawing groups in the p-position with respect to the halogen are capable of noticeably slowing down the conversion of each other, as well as stopping the conversion of other aryl bromides in the presence of Pd0 nanoparticles as a source of catalytically active forms of palladium. Additives of sodium salt anions (chloride, bromide and acetate) are able to prevent the reaction from stopping.

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作者简介

L. Nikoshvili

Tver State Technical University

编辑信件的主要联系方式.
Email: nlinda@science.tver.ru
俄罗斯联邦, Tver

E. Bakhvalova

Tver State Technical University

Email: nlinda@science.tver.ru
俄罗斯联邦, Tver

M. Sulman

Tver State Technical University

Email: nlinda@science.tver.ru
俄罗斯联邦, Tver

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2. Scheme 1. Suzuki cross-coupling response

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3. Fig. 1. Photograph of SNF polymer granules

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4. Fig. 2. High-resolution XRD spectrum of Pd3d (a) and light-field PEM image of the catalyst 1% Pd/SNF-R (b)

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5. Fig. 3. Dependence of catalytic activity on stirring rate in the cross-coupling reaction of 4-bromanisole and phenylboronic acid in the presence of 1% Pd/SNF-R

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6. Fig. 4. Time dependences of 4-bromanisole concentration (a, b), the fraction of the cross-coupling product in the mixture with the homocoupling product (biphenyl) on 4-bromanisole conversion (c, d), as well as the corresponding phase trajectories (e, f) when varying the reaction temperature in the presence of initial 1% Pd/SNF (a, c, e) and reduced 1% Pd/SNF-R (b, d, f) samples

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7. Fig. 5. Kinetic curves of aryl halide concentration-time dependence in the presence of competing substrates: 4-iododnisole and 4-bromanisole (a), 4-bromonitrobenzene and 4-bromanisole (b), as well as the effect of sodium salt additives on the concentration-time dependence of 4-bromonitrobenzene (solid lines) and 4-bromanisole (dashed lines) (c) and phase trajectories (d) in the presence of 1% Pd/SNF-R catalyst

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8. Fig. 6. Comparison of time dependences of 4-bromo-nitrobenzene and 4-bromobenzaldehyde concentrations in separate experiments (black symbols) and under conditions of competing substrates (grey symbols) in the presence of initial 1% Pd/SNF (a) and reduced 1% Pd/SNF-R (b) catalysts, as well as the corresponding phase trajectories obtained at the first and repeated use of samples of 1% Pd/SNF (c) and 1% Pd/SNF-R (d) under the conditions of competing substrates

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9. Fig. 7. Light-field PREM images of the initial 1% Pd/SNF-R (a) and samples of 1% Pd/SNF-R (b) and 1% Pd/SNF (c) after Suzuki reaction under the conditions of competing substrates (4-bromo-nitrobenzene and 4-bromobenzaldehyde); example of dark-field image (d) and Pd EDS mapping (e) for 1% Pd/SNF-R catalyst after reaction, as well as histograms of particle size distribution in samples (f)

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