Reaction Ways of Lignin Monomer Conversion in Propanol-2

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Lignin, a large-scale waste from the processing of lignocellulose biomass, is a promising raw material to obtain products with high added value. The processes of lignin depolymerization lead to the formation of oxygen-containing compounds, a.i. phenol derivatives. Since the depolymerization of lignin involves many reactions, including the conversion of monomers, the purpose of this work is to study the ways of conversion of phenol, anisole, guaiacol, syringol, eugenol, hydroquinone, and p-ethylphenol both as individual components and in a mixture during its catalytic processing. The experiments were carried out in the medium of propanol-2 in the presence of Ni–Ru/SiO2@HPS catalyst varying the process conditions. The composition of the products of conversion lignin monomers was studied. The main ways of the transformation of monophenols were found to be hydrogenation of the aromatic ring, deoxygenation and hydrogenation of the resulting aromatic hydrocarbons. The rate of component consumption during the conversion of the mixture was found to be lower than that for the individual substrates. A study of the process temperature and the partial pressure of hydrogen on the conversion of a mixture of substrates was carried out. Aromatic hydrocarbons were chosen as target products in this work. The optimal conditions for the conversion of a mixture of substrates in terms of process rate and selectivity to aromatic hydrocarbons were estimated to be a temperature of 280°C, a partial pressure of hydrogen 3.0 MPa.

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作者简介

A. Stepacheva

Tver State Technical University

编辑信件的主要联系方式.
Email: a.a.stepacheva@mail.ru
俄罗斯联邦, Tver

E. Tereshina

Tver State Technical University

Email: a.a.stepacheva@mail.ru
俄罗斯联邦, Tver

A. Tarasova

Tver State Technical University

Email: a.a.stepacheva@mail.ru
俄罗斯联邦, Tver

M. Akinchits

Tver State Technical University

Email: a.a.stepacheva@mail.ru
俄罗斯联邦, Tver

E. Ershova

Tver State Technical University

Email: a.a.stepacheva@mail.ru
俄罗斯联邦, Tver

S. Emelyanova

Tver State Technical University

Email: a.a.stepacheva@mail.ru
俄罗斯联邦, Tver

V. Matveeva

Tver State Technical University

Email: a.a.stepacheva@mail.ru
俄罗斯联邦, Tver

M. Sulman

Tver State Technical University

Email: a.a.stepacheva@mail.ru
俄罗斯联邦, Tver

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2. Fig. 1. Kinetic curves of substrate consumption and product accumulation during conversion of phenol (a), anisole (b), p-ethylphenol (c) and hydroquinone (d) in the presence of Ni-Ru/SiO2@HPS catalyst. Process conditions: temperature - 280°C, substrate to catalyst ratio - 10 mol substrate/g metal, hydrogen partial pressure - 3.0 MPa

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3. Fig. 2. Kinetic curves of substrate consumption and product accumulation during the conversion of guaiacol (a), syringol (b) and eugenol (c) in the presence of Ni-Ru/SiO2@HPS catalyst. Process conditions: temperature - 280°C, substrate to catalyst ratio - 10 mol substrate/g metal, hydrogen partial pressure - 3.0 MPa

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4. Scheme 1. Conversion pathways of lignin depolymerisation monomers: phenol (a), anisole (b), p-ethylphenol (c) and hydroquinone (d)

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5. Scheme 2. Conversion pathways of lignin depolymerisation monomers: guaiacol (a), syringol (b) and eugenol (c)

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6. Fig. 3. Consumption curves of lignin depolymerisation product mixture over time in the presence of Ni-Ru/SiO2@HPS catalyst. Process conditions: temperature - 280°C, substrate to catalyst ratio - 10 mol substrate/g metal, hydrogen partial pressure - 3.0 MPa

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