Email this article New 4,5-diaza-9,9'-spirobifluorene derivative – promising electron acceptor for nonfullerene polymer solar cells
- Authors: Kuklin S.A.1, Konstantinov I.O.1, Peregudov A.S.1, Ostapov I.E.2, Buyanovskaya A.G.1, Toropygun I.Y.3, Khokhlov A.R.1, Zou Y.4, Godovskii D.Y.1, Keshtov M.L.1
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Affiliations:
- Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
- Lomonosov Moscow State University
- Orekhovich Institute of Biomedical Chemistry
- Central South University
- Issue: Vol 485, No 3 (2019)
- Pages: 311-316
- Section: Chemical Technology
- URL: https://journals.eco-vector.com/0869-5652/article/view/12869
- DOI: https://doi.org/10.31857/S0869-56524853311-316
- ID: 12869
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Abstract
New 4,5-diaza-9,9'-spirobifluorene derivative 8 with two electron-accepting perylene diimide moieties has been prepared. The compound 8 was characterized by NMR spectroscopy, elemental analysis, UV-spectroscopy and cyclic voltammetry. Energies of HOMO/LUMO levels are of -5.81 eV/-3.89 eV; Egopt and Egech values are of 1.75 eV and 1.92 eV, respectively. Low-lying energy levels and strong absorption in the visible region of UV- spectrum indicate the potential use of the compound 8 as a new promising electron acceptor in nonfullerene polymer solar cells.
About the authors
S. A. Kuklin
Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Author for correspondence.
Email: ineos-50@mail.ru
Russian Federation, Moscow
I. O. Konstantinov
Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Email: ineos-50@mail.ru
Russian Federation, Moscow
A. S. Peregudov
Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Email: ineos-50@mail.ru
Russian Federation, Moscow
I. E. Ostapov
Lomonosov Moscow State University
Email: ineos-50@mail.ru
Russian Federation, Moscow
A. G. Buyanovskaya
Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Email: ineos-50@mail.ru
Russian Federation, Moscow
I. Yu. Toropygun
Orekhovich Institute of Biomedical Chemistry
Email: ineos-50@mail.ru
Russian Federation, Moscow
A. R. Khokhlov
Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Email: ineos-50@mail.ru
academician of the RAS
Russian Federation, MoscowY. Zou
Central South University
Email: ineos-50@mail.ru
Taiwan, Province of China, Changsha
D. Yu. Godovskii
Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Email: ineos-50@mail.ru
Russian Federation, Moscow
M. L. Keshtov
Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Email: ineos-50@mail.ru
Russian Federation, Moscow
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