Mechanisms of accumulation of chemical elements in the peat deposit in east part of the Vasyugan Swamp (the Western Siberia)

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Abstract

The results of mineralogical-geochemical studies of the oligotrophic pine-fruticulose-sphagnum segment of the Vasyugan Swamp (West Siberia) in the winter of 2017 are presented. A mathematical model is developed for the depth distribution of chemical elements in water and acid extracts of peats, organo-mineral sediments, and inorganic soil. It is shown that two complex geochemical barriers related to the changes in filtration properties of soils and contributing to the formation and/or accumulation of Fe compounds and other chemical elements function in the peat deposit. The first (oxidizing, reduction, sulfide, and adsorption hydroxide) barrier is found approximately at a depth of 0.40-1.25 m; the second (alkaline carbonate and hydrolytic, adsorption hydroxide, clayey, and carbonate) barrier lies in the lower layer of the peat deposit (a depth of 2.25-2.50 m). The result obtained is important for understanding the production-destruction methane cycle.

About the authors

O. G. Savichev

National Research Tomsk Polytechnic University

Author for correspondence.
Email: osavichev@mail.ru
Russian Federation, 30, Lenin Avenue,Tomsk, 634034

A. K. Mazurov

National Research Tomsk Polytechnic University

Email: osavichev@mail.ru
Russian Federation, 30, Lenin Avenue,Tomsk, 634034

M. A. Rudmin

National Research Tomsk Polytechnic University

Email: osavichev@mail.ru
Russian Federation, 30, Lenin Avenue,Tomsk, 634034

N. E. Shakhova

National Research Tomsk Polytechnic University

Email: osavichev@mail.ru
Russian Federation, 30, Lenin Avenue,Tomsk, 634034

V. I. Sergienko

Pacific Oceanological Institute, Far Eastern Branch of the Russian Academy of Sciences

Email: osavichev@mail.ru

Academician of the Russian Academy of Sciences

Russian Federation, 43, Baltiyskaya Street, Vladivostok, 690041

I. P. Semiletov

Pacific Oceanological Institute, Far Eastern Branch of the Russian Academy of Sciences; National Research Tomsk Polytechnic University

Email: osavichev@mail.ru

Corresponding Member of the Russian Academy of Sciences

Russian Federation, 43, Baltiyskaya Street, Vladivostok, 690041; 30, Lenin Avenue,Tomsk, 634034

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