Email this article Reduction of acridine and 9-chloroacridine by red phosphorus in the KOH/DMSO system
- Authors: Kuimov V.A.1, Gusarova N.K.1, Malysheva S.F.1, Kon’kova T.V.1, Trofimov B.A.1
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Affiliations:
- Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
- Issue: Vol 487, No 2 (2019)
- Pages: 151-153
- Section: Chemistry
- URL: https://journals.eco-vector.com/0869-5652/article/view/15466
- DOI: https://doi.org/10.31857/S0869-56524872151-153
- ID: 15466
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Abstract
Acridine reacts with red phosphorus in KOH/DMSO(H2O) system upon heating (100 ºC, 3 h) to regioselectively give and 9,10-dihydroacridine in almost quantitative yields. Under similar conditions, the reaction of 9-chloroacridine with the system Pred/KOH/DMSO(H2O) affords 9,10-dihydroacridine and acridone in 51 and 40% yields respectively.
About the authors
V. A. Kuimov
Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: boris_trofimov@irioch.irk.ru
Russian Federation, 1, Favorsky street, Irkutsk, 664033
N. K. Gusarova
Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: boris_trofimov@irioch.irk.ru
Russian Federation, 1, Favorsky street, Irkutsk, 664033
S. F. Malysheva
Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: boris_trofimov@irioch.irk.ru
Russian Federation, 1, Favorsky street, Irkutsk, 664033
T. V. Kon’kova
Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: boris_trofimov@irioch.irk.ru
Russian Federation, 1, Favorsky street, Irkutsk, 664033
B. A. Trofimov
Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Author for correspondence.
Email: boris_trofimov@irioch.irk.ru
Academician of the Russian Academy of Sciences
Russian Federation, 1, Favorsky street, Irkutsk, 664033References
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