Reduction of acridine and 9-chloroacridine by red phosphorus in the KOH/DMSO system

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Abstract


Acridine reacts with red phosphorus in KOH/DMSO(H2O) system upon heating (100 ºC, 3 h) to regioselectively give and 9,10-dihydroacridine in almost quantitative yields. Under similar conditions, the reaction of 9-chloroacridine with the system Pred/KOH/DMSO(H2O) affords 9,10-dihydroacridine and acridone in 51 and 40% yields respectively.


About the authors

V. A. Kuimov

Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: boris_trofimov@irioch.irk.ru

Russian Federation, 1, Favorsky street, Irkutsk, 664033

N. K. Gusarova

Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: boris_trofimov@irioch.irk.ru

Russian Federation, 1, Favorsky street, Irkutsk, 664033

S. F. Malysheva

Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: boris_trofimov@irioch.irk.ru

Russian Federation, 1, Favorsky street, Irkutsk, 664033

T. V. Kon’kova

Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: boris_trofimov@irioch.irk.ru

Russian Federation, 1, Favorsky street, Irkutsk, 664033

B. A. Trofimov

Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Author for correspondence.
Email: boris_trofimov@irioch.irk.ru

Russian Federation, 1, Favorsky street, Irkutsk, 664033

Academician of the Russian Academy of Sciences

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