Email this article N-heterocyclic compounds of phosphorus based ON N,N-disubstituted 9,10-phenanthrenediimines
- Authors: Abakumov G.A.1, Druzhkov N.O.1, Kazakov G.G.1,2, Fukin G.K.1, Rumyantcev R.V.1, Cherkasov V.K.1,2
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Affiliations:
- Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
- Lobachevsky State University of Nizhni Novgorod
- Issue: Vol 489, No 4 (2019)
- Pages: 368-372
- Section: Chemistry
- URL: https://journals.eco-vector.com/0869-5652/article/view/18689
- DOI: https://doi.org/10.31857/S0869-56524894368-372
- ID: 18689
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Abstract
N‑heterocyclic phospholes based on N,N¢-disubstituted 9,10-phenanthrenediimines were synthesized. Dimeric 1,3,2-diazaphospholes were obtained by reduction of 2-bromo diazaphospholes. In case phenanthrediimine with the most sterically hindrance, diphosphole can dissociate into phosphorus-centered radicals at record low temperatures (220 K) for this class. This behavior will allow the synthesis of new metal complexes and phosphorus-organic compounds under mild conditions.
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About the authors
G. A. Abakumov
Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
Email: gkazakov@iomc.ras.ru
Academician of the Russian Academy of Sciences
Russian Federation, 49, Tropinin street, Nizhny Novgorod, 603950N. O. Druzhkov
Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
Email: gkazakov@iomc.ras.ru
Russian Federation, 49, Tropinin street, Nizhny Novgorod, 603950
G. G. Kazakov
Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences; Lobachevsky State University of Nizhni Novgorod
Author for correspondence.
Email: gkazakov@iomc.ras.ru
Russian Federation, 49, Tropinin street, Nizhny Novgorod, 603950; 23, Gagarin avenue, Nizhni Novgorod, 603600
G. K. Fukin
Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
Email: gkazakov@iomc.ras.ru
Russian Federation, 49, Tropinin street, Nizhny Novgorod, 603950
R. V. Rumyantcev
Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences
Email: gkazakov@iomc.ras.ru
Russian Federation, 49, Tropinin street, Nizhny Novgorod, 603950
V. K. Cherkasov
Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences; Lobachevsky State University of Nizhni Novgorod
Email: gkazakov@iomc.ras.ru
Corresponding Member of the Russian Academy of Sciences
Russian Federation, 49, Tropinin street, Nizhny Novgorod, 603950; 23, Gagarin avenue, Nizhni Novgorod, 603600References
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