Analysis of chromatograms for study of the vadose zone and shallow aquifer contamination by petroleum products

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅或者付费存取

详细

Contamination of shallow aquifers and rocks in the vadose zone with oil and its refined products is one of the most common types of technogenic pollution of the geological environment. Specifics of infrastructure development of territories require the compact location of enterprises engaged in the storage and transportation of petroleum products belonging to different business entities. When carrying out engineering and environmental survey, it is important not only to outline the contamination plume in plan and by geological cross-section, but also to identify correctly the sources of oil products entering the subsurface. To solve this problem, an approach was proposed based on comparing data on the chemical composition of oil products samples from prospecting boreholes. It is proposed to normalize chemical analysis data using a common and clearly distinguishable peak for all chromatograms. The approach was tested on the oil-polluted site. Comparison of chromatograms allows identifying the affiliation of petroleum products to different sources of pollution even if they are of the same type and have close average molecular weights. The results of the studies made it possible to prove the multiplicity of pollution sources (at least 4). The main directions of pollution transformation are the loss of light hydrocarbons and aromatic compounds as a result of their evaporation, dissolution in groundwater and biodegradation.

全文:

受限制的访问

作者简介

I. Kharkhordin

Geostroyproekt Ltd.

编辑信件的主要联系方式.
Email: kharkhordin@rambler.ru
俄罗斯联邦, St. Petersburg

О. Soldatova

St. Petersburg Scientific Center, Russian Academy of Science

Email: soldatova.olga94@gmail.com
俄罗斯联邦, St. Petersburg

Е. Korneeva

St. Petersburg State University of Architecture and Civil Engineering

Email: kharkhordin@rambler.ru
俄罗斯联邦, St. Petersburg

A. Avsyukevich

St. Petersburg State University of Architecture and Civil Engineering

Email: kharkhordin@rambler.ru
俄罗斯联邦, St. Petersburg

参考

  1. Korneeva, E.A., Avsyukevich, A.P., Kudryavtsev, A.V. [Survey and elimination of groundwater contaminations]. Promyshlennoe i grazhdanskoe stroitelstvo, 2022, no. 5, pp. 31–37. (in Russian)
  2. Mironenko, V.A., Petrov, N.S. [Groundwater contamination with hydrocarbons]. Geoekologiya, 1995, no. 1, pp. 3–27. (in Russian)
  3. Mironenko, V.A., Rumynin, V.G. [Problems of environmental geoscience. Vol. 3. Book 2]. Moscow, Nedra Publ., 2002, 504 p.
  4. Pinchuk, N.P., Yunak, A.I., Pokutnik, A.S., Kharkhordin, et al. [Investigation and remediation of groundwater aquifer and vadose zone contaminated with petroleum products (Analytic review]. Moscow, NIA–Priroda Publ., 2002, 48 p. (in Russian)
  5. [Commercial petroleum products, their properties and applications. Handbook]. N.G. Puchkov, Ed., Moscow, Khimiya Publ., 1971, 415 p. (in Russian)
  6. Kharkhordin, I.L., Abramov, V.Yu., Potapov, A.A., Blinov, V.K. [Neva River contamination by petroleum products transported with groundwater flow]. Razvedka i okhrana nedr, 1998, no. 7–8, pp. 71–73. (in Russian)
  7. Alimi, H., Ertel, T., Schug, B. Fingerprinting of hydrocarbon fuel contaminants: literature review. Environmental Forensics, 2003, no. 4, pp. 25–38.
  8. Bhuparthiraju, V.K., Krauter, P., Holman, H.-Y.N., et al. Assessment of in-situ bioremediation at a refinery waste-contaminated site and an aviation gasoline contaminated site. Biodegradation, 2002, vol. 13, pp. 79–90.
  9. Borden, R.S., Bedient, P.B. Transport of dissolved hydrocarbons influenced by oxygen-limited biodegradation. 1. Theoretical development. Water Resources Research, 1986, vol. 22, no. 13, pp. 1973–1982.
  10. Faust, C.R. Transport of immiscible fluids within and below unsaturated zone: A numerical model. Water Resources Research, 1985, vol. 21, no. 4, pp. 587–596.
  11. Hunt, J.R., Sitar, N., Udell, K.S. Nonaqueos phase transport and cleanup. Analysis of mechanisms. Water Resources Research, 1988, vol. 24, no. 8, pp. 1247–1258.
  12. Karickhoff, S.W. Organic pollutant sorption in aquatic system. Journal of Hydraulic Engineering, 1979, vol. 110, no. 6, pp. 707–735.
  13. Lenhard, R.J., Parker, J.C. Estimation of free product hydrocarbon volume from liquid levels in monitoring wells. Ground Water, 1990, vol. 28, pp. 57–67.
  14. Mackay, D.L., Cherry, J.A. Groundwater contamination: pump-and-treat remediation. Environmental Science & Technology, 1989, vol. 23, no. 6, pp. 620–636.
  15. Marrin, D.L. Soil-gas sampling and misinterpretation. Groundwater Monitoring &Remediation,1988, Spring, pp. 51–54.
  16. Mercer, I.W., Cohen, R.M. A review of immiscible fluids in the subsurface: properties, models, characterization and remediation. Journal of Contaminant Hydrology, 1990, no. 6, pp. 107–163.
  17. Washington, J.W. Gas partitioning of dissolved volatile organic compounds in the vadose zone: principles, temperatures effects, and literature review. Ground Water, 1996, vol. 34, no. 4, pp. 709–718.

补充文件

附件文件
动作
1. JATS XML
下载
2. Fig. 1. Work areas and observation wells.

下载 (851KB)
索引源数据
3. Fig. 2. Soil of the coastal strip contaminated with oil products and a film of oil products on the water.

下载 (809KB)
索引源数据
4. Fig. 3. Gas-liquid chromatogram for a sample taken from well 7n.

下载 (436KB)
索引源数据
5. Fig. 4. Normalized to C12 concentrations of hydrocarbons in samples of petroleum products from the contaminated site.

下载 (653KB)
索引源数据
6. Fig. 5. Comparison of normalized concentrations of hydrocarbons in samples: a - 1n and 2n, b - 1n and 3n.

下载 (183KB)
索引源数据
7. Fig. 6. Comparison of normalized concentrations of hydrocarbons in samples: a - 7n and 6n, b - 9n and 8n, c - 6n and 9n.

下载 (271KB)
索引源数据
8. Fig. 7. Comparison of normalized concentrations of hydrocarbons in samples: a - 5n and 1n, b - 4n and 1n, c - 8n and 1n.

下载 (295KB)
索引源数据

版权所有 © Russian academy of sciences, 2025