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Lutetium Cyclopentadienyl Complex with the 2,6-Di-tert-Butylanthracene Dianion
- Authors: Roitershtein D.M.1,2, Lyssenko K.A.3, Nifant’ev I.E.1,2,3, Minyaev M.E.2
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Affiliations:
- Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia
- Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
- Moscow State University, Moscow, Russia
- Issue: Vol 49, No 6 (2023)
- Pages: 367-374
- Section: Articles
- URL: https://journals.eco-vector.com/0132-344X/article/view/667506
- DOI: https://doi.org/10.31857/S0132344X22600497
- EDN: https://elibrary.ru/UQIJUF
- ID: 667506
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Abstract
The reaction of 2,6-di(tert-butyl)anthracene with potassium graphite and monocyclopentadienyllutetium dichloride tetrahydrofuranate in THF gave the anthracenide complex [(η5-C5H5)Lu(η2-2,6-tBu2C14H8)(THF)2] (I), which was studied by X-ray diffraction (CCDC no. 2215512). Complex I crystallizes in the orthorhombic space group P212121. The structural rigidity of the Lu(O)2Cp(anthracene) crystallographic node was demonstrated. The retention of the structure of complex I in solution was confirmed by NMR techniques.
About the authors
D. M. Roitershtein
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia; Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: mminyaev@ioc.ac.ru
Россия, Москва; Россия, Москва
K. A. Lyssenko
Moscow State University, Moscow, Russia
Email: mminyaev@ioc.ac.ru
Россия, Москва
I. E. Nifant’ev
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia; Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia;Moscow State University, Moscow, Russia
Email: mminyaev@ioc.ac.ru
Россия, Москва; Россия, Москва; Россия, Москва
M. E. Minyaev
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
Author for correspondence.
Email: mminyaev@ioc.ac.ru
Россия, Москва
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